Hydrolysis of the terminal dimethylacetal moiety on the spacers bound to carboxy groups containing glucans

Carbohydrate Polymers

Volumn 74, Issue 1, 2008, Pages 133-136

  Farkaš, Pavol ^a   Bystrický, Slavomír ^a  

^a INSTITUTE OF CHEMISTRY   (Slovakia)

Author keywords

Conjugate; Dimethyl acetal; Glucan; Hydrolysis; Linker

Indexed keywords

CARBONYLATION; CROSSLINKING; DERIVATIVES; HYDROLYSIS; RATE CONSTANTS;

ANALOGOUS DERIVATIVES; CARBOXYMETHYLGLUCAN (CMG); DIMETHYL ACETAL; LINKERS;

AROMATIC COMPOUNDS;

EID: 44949085529     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2008.01.005     Document Type: Article

References (7)

1. Bulpitt P., and Aeschliman D. New strategy for chemical modification of hyaluronic acid: Preparation of functionalized derivatives and their use in the formation of novel biocompatible hydrogels. Journal of Biomedical Materials Research 47 (1999) 152-169
2. Dean K.E.S., and Kirby A.J. Concerted general acid and nucleophilic catalysis of acetal hydrolysis. A simple model for the lysozyme mechanism. Journal of Chemical Society, Perkin Transactions 2 (2002) 248-432
3. Farkaš P., and Bystrický S. Efficient activation of carboxyl polysaccharides for the preparation of conjugates. Carbohydrate Polymers 68 (2007) 187-190
4. Machová E., Kogan G., Alföldy J., Šoltés L., and Šandula J. Enzymatic and ultrasonic depolymerization of carboxymethylated β-1,3-d-glucans derived from Saccharomyces cerevisiae. Journal of the Applied Polymer Science 55 (1995) 699-704
5. Painter T.J., Cesaro A., Delben F., and Paloeti S. New glucuronoglucans obtained by oxidation of amylose at position 6. Carbohydrate Research 140 (1985) 61-68
6. Park J.T., and Johnson M.J. A submicrodetermination of glucose. J. Biol. Chem. 181 (1949) 149-151
7. Zhang J., Yergey A., Kowalak J., and Kováč P. Linking carbohydrates to proteins using N-(2,2-dimethoxyethyl)-6-hydroxy hexanamide. Tetrahedron 54 (1998) 11783-11792