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Volumn 20, Issue 10, 2008, Pages 3239-3241

Solvothermal conversion of discrete cubic cadmium thiolate cluster into supertetrahedral cluster decorating quartz-type chiral superlattice

Author keywords

[No Author keywords available]

Indexed keywords

CHALCOGENIDE; CLUSTER BASED; CUBIC CLUSTERS; IONIC SALTS; ROOM-TEMPERATURE (RT); SOLVOTHERMAL; SOLVOTHERMAL SYNTHESIS; SUPERLATTICE (SL); SYNTHESIS (OF CHIRAL IONIC LIQUIDS); SYNTHETIC PROCEDURES; THIOLATE; THREE DIMENSIONAL (3D); THREE STEP PROCESS;

EID: 45749142062     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm702874s     Document Type: Article
Times cited : (37)

References (33)
  • 15
    • 45749111161 scopus 로고    scopus 로고
    • 2O (3.08 g, 10 mmol) was dissolved in methanol (50 mL) to form a clear solution. This solution was then added to a methanol solution prepared by dissolving 3-fluorothiophenol (2.56 g, 20 mmol) and triethylamine (2.02 g, 20 mmol) in 50 mL of methanol. The mixture was stirred for 2 h at room temperature. The resulting white precipitate was filtered, washed with methanol, then dissolved in DMF, and layered by methanol. After 4-6 weeks, cubic crystals were harvested.
    • 2O (3.08 g, 10 mmol) was dissolved in methanol (50 mL) to form a clear solution. This solution was then added to a methanol solution prepared by dissolving 3-fluorothiophenol (2.56 g, 20 mmol) and triethylamine (2.02 g, 20 mmol) in 50 mL of methanol. The mixture was stirred for 2 h at room temperature. The resulting white precipitate was filtered, washed with methanol, then dissolved in DMF, and layered by methanol. After 4-6 weeks, cubic crystals were harvested.
  • 16
    • 45749138146 scopus 로고    scopus 로고
    • 100 mg of CMM-5, 50 mg of thiourea, and 6 g of acetone/water (weight ratio = 2/1) were placed in a glass vial and stirred for 30 min. The vial was then sealed and heated at 85 °C for 3 weeks
    • The detailed synthesis for CMF-8 is as follows
    • The detailed synthesis for CMF-8 is as follows: 100 mg of CMM-5, 50 mg of thiourea, and 6 g of acetone/water (weight ratio = 2/1) were placed in a glass vial and stirred for 30 min. The vial was then sealed and heated at 85 °C for 3 weeks. After cooling to room temperature, the colorless crystals were collected and washed three times with methanol.
    • After cooling to room temperature, the colorless crystals were collected and washed three times with methanol
  • 17
    • 45749119706 scopus 로고    scopus 로고
    • Crystal data: CMM-5, Cd8(SPhF-3)14(DMF) 6(NO3, NO3, triclinic, space group P1, a, 14.8591(2) Å, b, 15.0112(2) Å, c, 15.6142(2) Å, a, 93.2690(10)°, β, 114.2920(10)°, γ, 103.7010(10)°, V, 3036.82(7) Å3, Z, 1, Mo Kα radiation, λ, 0.71073 Å, 2θmax, 50°, 38561 reflections collected, 10670 unique (Rint, 0.0185, final GOF, 1.039, R1, 0.0372, wR2, 0.1042, R indices based on 9948 reflections with I > 2σ(I, refinement on F 2, 603 parameters; CMF-8, Cd8S(SC6H 4F-3)14, trigonal, space group P3221, a, 18.3529(2) Å, c, 24.0908(4) Å, V, 7027.34(16) Å3, Z, 3, Mo Kα radiation, λ, 0.71073 Å, 2
    • 2), 573 parameters.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.