Real-time FTIR monitoring of the mechanism of initiation of isobutylene polymerizations by epoxide/lewis acid systems

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 46, Issue 11, 2008, Pages 3611-3618

  Soytaş, Serap Hayat ^a   Puskas, Judit E ^a   Kulbaba, Kevin ^b  

^a University of Akron   (United States)

^b Lanxess Inc   (Canada)

Author keywords

Cationic polymerization; Epoxide; FTIR; Synthesis

Indexed keywords

ACID SYSTEMS; FIBER OPTIC TRANSMISSIONS; FOURIER TRANSFORMATIONS; INFRARED (IR); INITIATION (ELECTRIC DISCHARGES); ISOBUTYLENE (IB); METHYL STYRENE; MONITOR (CO); REAL-TIME FT-IR;

BUTENES; CHEMICAL REACTIONS; FIBER OPTICS; FOURIER ANALYSIS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; INFRARED SPECTROSCOPY; MICROFLUIDICS; MONITORING; MONOMERS; PARAFFINS; POLYMERIZATION; POLYMERS;

REAL TIME SYSTEMS;

EID: 44949241313     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.22699     Document Type: Article

References (19)

1. Puskas, J. E.; Brister, L. B.; Michel, A. J.; Lanzendörfer, M. G.; Jamieson, D.; Pattern, W. G. J Polym Sci Part A: Polym Chem 2000, 38, 444-452.
2. Michel, A. J.; Puskas, J. E.; Brister, L. B. Macromolecules 2000, 33, 3518-3524.
3. Puskas, J. E.; Lanzendörfer, M. G.; Peng, H.; Michel, A. J.; Brister, L. B.; Paulo, C. In Nato Science Series; Puskas, J. E., Ed.; Kluwer Academic Publishers: Netherlands, 1999; p. 143.
4. Puskas, J. E.; Chen, Y.; Tomkins, M. Eur Polym J 2003, 39, 2147-2153.
5. Puskas, J. E.; Wilds, C. Rubber Chem Technol 1994, 67, 329-341.
6. Kwon, Y.; Puskas, J. E. Eur Polym J 2004, 40, 119-127.
7. Gagnon, S. D. In Encyclopedia of Polymer Science and Engineering; Klingsberg, A.; Muldoon, J., Eds.; Wiley-Interscience: New York, 1986; Vol. 6, pp 283-284.
8. Faust, R.; Kennedy, J. P. Polym Bull 1986, 15, 317-323.
9. Faust, R.; Kennedy, J. P. J Polym Sci Polym Chem Ed 1987, 25, 1847-1869.
10. Mishra, M. K.; Kennedy, J. P. J Macromol Sci Chem A 1987, 24, 933-948.
11. Kaszas, G.; Puskas, J. E.; Chen, C. C.; Kennedy, J. P. Polym Bull 1988, 20, 413-419.
12. Kaszas, G.; Puskas, J. E.; Kennedy, J. P.; Chen, C. C. J Macromol Sci, Chem A 1989, 26, 1099-1114.
13. Balogh, L.; Faust, R. Polym Bull 1992, 28, 367-374.
14. Swan, J. D. Anal Chem 1954, 26, 878-880.
15. Eisch, J. J.; Liu, Z.; Ma, X.; Zheng, G. J. Org Chem 1992, 57, 5140-5144.
16. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part B; Wiley: New York, 1997, pp 257-305.
17. Puskas, J. E.; Michel, A. Macromol Symp 2000, 161, 141-148.
18. Lappert, M. F. J Chem Soc 1961, 542, 817-822.
19. Kennedy, J. P.; Huang, S. Y.; Feinberg, S. C. J Polym Sci Polym Chem 1977, 15, 2869-2892.