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Volumn 112, Issue 13, 2008, Pages 2813-2819

Two-state model based on electron-transfer reactivity changes to quantify the noncovalent interaction between Co(NH3)5Cl 2+ and 18-crown-6 ether: The effect of second-sphere coordination on electron-transfer processes

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON TRANSFER (ET); ELECTRON TRANSFER (ET) REACTIONS; NON COVALENT INTERACTIONS; REACTIVITY CHANGES; TWO STATE MODELS;

EID: 44949121917     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp7112544     Document Type: Article
Times cited : (6)

References (20)
  • 11
    • 0000804470 scopus 로고
    • Brauer, G, Ed, 2nd ed, Academic Press: New York
    • Brauer, G., Ed.; Handbook of Preparative Inorganic Chemistry, 2nd ed.; Academic Press: New York, 1965; Vol. 2, p 1511.
    • (1965) Handbook of Preparative Inorganic Chemistry , vol.2 , pp. 1511
  • 15
    • 47149084820 scopus 로고    scopus 로고
    • In order to obtain eq 7 from eq 5 and 6 an additional hypothesis is necessary on the equilibrium distribution described by eq 5: the concentration of the partitioned substrate must be low enough in order to avoid saturation of the dispersed pseudophase. Indeed, even in this case, it is implicit that the presence of a substrate molecule in the dispersed pseudophase neither encourages nor discourages the union of a second molecule of substrate: in other words, binding of the substrate to the dispersed pseudophase is non-cooperative in character.
    • In order to obtain eq 7 from eq 5 and 6 an additional hypothesis is necessary on the equilibrium distribution described by eq 5: the concentration of the partitioned substrate must be low enough in order to avoid saturation of the dispersed pseudophase. Indeed, even in this case, it is implicit that the presence of a substrate molecule in the dispersed pseudophase neither encourages nor discourages the union of a second molecule of substrate: in other words, binding of the substrate to the dispersed pseudophase is non-cooperative in character.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.