Crystal structure of [Rh(cacsm-κN,κS)(CO)(PPh 3)].CH3COCH3, (cacsm=methyl 2-(cyclohexylamino)-1-cyclopentene-1-dithiocarboxylate) and kinetics of iodomethane oxidative addition

South African Journal of Chemistry

Volumn 54, Issue , 2001, Pages 242-263

  Steyn, Gideon J J ^a   Roodt, Andreas ^a  

^a UNIVERSITY OF THE FREE STATE   (South Africa)

Author keywords

Crystal structure; Kinetics; Oxidative addition; Rhodium

Indexed keywords

ACETIC ACID ETHYL ESTER; ACETONE; CARBON; CARBOXYLIC ACID DERIVATIVE; CHLOROFORM; CYANOACRYLATE; HYDROGEN; METAL; METHANE; METHYL GROUP; OXYGEN; PHENYL GROUP; PHOSPHORUS; RHODIUM; SOLVENT;

ADDITION REACTION; ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; KINETICS; OXIDATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY ANALYSIS;

EID: 4544354542     PISSN: 03794350     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (35)

1. P. Maitlis, A. Haynes, G.A. Sunley and M.J. Howard, J. Chem. Soc., Dalton Trans, 1996, 2187.
2. W.A. Herrmann, Applied Homogeneous Catalysis with Organometallic Compounds (B. Cornils and W.A. Herrmann, eds.), VCH Weinheim, 1995.
3. G.J.J. Steyn, A. Roodt and J.G. Leipoldt, Inorg. Chem., 1992, 31, 3477.
4. A. Roodt and G.J.J. Steyn, Recent Research Developments in Inorganic Chemistry (S.G. Pandalai, ed), Transworld Research Network, Trivandrum. 2000, 2, pp. 1-23.
5. G.J.J. Steyn, A. Roodt and J.G. Leipoldt, Rhodium Express, 1993, 1, 25.
6. (a) B. Bordas, P. Sohar, G. Matolcsy and P. Berencsi, J. Org. Chem., 1972, 37, 1727;
7. (b) K. Nag and D.S. Joardar, Inorg. Chim. Acta, 1975, 14, 133.
8. -3.
9. SCIENTIST. Program for least-squares minimization. Micromath Inc., Utah, USA.
10. V.A. Streltsov and V.E. Zavodnik, Kristallographia, 1989, 34, 1369.
11. G. M. Sheldrick, SHELXS-86, Acta Cryst., 1990, A46, 467.
12. G.M. Sheldrick, SHELXL-97, Program for structure refinement, University of Göttingen, 1997.
13. G.J.J Steyn A. Roodt, A. Poletaeva and Y.S. Varshavsky, J. Organomet. Chem., 1997, 536/7, 797.
14. C.H. Langford and H.B. Gray, Ligand Substitution Processes, Benjamin, New York, 1965.
15. D.E. Graham, G.J. Lamprecht, I.M. Potgieter, A. Roodt and J.G. Leipoldt, Transition Met. Chem., 1991, 16, 193.
16. S.S. Basson, J.G. Leipoldt, W. Purcell, G.J. Lamprecht and H. Preston, Acta Cryst., 1992, C48, 167.
17. J.G. Leipoldt, G.J. Lamprecht and D.E. Graham, Inorg. Chim. Acta, 1985, 101, 123.
18. J.G. Leipoldt, S.S. Basson, E.C. Grobler and A. Roodt, Inorg. Chim. Acta, 1985, 99, 13.
19. J.G. Leipoldt, S.S. Basson and C.R. Dennis, Inorg. Chim. Acta, 1981, 50, 121.
20. K.G. van Aswegen, J.G. Leipoldt, I.M. Potgieter, G.J. Lamprecht, A. Roodt and G.J. van Zyl, Transition Met. Chem., 1991, 16, 369.
21. (a) L.J. Botha, S.S. Basson and J.G. Leipoldt, Inorg. Chim. Acta, 1987, 126, 25;
22. (b) A. Roodt, J.G. Leipoldt, J.C. Swarts and G.J.J. Steyn, Acta. Cryst., 1992, C48, 547;
23. (c) J.G. Leipoldt, S.S. Basson, L.D.C. Bok and T.I.A. Gerber, Inorg. Chim. Acta, 1978, 25, L35.
24. J.G. Leipoldt, S.S. Basson and L.J. Botha, Inorg. Chim. Acta, 1990, 168, 215.
25. Comprehensive Coordination Chemistry (G. Wilkinson, ed.), Pergamon Press, New York, 1987.
26. G. Kemp, W. Purcell and A. Roodt, Rhodium Express, 1996, 16, 17.
27. S. Otto, A. Roodt, J.J.C. Erasmus and J.C. Swarts, Polyhedron, 1998, 17, 2447.
28. (a) A.M. Treciak and J.J. Ziolkowski, Inorg. Chim. Acta, 1985, 96, 15;
29. (b) W. Purcell, S.S Basson, J.G. Leipoldt, A. Roodt and H. Preston, Inorg. Chim. Acta, 1995, 234, 153;
30. (c) T.G. Cherkasova, M.R. Galding, L.V. Osetrova and Y.S. Varshavsky, Rhodium Express 1994, 3, 17;
31. (d) I.A. Poletaeva, T.G. Cherkasova, L.V. Osetrova, Y.S. Varshavsky, A. Roodt and J.G. Leipoldt, Rhodium Express 1994, 3, 21.
32. C.A. Tolman, Chem. Rev. 1977, 77, 313.
33. J.A. Venter, J.G. Leipoldt and R. van Eldik, Inorg. Chem. 1991, 30, 2209.
34. (a) M. Sandström, I. Persson and P. Persson, Acta Chem. Scand. 1990, 44, 653;
35. (b) J. Rydberg, Principles and practices of solvent extraction (J. Rydberg, C. Musikas and G.R. Choppin, eds.), Marcel Dekker, New York, 1992, p. 23.