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2(L), two coordination modes can be proposed, namely symmetric and asymmetric, and two isomers are postulable for the symmetric mode, namely cis and trans (vide infra).
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85153191626
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note
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nX moieties. On the other hand, the two halves of the asymmetrically coordinated L should be nonequivalent.
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25
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13C), but at 193 K they yield two signals in agreement with the proposed molecular structure, suggesting exchange of the two methyl groups at room temperature.
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2 π-bonding. Nevertheless, due to the similar nature of 15 and 17, this contribution is expected to be similar in the two complexes, thus making the above-mentioned steric factors decisive in influencing the exchange mechanism.
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