REE3+ and Mn2+ activated cathodoluminescence in lateglacial and Holocene stalagmites of central Europe: Evidence for climatic processes?

Holocene

Volumn 14, Issue 5, 2004, Pages 759-767

  Richter, Detlev K ^a   Götte, Thomas ^a   Niggemann, Stefan ^a   Wurth, Georg ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Cathodoluminescence; Central Europe; Holocene; Lateglacial; Manganese; Mn; Palaeoclimate; Rare earth elements; REE; Stalagmites

Indexed keywords

CATHODOLUMINESCENCE; HOLOCENE; LATE GLACIAL; MANGANESE; PALEOCLIMATE; RARE EARTH ELEMENT; STALAGMITE;

EURASIA; EUROPE;

LAMIINAE;

EID: 4544272689     PISSN: 09596836     EISSN: None     Source Type: Journal    
DOI: 10.1191/0959683604hl754rp     Document Type: Article

References (61)

1. Ayliffe, L.K., Marianelli, P.C., Moriarty, K.C., Wells, R.T., McCulloch, M.T., Mortimer, G.E. and Hellstom, J.C. 1998. 500ka precipitation record from southeastern Australia: evidence for interglacial relative aridity. Geology 26, 147-50.
2. Baker, A., Genty, D., Dreybrodt, W., Barnes, W.L., Mockler, N.J. and Grapes, J. 1998: Testing theoretically predicted stalagmite growth rate with recent annually laminated samples: implications for past stalagmite deposition. Geochimica Cosmochimica Acta 62, 393-404.
3. Baker, A., Smart, P.L. and Ford, D.C. 1993a: Northwest European paleoclimate as indicated by growth frequency variations of secondary calcite deposits. Palaeogeography Palaeoclimatology Palaeoecology 100, 291-301.
4. Baker, A., Smart, P.L., Lawrence Edwards, R. and Richards, D.A. 1993b: Annual growth banding in a cave stalagmite. Nature 364, 518-20.
5. Banner, J.L., Musgrove, M., Asmerom, Y., Edwards, R.L. and Hoff, J.A. 1996: High-resolution temporal record of Holocene ground-water chemistry: tracing link between climate and hydrology. Geology 24, 1049-53.
6. Bar-Matthews, M., Ayalon, A. and Kaufman, A. 1998: palaeoclimate evolution in the eastern Mediterranean region during the last 58000yr as derived from stable isotopes of speleothems (Soreq Cave, Israel). In Murphy, P., editor, Proceedings of the International Symposium on Isotope Techniques in the Study of Past and Current Environmental Changes in the Hydrosphere and the Atmosphere, Vienna: International Atomic Energy Agency, IAEA-SM-349/17, 673-82.
7. Bar-Matthews, M., Matthews, A. and Ayalon, A. 1991: Environmental controls of speleothem mineralogy in a karstic dolomitic terrain (Soreq Cave, Israel). Journal of Geology 99, 189-207.
8. Bhalla, R.J.R.S.B. and White, E.W. 1971: Intrinsic cathodoluminescence emission from willemite single crystals. Journal of Luminescence 4, 2267-68.
9. Burns, S.J., Matter, A., Frank, N. and Mangini, A. 1998: Speleothem-based palaeoclimate record from northern Oman. Geology 26, 499-502.
10. Caspers, G., Freund, H., Kleinmann, A. and Merkt, J. 1999: Das Klima im Quartär. In Boetzkes, M., Schweitzer, I. and Vespermann, J., editors, Eiszeit-Das große Abenteuer der Naturbeherrschung, Stuttgart: Thortfecke, 78-94.
11. Emeis, K.-C. and Kempe, S. 1986: Speleothems of the Winterberg and Quaternary climate of the Harz Mountains. Proceedings of the 9th Internatinal Congress of Speleology 1, 281-4.
12. Falk, F., Hahne, K. and Lützner, H. 2000: Der Beginn siliziklastischer Sedimentation im Altpaläozoikum des Saxothuringikums: Sedimentologie und Geochemie des Richtprofils Goldisthal (Thüringisches Schiefergebirge). Zeitschrift der deutschen geologischen Gesellschaft 151, 365-414.
13. Fleet, A.J. 1984: Aqueous and sedimentary geochemistry of rare earth elements. In Henderson, J., editor, Rare earth element geochemistry, Amsterdam: Elsevier, 343-73.
14. Frank, N., Braun, M., Hambach, U., Mangini, A. and Wagner, A. 2000: Warm period growth of travertin during the last interglaciation in southern Germany. Quaternary Research 54, 38-48.
15. Frisia, S., Borsato, A., Fairchild, I.J. and McDermott, F. 2000: Calcite fabrics, growth mechanisms and environments of formation in speleothems from the Italian Alps and southwestern Ireland. Journal of Sedimentary Research 70, 1183-96.
16. Füchtbauer, H. and Richter, D.K. 1988: Karbonatgesteine. In Füchtbauer, H., editor, Sedimente und Sedimentgesteine Teil II, Stuttgart: Schweizerbart, 233-434.
17. Gascoyne, M. 1992: paleoclimate determination from cave calcite deposits. Quaternary Science Reviews 11, 609-32.
18. Genty, D. and Quinif, Y. 1996: Annually laminated sequences in the internal structure of some Belgian stalagmites-importance for paleoclimatology. Journal of Sedimentary Research 66, 275-88.
19. Genty, D., Baker, A. and Barnes, W. 1997: Comparaison entre les lamines luminescentes et les lamines visibles annuelles de stalagmites. Compte Rendu de Académic des Science Paris, Sciences de la terre et des planètes 320, 193-200.
20. Genty, D., Deflandre, G., Quinif, Y. and Verheyden, S. 1999: Les lamines de croissance des speleothemes: origine et interet paleoclimatique. Bulletin de la Societé Geologique de Belgique 106, 63-77.
21. 14C-Daten von Kalksinter und organischen Substanzen. Geologisches Jahrbuch Beihefte 98, 15-22.
22. Geyh, M.A., Reiff, W. and Frank, N. 1999: Grenzen der radiometrischen 230 Th/U-Altersbestimmung der Sauerwasserkalkvorkommen (Travertine) in Stuttgart. Zeitschrift der deutschen geologischen Gesellschaft 150, 703-33.
23. Goede, A. and Vogel, J.C. 1991: Trace element variations and dating of a Late Pleistocene Tasmanian speleothem. Paleogeography Paleoclimatology Paleoecology 88, 121-31.
24. Goede, A., McCulloch, M., McDermott, F. and Hawkesworth, C. 1998: Aeolian contribution to strontium and strontium isotope variations in a Tasmanian speleothem. Chemical Geology 149, 37-50.
25. Götze, J., Habermann, D., Neuser, R.D. and Richter, D.K. 1999: High-resolution spectrometric analysis of rare earth elements-activated cathodoluminescence in feldspar minerals. Chemical Geology 153, 81-91.
26. Gradzinski, M. 2000: Climate changes - the Karst record II, guidebook and abstracts. Cracow: Institute of Geological Sciences, Jagiellonian University, 108 pp.
27. Habermann, D., Götze, J., Neuser, R.D. and Richter, D.K. 1999a: The phenomenon of intrinsic cathodoluminescence: case studies of quartz, calcite and apatite. Zentralblatt für Geologie und Paläontontologie Teil I 1997, 1275-84.
28. Habermann, D., Meijer, J., Neuser, R.D., Richter, D.K., Rolfs, C. and Stephan, A. 1999b: Micro-PIXE and quantitative cathodoluminescence spectroscopy: combined high resolution trace element analyses in minerals. Nuclear Instruments and Methods in Physics Research B150, 470-77.
29. Habermann, D., Neuser, R.D. and Richter, D.K. 1996: REE-activated cathodoluminescence of calcite and dolomite: high resolution spectrometric analysis of CL emission (HRS-CL). Sedimentary Geology 101, 1-7.
30. 2+ activated cathodoluminescence of calcite: state of the art. Sedimentary Geology 116, 13-24.
31. Jones, B. 2000: Microbial sediments in tropical karst terrains: a model based on Cayman Islands. In Riding, R.E. and Awramik, S.M., editors, Microbial sediments, Berlin-Heidelberg: Springer Verlag, 171-78.
32. Lauritzen, S.-E., editor 1996: Climate change: the Karst record, Karst Waters Institute special publications. Charles Town: Karst Water Institute, 196 pp.
33. Lauritzen, S.E. and Lundberg, J. 1999: Speleothems and climate. The Holocene 9, 643-722.
34. Maire, R. 1990: La haute montagne calcaire. Karsts, cavites, remplissages quaternaire, paléoclimats. Mémoires 3, 1-725.
35. Mann, M.E., Bradley, R.S. and Hughes, M.K. 1998: Global-scale temperature patterns and climate forcing over the past six centuries. Nature 392, 779-87.
36. Marshall, D.J. 1988: Cathodoluminescence in geosciences. Boston: Unwin Hyman, 146 pp.
37. Mason, R.A. and Mariano, A.N. 1990: Cathodoluminescence activation in manganese bearing and rare earth bearing synthetic calcites. Chemical Geology 88, 191-260.
38. 18O, textural and extension-rate variations in three speleothems. Quaternary Science Reviews 18, 1021-38.
39. McGarry, S. and Baker, A. 2000: Organic acid fluorescence: applications to speleothem palaeoenvironmental reconstruction. Quaternary Science Reviews 19, 1087-101.
40. McLennan, S.M. 1989: Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. In Lipin, B.R. and McKay, G.A., editors, Geochemistry and mineralogy of rare earth elements, Reviews in Mineralogy 21, 168-200.
41. Mergner, W., Brix, M.R., Hagemann, P., Oelze, R. and Richter, D.K. 1992: Sinterbecken im Malachitdom mit wasserspiegelparallelen Karbonatkrusten. In Geologisches Landesamt NRW, editor, Der Malachitdom. Ein Beispiel interdisziplinärer Höhlenforschung im Sauerland, Krefeld: Geologisches Landesamt Von Nordhein-Westfalen, 151-73.
42. Miotke, F.D. 1974: Carbon dioxide and the soil atmosphere. Abhandlungen zur Karst- und Höhlenkunde Reihe A9, 1-49.
43. Neuser, R.D. 1995: A new high-intensity cathodoluminescence microscope and its application to weakly luminescing minerals. Bochumer geologische und geotechnische Arbeiten 44, 116-18.
44. Neuser, R.D., Bruhn, F., Götze, J., Habermann, D. and Richter, D.K. 1996: Kathodolumineszenz: Methodik und Anwendung. Zentralblatt für Geologie und Paläontologie Teil I 1995, 287-306.
45. Niggemann, S. 2000: Klimabezogene Untersuchungen an spät- bis postglazialen Stalagmiten aus Massenkalkhöhlen des Sauerlandes. In Richter, D.K. and Wurth, G., editors, Beiträge zur Speleologie I, Bochumer geologische und geotechnische Arbeiten 55, 5-129.
46. Niggemann, S., Frank, N., Mangini, A., Richter, D.K. and Wurth, G. 2000: Holozäne Stalagmiten des Sauerlandes (Deutschland) als Klimaarchive. Mitteilungen des Verbandes der deutschen Höhlen- und Karstforscher 46, 84-90.
47. Niggemann, S., Mangini, A., Richter, D.K. and Wurth, G. 2003: A palaeoclimate record of the last 17600 years in stalagmites from the B7-Cave, Sauerland, Germany. Quaternary Science Reviews 22, 557-69.
48. Niggemann, S., Richter, D.K. and Wurth, G. 1999: Graue Sinter in Besucherhöhlen des Sauerlandes. Terra Nostra 99, 186-88.
49. Railsback, L.B., Brook, G.A., Chen, J., Kalin, R. and Fleisher, C.J. 1994: Environmental controls on the petrology of a Late Holocene speleothem from Botswana with annual layers of aragonite and calcite. Journal of Sedimentary Research A64, 147-55.
50. Richter, D.K., Götte, Th., Götze, J. and Neuser, R.D. 2003: Progress and application of cathodoluminescence in sedimentary petrology. Mineralogy and Petrology 79, 127-66.
51. Richter, D.K., Götte, Th., Niggemann, S. and Wurth, G. 2002: Cathodoluminescence of carbonate speleothems: state of the art. In Carrasco, F., Duran, J.J. and Andreo, B., editors, Karst and environment, Malaga: Fundación Cueva de Nerja, 381-87.
52. Richter, D.K., Habermann, D., Neuser, R.D. and Oelze, R. 1995: Kathodolumineszenz-Untersuchungen an Höhlensintern des nördlichen Sauerlandes. Späleologisches Jahrbuch Verein für Höhlenkunde in Westfalen 11, 33-7.
53. Roberts, M.S., Smart, P.L., Hawkesworth, C.J., Perkins, W.T. and Pearce, N.J.G. 1999: Trace element variations in coeval Holocene speleothems from GB Cave, southwest England. The Holocene 9, 707-13.
54. Schönwiese, C.D. 1995: Klimaänderungen. Daten. Analysen, Prognosen. Berlin/Heidelberg: Springer Verlag.
55. Sippel, R.F. and Spencer, A.B. 1970: Luminescence petrography and properties of lunar crystalline rocks and breccias. In Levison, A.A., editor, Proceedings of Apollo II Lunar Science Conference, vol. 3, Geochimica Cosmochimica Acta Supplement 1, 2413-26.
56. Stolz, J.F. 2000: Structure of microbial mats and biofilms. In Riding, R.E. and Awramik, S.M., editors, Microbial sediments, Berlin-Heidelberg: Springer Verlag, 1-8.
57. Wiesenfeld, K. and Moss, F. 1995: Stochastic resonance and the benefits of noise: from ice age to cray-fish and SQUIDs. Nature 373, 33-36.
58. Winograd, I.J., Coplen, T.B., Landwehr, J.M., Riggs, A.C., Ludwig, K.R., Szabo, B.J., Kolesar, P.T. and Revesz, K.M. 1992: Continuous 500,000-year climate record from vein calcite in Devil's Hole, Nevada. Science 258, 255-60.
59. Wurth, G. 2002: Klimagesteuerte Rhythmik in spät- bis postglazialen Stalagmiten des Sauerlandes, der Fränkischen Alb und der Bayrischen Alpen. PhD thesis, Ruhr-University Bochum, Bochum.
60. Wurth, G., Niggemann, S. and Richter, S. 2000: Der hierarchische Aufbau des Laminationsgefüges eines spät/postglazialen Kerzenstalagmiten aus der Zoolithenhöhle bei Burggaillenreuth (Fränkische Schweiz). In Richter, D.K. and Wurth, G., editors, Beiträge zur Speläologie I, Bochumer geologische und geotechnische Arbeiten 55, 131-51.
61. Zhengtang, G., Shuzhen, P. and Tungshen, L. 2001: Millennial-scale oscillations of loess weathering over the last glacial period. Past Global Changes Newsletter 9(2), 9.