Stereoselective synthesis of β,γ-unsaturated ketones by acid-mediated Julia-type transformation from 2-(1-hydroxyalkyl)-1- alkylcyclopropanols

Synlett

Volumn , Issue 9, 2008, Pages 1412-1414

  Nomura, Kenichi ^a   Matsubara, Seijiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

, unsaturated ketone; Carbocation; Cyclopropanol; Methylene insertion; Stereoselective

Indexed keywords

KETONE DERIVATIVE; PROPRANOLOL DERIVATIVE; TRIFLUOROACETIC ACID;

ARTICLE; CHEMICAL REACTION; CYCLOPROPANATION; STEREOCHEMISTRY; STEREOSPECIFICITY;

EID: 45749143684     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1067077     Document Type: Article

References (14)

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13. 2O to this system did not also change the ratio. These experiments mean that the diastereoselectivity does not come from isomerization of the initial product.
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