Tandem palladium-catalyzed cyclocarbonylation of isolimonene: A mechanistic investigation and theoretical calculations on the fully diastereoselective step

European Journal of Inorganic Chemistry

Volumn , Issue 4, 2004, Pages 791-797

  Lenoble, Géraldine ^a   Lacaze Dufaure, Corinne ^b   Urrutigoïty, Martine ^a   Mijoule, Claude ^b   Kalck, Philippe ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

^b INSTITUT CARNOT CIRIMAT   (France)

Author keywords

Asymmetric induction; Cyclocarbonylation; Density functional calculations; Homogeneous catalysis; NMR spectroscopy; Palladium

Indexed keywords

CATALYSIS; CYCLIZATION; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM COMPOUNDS; TIN COMPOUNDS;

ASYMMETRIC INDUCTION; C-C BONDS; CYCLOCARBONYLATION; DENSITY-FUNCTIONAL CALCULATIONS; DIASTEREOMERIC EXCESS; HOMOGENEOUS CATALYSIS; MECHANISTICS; NMR-SPECTROSCOPY; PALLADIUM-CATALYZED; THEORETICAL CALCULATIONS;

DENSITY FUNCTIONAL THEORY;

4,8 DIMETHYLBICYCLO[4.3.0]NON 8 EN 2 ONE; CARBON; CYCLOPENTANONE DERIVATIVE; LIGAND; LIMONENE; PALLADIUM; PALLADIUM COMPLEX; PHOSPHORUS DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHIRALITY; CYCLIZATION; CYCLOCARBONYLATION; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; GEOMETRY; ISOMER; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; THEORETICAL STUDY;

EID: 4544373283     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300540     Document Type: Article

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