Pressure-induced cis-to-trans isomerization of poly[(p-methylthiophenyl) acetylene] prepared with a [Rh(norbornadiene)Cl]2 catalyst - A Raman, UV-Vis, and ESR study

Macromolecular Chemistry and Physics

Volumn 205, Issue 6, 2004, Pages 762-770

  Huang, Kai ^a   Mawatari, Yasuteru ^a   Tabata, Masayoshi ^a   Sone, Takeyuki ^a   Miyasaka, Atsushi ^a   Sadahiro, Yoshikazu ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

cis to trans isomerization; Poly (p methylthiophenyl)acetylene ; Pressure; Rh complex catalyst; Stereospecific polymers

Indexed keywords

CATALYSTS; ISOMERIZATION; MACROMOLECULES; MOLECULAR WEIGHT; POLYMERIZATION; POLYMERS; SOLVENTS; STEREOCHEMISTRY; VACUUM;

CIS-TO-TRANS ISOMERIZATION; CIS-TRANSOID STRUCTURES; COCATALYSTS;

ACETYLENE;

ACETYLENE DERIVATIVE; NORBORNADIENE DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CIS TRANS ISOMERISM; COMPRESSION; ELECTRON SPIN RESONANCE; GEOMETRY; MOLECULAR WEIGHT; POLYMERIZATION; PRESSURE; RAMAN SPECTROMETRY; ROOM TEMPERATURE; SOLID STATE; STEREOSPECIFICITY; TEMPERATURE DEPENDENCE; ULTRAVIOLET SPECTROSCOPY;

EID: 4544361550     PISSN: 10221352     EISSN: None     Source Type: Journal    
DOI: 10.1002/macp.200300065     Document Type: Article

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