Sulphamic acid - An efficient and cost-effective solid acid catalyst for the pechmann reaction

Synlett

Volumn , Issue 11, 2004, Pages 1909-1912

  Singh, Pankajkumar R ^a   Singh, Devendrapratap U ^a   Samant, Shriniwas D ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Coumarins; Pechmann reaction; Sulphamic acid

Indexed keywords

ACID; COUMARIN; ESTER DERIVATIVE; SOLVENT; SULFAMIC ACID; UNCLASSIFIED DRUG;

ARTICLE; BECKMANN REARRANGEMENT; CATALYSIS; CATALYST; CHEMICAL REACTION; COST EFFECTIVENESS ANALYSIS; ESTERIFICATION; NEUTRON DIFFRACTION; PECHMANN REACTION; X RAY;

EID: 4544253640     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-830858     Document Type: Article

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39. Typical Experimental Procedure: To the weighed quantity of phenol (10 mmol), and β-keto ester (10 mmol), the sulphamic acid (5 mmol) was added and the reaction mixture was stirred at 130°C in a pre-heated oil-bath. After completion of the reaction at the desired time as indicated in Table 1, the reaction mixture was poured into water and the resultant product was filtered. The products were further purified by column chromatography. The compounds are well known and in agreement with spectral and physical data.