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Volumn 43, Issue 28, 2004, Pages 3728-3731

Thermally induced electron transfer in a CsCoFe Prussian blue derivative: The specific role of the alkali-metal ion

Author keywords

Electron transfer; Prussian blue analogues; Spin crossover; X ray absorption spectroscopy; X ray diffraction

Indexed keywords

ALKALI METALS; CESIUM COMPOUNDS; DERIVATIVES; ELECTRONS; POSITIVE IONS; THERMAL EFFECTS;

EID: 4544320880     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460086     Document Type: Article
Times cited : (92)

References (24)
  • 16
    • 85083120062 scopus 로고    scopus 로고
    • note
    • The C-N distance in the CN bridge calculated from the calculated coordinates is 1.2(1) Å at 300 K and 1.1(1) Å at 20 K, and thus of the expected order of magnitude (1.14 Å).
  • 20
    • 85083142879 scopus 로고    scopus 로고
    • note
    • III-NC-Fe entity, the calculated EXAFS signal is completely different from the experimental one.
  • 21
    • 85083147521 scopus 로고    scopus 로고
    • note
    • The number of Co atoms per unit cell surrounding one Td site is (1 + 3/4). As the Cs ions are diluted in the structure (0.7 per unit cell), the number of Co atoms surrounding one Cs ion is given by 0.7 × (1 + 3/4), which corresponds to 30% of the Co ions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.