Diamide derivatives of dipicolinic acid as actinide and lanthanide extractants in a variation of the UNEX process

GLOBAL 2007: Advanced Nuclear Fuel Cycles and Systems

Volumn , Issue , 2007, Pages 1106-1110

  Peterman, D R ^a   Herbst, R S ^a   Law, J D ^a   Tillotson, R D ^a   Garn, T G ^a   Todd, T A ^a   Romanovskiy, V N ^b   Babain, V A ^b   Alyapyshev, M Yu ^b   Smirnov, I V ^b  

^a IDAHO NATIONAL LABORATORY   (United States)

^b KHLOPIN RADIUM INSTITUTE   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

(E ,3E) PROCESS; ACIDIC SOLUTIONS; ACTINIDE; CHLORINATED COBALT DICARBOLLIDE (CCD); DIAMIDE; DIPICOLINIC ACID (DPA); EXTRACTANTS; LANTHANIDE(III); NUCLEAR-FUEL CYCLES; SIMULTANEOUS EXTRACTION;

ACTINIDES; ALKALI METALS; ALKALINE EARTH METALS; CESIUM; COBALT; ETHYLENE GLYCOL; EXTRACTION; FUELS; GLYCOLS; NUCLEAR ENERGY; NUCLEAR ENGINEERING; NUCLEAR FUELS; ORGANIC ACIDS; POLYETHYLENE GLYCOLS; RARE EARTH ELEMENTS; SOLUTIONS; SOLVENT EXTRACTION; STRONTIUM; TRANSITION METALS;

CHEMICAL MODIFICATION;

EID: 45149116041     PISSN: None     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (15)

1. J. Rais, S. Tachimori, "Extraction of Europium and Americium by a Mixture of CMPO and Dicarbollide," J. Radioanal. Nucl. Chem. Lett. 1994, 188, 157-162.
2. J. Rais, S. Tachimori, P. Selucky, L. Kadlecova, "Synergetic Extraction in Systems with Dicarbollide and Bidentate Phosphonate," Sep. Sci. Technol. 1994, 29, 261-274.
3. J. D. Law, R. S. Herbst, D. R. Peterman, R. D. Tillotson, and T. A. Todd, "Development of a Cobalt Dicarbollide/Polyethylene Glycol Solvent Extraction Process for Separation of Cesium and Strontium to Support Advanced Aqueous Reprocessing," proceedings of Global 2003, New Orleans, LA, November 2003.
4. B.N. Zaitsev, V.M. Esimantovskiy, L.N. Lazarev, E.G. Dzekun, V.N. Romanovskiy, T.A. Todd, K. N. Brewer, R.S. Herbst, J.D. Law, US. Patent 6270737, August 2001.
5. J. D. Law, R. S. Herbst, T. A. Todd, D. J. Wood, V. N. Romanovskiy, V. M. Esimantovskiy, I. V. Smimov, V. A. Babain, B. N. Zaitsev, "Demonstration of a Universal Solvent Extraction Process for the Separation of Actinides, Cesium and Strontium from Actual Acidic Tank Waste at the INEEL," proceedings of the International Conference on Future Nuclear Systems- Global '99, Jackson, Wyoming, August 29-September 3, 1999.
6. V.N. Romanovskiy, I.V. Smimov, V.A. Babain, T.A. Todd, J.D. Law, R.S. Herbst, K.N. Brewer, "The Universal Solvent Extraction (UNEX) Process. I. Development of the UNEX Process Solvent for the Separation of Cesium, Strontium, and the Actinides From Acidic Radioactive Waste," Sol. Extr. Ion Exch. 2001, 19, 1-21.
7. J.D. Law, R. S. Herbst, T.A. Todd, V.N. Romanovskiy, V.A. Babain, V.M. Esimantovskiy, I.V. Smimov, B.N. Zaitsev, "The Universal Solvent Extraction (UNEX) Process. II. Flowsheet Development and Demonstration of the UNEX Process for the Separation of Cesium, Strontium, and the Actinides From Actual Acidic Radioactive Waste," Sol. Extr. Ion Exch. 2001, 19, 23-36.
8. R.S. Herbst, J.D. Law, T.A. Todd, V.N. Romanovskiy, I.V. Smimov, V.A. Babain, V.M. Esimantovskiy, B.N. Zaitsev, "Development of the Universal Extraction (UNEX) Process for the Simultaneous Recovery of Cesium, Strontium and Actinides from Acidic Radioactive Wastes," Sep. Sci. Technol. 2003, 38, 2685-2708.
9. T.A. Todd, J.D. Law, R.S. Herbst, V.N. Romanovskiy, I.V. Smimov, V.A. Babain, V.M. Esimantovskiy, B.N. Zaitsev, E.G. Nazin, and G.F. Egorov, "Development and Characterization of a Universal Solvent Mixture for the Separation of Cesium, Strontium, Actinides and Rare Earth Elements from Acidic Radioactive Waste," proceedings of the International Solvent Extraction Conference (ISEC 2002), Cape Town, South Africa, pp. 1216-1221, March 2002.
10. J. Banaee, CM. Barnes, T. Battisti, S. Hermann, S.J. Losinski, S. McBride, "INTEC High-Level Waste Studies Universal Solvent Extradant Feasibility Study," INEEL/EXT-2000-01209, (2000).
11. M. L. Dietz and E. P. Horwitz, in Science and Technology for Disposal of Radioactive Tank Waste, Schulz, W. W.; Lombardo, W. W.: Eds., Plenum Publishing Co., NY (1998) p. 231.
12. L. Nigond, P. Y. Condamines, J. Cordier, C. Livet, C. Madic, C. Cuillerdier, C. Musikas, M. J. Hudson, "Recent Advances in the Treatment of Nuclear Wastes by the Use of Diamide and Picolinamide Extractants," Sep. Sci. Technol. 1995, 30, 2075-2099.
13. L. Tittse, T. Aicher., Preparative Organic Chemistry, Mir, Moscow, Russia (1999) p. 397.
14. Shimada, T. Yaita, H. Narita, S. Tachimori, O. Okuna, "Extraction Studies of Lanthanides(III) Ions with N,N′-Dimethyl-N,N-diphenylpyridine- 2,6- dicarboxyamide (DMDPhPDA) from Nitric Acid Solutions," Solv. Extr. Ion Exch. 2004, 22, 147-161.
15. M. Yu Alyapyshev, V.A. Babain, I.V. Smimov, "Extractive properties of Synergistic mixtures of Dipicolinic Acid Diamides and Chlorinated Cobalt Dicarbollide," Radiochemistry, (Engl. Ed.) 2004, 46, 270-271.