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Volumn 4, Issue 5, 2008, Pages 534-537

Crystallographically proven nanometer-sized gold thiolate cluster Au 102(SR)44: Its unexpected molecular anatomy and resulting stereochemical and bonding consequences

Author keywords

Gold; Nanoclusters; Stereochemistry; Thiolate ligands; X ray crystallography

Indexed keywords

GOLD; GOLD ALLOYS; PHOTORESISTS; QUANTUM CHEMISTRY;

EID: 44949197607     PISSN: 16136810     EISSN: 16136829     Source Type: Journal    
DOI: 10.1002/smll.200800051     Document Type: Article
Times cited : (46)

References (32)
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    • I. L. Garzón, K. Michaelian, M. R. Beltrán, A. Posada-Amarillas, P. Ordejón, E. Artacho, D. Sánchez-Portal,. M. Soler, Phys. Rev. Lett. 1998, 81, 1600;
    • a) I. L. Garzón, K. Michaelian, M. R. Beltrán, A. Posada-Amarillas, P. Ordejón, E. Artacho, D. Sánchez-Portal,). M. Soler, Phys. Rev. Lett. 1998, 81, 1600;
  • 8
    • 44949212703 scopus 로고    scopus 로고
    • One notable exception is the Teo-Zhang general clusters of clusters growth-sequence model involving vertex sharing of centered icosahedra, found for the Au-Ag-M halide/phosphine polyicosahedral family (where M denotes centered Pd, Pt, or Ni):
    • One notable exception is the Teo-Zhang general "clusters of clusters" growth-sequence model involving vertex sharing of centered icosahedra, found for the Au-Ag-M halide/phosphine polyicosahedral family (where M denotes centered Pd, Pt, or Ni):
  • 14
    • 44949184388 scopus 로고    scopus 로고
    • 1 = z-0.25.
    • 1 = z-0.25.
  • 15
    • 17144417903 scopus 로고    scopus 로고
    • This is one of the two smallest multitwinned MD nanoparticles of fivefold symmetry; much larger ones have been proposed based upon theoretical calculations and indirectly observed (e.g, with transmission electron microscopy) for naked nanoparticles of decahedral morphology: a) L. D. Marks, J. Crystal Growth 1983, 61, 556;
    • This is one of the two smallest multitwinned MD nanoparticles of fivefold symmetry; much larger ones have been proposed based upon theoretical calculations and indirectly observed (e.g, with transmission electron microscopy) for naked nanoparticles of decahedral morphology: a) L. D. Marks, J. Crystal Growth 1983, 61, 556;
  • 25
    • 0040744020 scopus 로고
    • Adv. Chem. Phys. 1988, 70, 45.
    • (1988) Adv. Chem. Phys , vol.70 , pp. 45
  • 28
    • 44949131558 scopus 로고    scopus 로고
    • This terminology, which was coined in 1989 by Schmidbaur,[17] is used to describe Au-Au connectivities among closed-shell Au(l) centers at distances of 2.7-3.3 Å; extensive experimental and theoretical evidence[3b,3c,17] has assigned these attractive interactions (energetically estimated to be analogous to standard hydrogen bonding) to strong dispersion forces (also described as correlation effects) that are markedly enhanced by relativistic effects, which are particularly pronounced for gold
    • [3b,3c,17] has assigned these attractive interactions (energetically estimated to be analogous to standard hydrogen bonding) to strong dispersion forces (also described as correlation effects) that are markedly enhanced by relativistic effects, which are particularly pronounced for gold.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.