Phase diagram for solutions of α-helical poly(l-glutamate)s in m-cresol including isotropic, cholesteric, and columnar phases

Macromolecules

Volumn 41, Issue 10, 2008, Pages 3727-3733

  Yen, Chu Chun ^a,b   Edo, Susumu ^a   Oka, Hideki ^a   Tokita, Masatoshi ^a   Watanabe, Junji ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b FUDAN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHAIN LENGTH; CHEMICAL MODIFICATION; CLARIFICATION; CUBIC BORON NITRIDE; GRAPHIC METHODS; PHASE BOUNDARIES; PHASE DIAGRAMS; SET THEORY; SOLID SOLUTIONS; SOLUTIONS; TOPOLOGY; X RAY ANALYSIS;

AMERICAN CHEMICAL SOCIETY (ACS); CHOLESTERIC PHASE; COEXISTENCE REGION; COLUMNAR PHASE; COLUMNAR PHASES; CONCENTRATION (COMPOSITION); CONCENTRATION RANGES; CRITICAL CONCENTRATIONS; HEXAGONAL PACKING; HIGH TEMPERATURE (HT); HIGHER CONCENTRATIONS; ISOTROPIC PHASE; L GLUTAMATE; LATTICE THEORIES; LOW CONCENTRATIONS; LOW TEMPERATURE (LTR); LYOTROPIC SOLUTIONS; M CRESOL; MICROSCOPIC OBSERVATIONS; POLY(L GLUTAMATE); SIDE CHAINS; SOLID-STATE STRUCTURES; TEMPERATURE RANGES; THREE PHASES; TRANSITION (JEL CLASSIFICATIONS:E52 ,E41 ,E31); X RAY MEASUREMENTS;

PHASE BEHAVIOR;

EID: 45749090892     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma701971f     Document Type: Article

References (33)

1. Onsager, L. Ann. N.Y. Acad. Sci. 1949, 51, 627.
2. Flory, P. J. Proc. R. Soc. London 1956, A234, 60.
3. Parry, D. A. D.; Elliott, A. J. Mol. Biol. 1967, 25, 1.
4. Miller, W. G.; Wu, C. C.; Wee, E. L.; Santee, G. L.; Rai, J. H.; Goebel, K. G. Pure Appl. Chem. 1974, 38, 37.
5. Russo, P. S.; Miller, W. G. Macromolecules 1983, 16, 1690.
6. Russo, P. S.; Miller, W. G. Macromolecules 1984, 17, 1324.
7. Cohen, Y.; Dagan, A. Macromolecules 1995, 28, 7638.
8. (a) Hoshino, M.; Nakano, H.; Kimura, H. J. Phys. Soc. Jpn. 1979, 46, 1709.
9. (b) Hoshino, M.; Nakano, H.; Kimura, H. J. Phys. Soc. Jpn. 1979, 47, 740.
10. (c) Hoshino, M.; Nakano, H.; Kimura, H. J. Phys. Soc. Jpn. 1982, 51, 741.
11. Gray, G. W. Smectic Liquid Crystals; Leonard Hill: London, 1984.
12. Mulder, B. Phys. Rev. 1987, A53, 3095.
13. Kimura, H.; Tsuchiya, M. J. Phys. Soc. Jpn. 1990, 59, 3563.
14. Hentschke, R.; Hertfeld, J. Phys. Rev. 1991, A44, 1148.
15. Stroobants, A.; Lekkerkerker, H. N. W.; Frenkel, D. Phys. Rev. 1987, A36, 2929.
16. Frenkel, D. Mol. Phys. 1987, 60, 1.
17. Frenkel, D.; Lekkerkerker, H. N. W.; Stroobants, A. Nature 1988, 332, 822.
18. Bolhuis, P.; Frenkel, D. J. Chem. Phys. 1997, 106, 666.
19. Okoshi, K.; Kamee, H.; Suzaki, G.; Tokita, M.; Fujiki, M.; Watanabe, J. Macromolecules 2002, 35, 4556.
20. Sluckin, T. J. Liq. Cryst. 1989, 6, 111.
21. Stroobands, A. Phys. Rev. Lett. 1992, 69, 2388.
22. Bates, M. A.; Frenkel, D. J. Chem. Phys. 1998, 109, 6193.
23. Lee, S.; Meyer, R. B. Liq. Cryst. 1990, 7, 451.
24. Livolant, F.; Bouligand, Y. J. Phys. (Paris) 1986, 47, 1813.
25. Watanabe, J. Ordering in Macromolecular Systems; Teramoto, A., Kobayashi, M., Norisue, T., Eds.; Springer: Berlin, 1993; pp 99-113.
26. Watanabe, J.; Takashina, Y. Macromolecules 1991, 24, 3423.
27. Yu, S. M.; Coticello, V. P.; Zhang, G.; Kayser, C.; Fournier, M. J.; Manson, T. L.; Tirrell, D. A. Nature 1997, 389, 167.
28. Strzelecka, T. E.; Davidson, M. W.; Rill, R. L. Nature 1988, 331, 457.
29. Livolant, F.; Levelut, A. M.; Doucet, J.; Benoit, J. P. Nature 1989, 339, 724.
30. Wen, X.; Meyer, R. B.; Caspar, D. L. D. Phys. Rev. Lett. 1989, 63, 2760.
31. Doty, P.; Bradbury, J. H.; Holtzer, A. M. J. Am. Chem. Soc. 1956, 78, 947.
32. Such a phase transformation has also been detected by the pioneering X-ray studies by Luzzati et al.: Luzzati, V.; Cesari, M.; Spach, G.; Masson, F.; Vincent, J. M. J. Mol. Biol. 1961, 3, 566. Therein, the columnar phase is called the paracrystalline phase.
33. Watanabe, J.; Imai, K.; Gehani, R.; Uematsu, I. J. Polym. Sci., Polym. Phys. Ed. 1981, 19, 653.