Ethanol decomposition: C-C cleavage selectivity on Rh(111)

ChemPhysChem

Volumn 5, Issue 8, 2004, Pages 1133-1140

  Vesselli, Erik ^a,b   Baraldi, Alessandro ^a,b   Comelli, Giovanni ^a,b   Lizzit, Silvano ^c   Rosei, Renzo ^a,b  

^a LABORATORIO TASC   (Italy)

^b UNIVERSITY OF TRIESTE   (Italy)

^c SINCROTRONE TRIESTE   (Italy)

Author keywords

Alcohols; Hydrogen; Reaction mechanisms; Spectroscopy; Surface chemistry; X ray absorption

Indexed keywords

ADSORPTION; ALCOHOLS; CARBON MONOXIDE; CHEMICAL BONDS; DISSOCIATION; ETHANOL; HYDROGEN; RHODIUM COMPOUNDS; SPECTROSCOPY; SURFACE CHEMISTRY; TEMPERATURE PROGRAMMED DESORPTION; X RAY ABSORPTION; X RAY PHOTOELECTRON SPECTROSCOPY;

ADSORPTION ENERGIES; DISSOCIATION BARRIER; DISSOCIATION CHANNELS; ETHANOL DECOMPOSITION; MULTILAYER FORMATION; QUADRATIC EXPONENT POTENTIALS; REACTION MECHANISM; SURFACE TEMPERATURES;

CORE LEVELS;

ALCOHOL; ALCOHOL DERIVATIVE; CARBON; CARBON MONOXIDE; HYDROGEN; RHENIUM; RHENIUM 111; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; DECOMPOSITION; DESORPTION; DISSOCIATION; ENERGY; REACTION ANALYSIS; SURFACE PROPERTY; TEMPERATURE; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 4544225690     PISSN: 14394235     EISSN: None     Source Type: Journal    
DOI: 10.1002/cphc.200400043     Document Type: Article

References (51)

1. V. Louz, V. Fierro, P. Denton, H. Katz, J. P. Lisse, S. Bouvot-Mauduit, C. Mirodatos, J. Power Sources 2002, 105, 26.
2. R. D. Cortright, R. R. Davda, J. A. Dumesic, Nature 2002, 418, 964.
3. S. Freni, J. Power Sources 2001, 94, 14.
4. S. Cavallaro, S. Freni, Int. J. Hydrogen Energy 1996, 21, 465.
5. F. Gonçalves, P. R. S. Medeiros, J. G. Eon, L. Appel, Appl. Catal., A 2000, 193, 195.
6. W. Wang, Z. Wang, Y. Ding, J. Xi, G. Ly, Catal. Lett. 2002, 81, 63.
7. S. Freni, S. Cavallaro, N. Mondello, L. Spadaio, F. Frusteri, J. Power Sources 2002, 108, 53.
8. G. Maggio, S. Freni, S. Cavallaro, J. Power Sources 1998, 74, 17.
9. R. Alcalá, M. Mavrikakis, J. A. Dumesic, J. Catal. 2003, 218, 178.
10. M. Bowker, R. P. Holroyd, R. G. Scharpe, J. S. Corneille, S. M. Francis, D. W. Goodman, Surf. Sci. 1997, 370, 113.
11. M.K. Rajumon, M. W. Roberts, F. Wang, P. B. Wells, J. Chem. Soc. Faraday Trans. 1998, 94, 3699.
12. J. Xu, X. Zhang, R. Zenobi, J. Yoshinobu, Z. Xu, J. T. Yates Jr., Surf. Sci. 1991, 256, 288.
13. T. Kratchowil, M. Wittmann, J. Küppers, J. Electron Spectrosc. Relat. Phenom. 1993, 64/65, 609.
14. M. Carbone, M. N. Piancastelli, J. J. Paggel, C. Weindel, K. Horn, Surf. Sci. 1998, 412/413, 441.
15. M. P. Casaletto, R. Zanoni, M. Carbone, M. N. Piancastelli, L. Aballe, K. Weiss, K. Horn, Surf. Sci. 2000, 447, 237.
16. R. P. Holroyd, R. A. Bennett, I. Z. Jones, M. Bowker, J. Chem. Phys. 1999, 110, 8703.
17. K. Siegbahn, C. Nordling, A. Fahlman, R. Nordberg, K. Hamrin, J. Hedman, G. Johansson, T. Bergmark, S. E. Karlsson, I. Lindgren, B. Lindberg, ESCA: Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy, Almqvist & Wiksells, Uppsala, 1967, 20.
18. K. Siegbahn, C. Nordling, G. Johansson, J. Hedman, P. F. Heden, K. Hamrin, U. Gelius, T. Bergmark, L. Werme, R. Manne, Y. Baer, ESCA: Applied to Free Molecules, North Holland Publishing Company, Amsterdam, 1969.
19. Y. Cong, V. van Spaendonk, R. I. Masel, Surf. Sci. 1997, 385, 246.
20. A. F. Lee, D. E. Gawthrope, N. J. Hart, K. Wilson, Surf. Sci. 2004, 548, 200.
21. C. J. Houtman, M. A. Barteau, J. Catal. 1991, 130, 528.
22. Z. J. Tian, X. M. Wei, R. S. Zhai, S. Z. Ren, D. B. Liang, L. W. Lin, Chem. J. Chin. Univ. 1997, 7, 1153.
23. D. C. Papageorgopoulos, D. A. King, J. Phys. Chem. 1995, 99, 17 645.
24. J. T. Yates, P. A. Thiel, W. H. Weinberg, Surf. Sci. 1979, 84 427.
25. S. Doniach, M. Sunjic, J. Phys. C 1970, 3, 185.
26. R. Larciprete, A. Goldoni, A. Groso, S. Lizzit, G. Paolucci, Surf. Sci. 2001, 482-485, 134.
27. J. A. Lloyd, W. L. Manner, M. T. Paffett, Surf. Sci. 1999, 423, 265.
28. M. Wiklund, A. Beutler, R. Nyholm, J. N. Andersen, Surf. Sci. 2000, 461, 107.
29. A. Baraldi, G. Comelli, S. Lizzit, D. Cocco, G. Paolucci, R. Rosel, Surf. Sci. 1996, 367, L67.
30. M. Smedh, A. Beutler, M. Borg, R. Nyholm, J. N. Andersen, Surf. Sci. 2001, 491, 115
31. A. Beutler, E. Lundgren, R. Nyholm, J. N. Andersen, B. Setlik, D. Heskett, Surf. Sci. 1997, 371, 381.
32. E. Lundgren, X. Torrelles, J. Alvarez, S. Ferrer, H. Over, A. Beutler, J.N. Andersen, Phys. Rev. B 1999, 59, 5876.
33. M. Smedh, A. Beutler, M. Borg, R. Nyholm, J. N. Andersen, Surf. Sci. 2001, 491, 115.
34. M. Birgersson, C. O. Almbladh, M. Borg, J. N. Andersen, Phys. Rev. B 2003, 67, 045402.
35. T. Kecskés, R. Barthos, J. Rasḱo, J. Kiss, Vacuum 2003, 71, 107.
36. J. Kiss, A. Kis, F. Solymosi, Surf. Sci. 2000, 454, 273.
37. F. Solymosi, G. Klivènyi, J. Electron Spectrosc. Relat. Phenom. 1993, 64/65, 499.
38. R. Shekhar, M. A. Barteau, Catal. Lett. 1995, 31, 221.
39. B. S. Bunnik, G. J. Kramer, Methane activation and the rhodium surface (Conference Poster), 14th Interdisciplinary Surface Science Conference, Liverpool, United Kingdom, 2003.
40. C. Houtman, M. A. Barteau, Surf. Sci. 1991, 248, 57.
41. T. R. Bryden, S. Garrett, J. Phys. Chem. B 1999, 103, 10481.
42. A. Baraldi, G. Comelli, S. Lizzit, M. Kiskinova, G. Paolucci, Surf. Sci. Rep. 2003, 49, 169.
43. A. Baraldi, M. Barnaba, B. Brena, D. Cocco, G. Comelli, S. Lizzit, G. Paolucci, R. Rosei, J. Electron Spectrosc. Relat. Phenom. 1995, 76, 145.
44. A. Baraldi, V. R. Dhanak, J. Electron Spectrosc. Relat. Phenom. 1994, 67, 211.
45. L. Gori, R. Tommasini, G. Cautero, D. Giuressi, M. Barnaba, A. Accardo, S. Carrato, G. Paolucci, Nucl. Instrum. Methods Phys. Res. Sect A 1999, 431, 338.
46. E. Shustorovich, Surf. Sci. Rep. 1986, 6, 1.
47. E. Shustorovich, H. Sellers, Surf. Sci. Rep. 1998, 31, 1.
48. M. Mavrikakis, J. Rempel, J. Greeley, L. B. Hansen, J. Nørskov, J. Chem. Phys. 2002, 117, 6737.
49. C. Tohg Au, M. S. Liao, C. F. Ng, Chem. Phys. Lett. 1997, 267, 44.
50. P. P. Olivera, E. M. Patrito, H. Sellers, Surf. Sci. 1995, 327, 330.
51. J. March, Advanced Organic Chemistry: Reactions, Mechanisms and Structure, 3rd ed., John Wiley & Sons, New York, 1985.