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Volumn , Issue 8, 2004, Pages 1714-1723

The ligating ability of functionalised diaminodimethylsilanes towards zirconium(IV)

Author keywords

Chelates; N,O ligands; NMR spectroscopy; Silanes; Zirconium

Indexed keywords

SILANES; X RAY CRYSTALLOGRAPHY; ZIRCONIUM COMPOUNDS;

EID: 4544370682     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300700     Document Type: Article
Times cited : (13)

References (47)
  • 23
    • 85153303993 scopus 로고    scopus 로고
    • note
    • 2(L), two coordination modes can be proposed, namely symmetric and asymmetric, and two isomers are postulable for the symmetric mode, namely cis and trans (vide infra).
  • 24
    • 85153191626 scopus 로고    scopus 로고
    • note
    • nX moieties. On the other hand, the two halves of the asymmetrically coordinated L should be nonequivalent.
  • 39
    • 85153223060 scopus 로고    scopus 로고
    • note
    • 13C), but at 193 K they yield two signals in agreement with the proposed molecular structure, suggesting exchange of the two methyl groups at room temperature.
  • 41
    • 85153259048 scopus 로고    scopus 로고
    • note
    • 2 π-bonding. Nevertheless, due to the similar nature of 15 and 17, this contribution is expected to be similar in the two complexes, thus making the above-mentioned steric factors decisive in influencing the exchange mechanism.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.