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note
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Based on considerations of symmetry, a feature required to realize biaxial phases is molecular biaxiality. This could be due to the molecules having biaxial correlations or to their shape biaxiality. Here we consider only the latter.
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Several monodispersive cyclic compounds formed by combining a banana-shaped unit and a rodlike moiety have been reported to form uniaxial nematic and smectic mesophases: A. Godt, S. Duda, O. Unsal, J. Thiel, A. Harter, M. Roos, C. Tschierske, S. Diele, Chem. Eur. J. 2002, 8, 5094.
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