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Volumn 11, Issue 7, 2008, Pages 749-753

The chiral Zn(II)-Na(I) coordination polymer: Synthesis, crystal structure, thermal and optical properties

Author keywords

Chiral complex; Coordination polymer; Crystal engineering; NLO; Zn(II) complex

Indexed keywords


EID: 44749092531     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2008.03.018     Document Type: Article
Times cited : (12)

References (58)
  • 38
    • 44749084011 scopus 로고    scopus 로고
    • note
    • 2, EtOH, 2H), 4.92 (broad, OH, EtOH), 5.37 (singlet, CH, acac, 2H).
  • 39
    • 44749092908 scopus 로고    scopus 로고
    • note
    • e. UV-Vis region were recorded with a Schimadzu 2001 UV PC spectrophotometer using 1 cm pathlength cuvettes at room temperature.
  • 40
    • 44749090225 scopus 로고    scopus 로고
    • note
    • Suitable crystals were mounted on a Nonius KappaCCD diffractometer using Mo Kα radiation (λ = 0.71073 Å) and equipped with a CCD area detector. Intensities were collected at 293 K by means of the program COLLECT (Nonuis 1997-2001, COLLECT, Nonius BV, Delft, The Netherlands) with a step rotation angle of 1° for the ω angle. The structures were solved and refined by using the SHELXTL (SHELXTL; 5.030 ed.; Brucker Analytical X-ray Instruments, Inc.: Madisson, WI, 1998) and CRYSTALS (P.W. Betteridge, J.R. Carruthers, R.I. Cooper, K. Prout, D.J. Watkin, J. Appl. Cryst. 36 (2003) 1487). All non-hydrogen atoms were refined with anisotropic thermal parameters. The hydrogen atoms were included in the final refinement model in calculated positions with isotropic thermal parameters.
  • 41
    • 44749089830 scopus 로고    scopus 로고
    • note
    • 2 = 0.043.
  • 56
    • 44749083499 scopus 로고    scopus 로고
    • note
    • The efficiency of the crystals for frequency doubling was determined by the Kurtz and Perry powder test using a pulsed Nd:YAG laser (λ = 1064 nm). Prior to measurement the crystalline compound was ground into powders, sieved to an average particle size between 250 and 300 μm, and packed into pellets of 2 mm path length. The references used were urea, POM [3-methyl-4-nitropyridine-1-oxide] and NPP [N-(4-nitrophenyl)-(S)-prolinol].
  • 57
    • 44749092846 scopus 로고    scopus 로고
    • Gaussian 03, Revision D.01, Gaussian, Inc., Wallingford, CT, 2004.
    • Gaussian 03, Revision D.01, Gaussian, Inc., Wallingford, CT, 2004.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.