Modeling of ethylene polymerization kinetics over supported chromium oxide catalysts

Macromolecular Theory and Simulations

Volumn 13, Issue 2, 2004, Pages 169-177

  Choi, Kyu Yong ^a   Tang, Shihua ^a   Yoon, Won Jung ^a,b  

^a UNIVERSITY OF MARYLAND   (United States)

^b Gachon University   (South Korea)

Author keywords

Catalysts; Ethylene polymerization; Kinetic model; Modeling; Multi site model

Indexed keywords

CATALYSIS; MOLECULAR WEIGHT; POLYETHYLENES; POLYMERIZATION; RATE CONSTANTS; SILICA;

CHROMIUM SITES; DIVALENT SITES; INDUCTION PERIOD; POLYMERIZATION KINETICS;

MACROMOLECULES;

CHROMIUM; ETHYLENE; MONOMER; POLYETHYLENE;

ARTICLE; CATALYSIS; CATALYST; EXPERIMENT; KINETICS; LIQUID; MOLECULAR WEIGHT; POLYMERIZATION; QUANTITATIVE ANALYSIS; REACTION ANALYSIS;

EID: 4544316562     PISSN: 10221344     EISSN: None     Source Type: Journal    
DOI: 10.1002/mats.200300017     Document Type: Article

References (11)

1. M. P. McDaniel, Ind. Eng. Chem. Res. 1988, 27, 1559.
2. D. L. Embry, Modeling Phillips polyolefins process with Polymers Plus™, Paper presented at the AspenWorld97 Conference, Boston, MA, 1997.
3. M. P. McDaniel, Adv. Catal. 1985, 33, 47.
4. M. P. McDaniel, M. M. Johnson, J. Catal. 1986, 101, 446.
5. T. Servais (Solvay s.A.), personal communication, 1996.
6. M. P. McDaniel, M. B. Welch, J. Catal. 1983, 82, 98.
7. P. C. Thüne, J. Loos, A. M. de Jong, P. J. Lemstra, J. W. Niemantsverdriet, Top. Catal. 2000, 13, 67.
8. P. C. Thüne, C. P. J. Verhagen, M. J. G. van den Boer, J. W. Niemantsverdriet, J. Phys. Chem. B 1997, 101, 8559.
9. R. Merryfield, M. McDaniel, G. Parks, J. Catal. 1982, 77, 348.
10. M. P. McDaniel, S. J. Martin, J. Phys. Chem. 1991, 95, 3289.
11. J. B. P. Soares, A. E. Hamielec, Polymer 1995, 36, 2257.