A model for radiolysis of water and aqueous solutions of H2, H2O2 and O2

Radiation Physics and Chemistry

Volumn 77, Issue 8, 2008, Pages 928-935

  Ershov, B G ^a   Gordeev, A V ^a  

^a FRUMKIN INSTITUTE OF PHYSICAL CHEMISTRY AND ELECTROCHEMISTRY   (Russian Federation)

Author keywords

Aqueous solutions; Hydrogen; Hydrogen peroxide; Kinetic; Oxygen; Radiolysis; Rate constant; Reaction; Simulating; Water

Indexed keywords

COMPUTER SIMULATION; CONCENTRATION (PROCESS); HYDROGEN PEROXIDE; MATHEMATICAL MODELS; OXYGEN; RADIOLYSIS; RATE CONSTANTS; SOLUTIONS; WATER;

KINETIC MODELS; RADIATION CHEMICAL TRANSFORMATIONS;

HYDROGEN;

HYDROGEN; HYDROGEN PEROXIDE; OXYGEN; WATER;

AQUEOUS SOLUTION; ARTICLE; KINETICS; PH; RADIOLYSIS;

EID: 44649195032     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2007.12.005     Document Type: Article

References (33)

1. 2. A pulse radiolysis study. Rad. Phys. Chem. 71 (2004) 1087-1093
2. Anderson A.R., and Hart E.J. Radiation chemistry of water with pulsed high intensity electron beams. J. Phys. Chem. 66 (1962) 70-75
3. Bahnemann D., and Hart E.J. Rate constants of the reaction of the hydrated electron and hydroxyl radical with ozone in aqueous solution. J. Phys. Chem. 86 (1982) 252-255
4. - radicals in aqueous solution. J. Phys. Chem. Ref. Data 14 4 (1985) 1041-1100
5. Boyd A.W., Carver M.B., and Dixon R.S. Computed and experimental product concentrations in the radiolysis of water. Radiat. Phys. Chem. 15 2/3 (1980) 177-185
6. - as intermediates. J. Phys. Chem. 88 (1984) 2560-2564
7. Burns W.G., and Moore P.W. Radiat. Eff. 30 3 (1976) 233-242
8. Burns W.G., Marsk W.R., and Walters W.S. The γ-irradiation-enhanced corrosion of stainless and mild steels by water in the presence of air, argon and hydrogen. Radiat. Phys. Chem. 21 3 (1983) 259-279
9. -) in aqueous solution. J. Phys. Chem. Ref. Data 17 2 (1988) 513-886
10. Dickinson R.P., and Gelinas R.J. Sensitivity analysis of ordinary differential equation systems-a direct method. J. Comput. Phys. 21 (1976) 123-143
11. Ershler B.V. Doklady Akademii Nauk SSSR 129 4 (1959) 866-868
12. Ershler B.V. Effect of dose rate on the stationary concentrations of radiolytic products. High Energ. Chem. 2 3 (1968) 244-248
13. Ershov, B.G., Gordeev, A.V., 2005. Diffusionno-kineticeskaya model' radioliza vody i vodnykh rastvorov (Diffusion-kinetic model of radiolysis of water and aqueous solutions). In: Sovremennye Problemy Fizicheskoi Khimii (Modern Problems of Physical Chemistry). Dom "Granitsa" Publishers, Moscow, pp. 520-541.
14. - ions in aqueous solution. Radiat. Phys. Chem. 59 (2000) 309-312
15. Forni L., Bahnemann D., and Hart E.J. Mechanism of the hydroxide ion-initiated decomposition of ozone in aqueous solution. J. Phys. Chem. 86 (1982) 255-259
16. Gear C.W. DIFSUB for solution of ordinary differential equations [D2]. Commun. ACM 14 3 (1971) 185-190
17. Gordeev A.V., Kabakchi S.A., Ershov B.G., Grishkin V.L., and Bugaenko V.L. Mathematical model of accumulation and decomposition of molecular products of water radiolysis. Doklady Akademii Nauk SSSR 296 6 (1987) 1388-1392
18. Hayon E. Radiolysis of air-free aqueous solutions of hydrogen peroxide. Trans. Faraday Soc. I 60 (1967) 1059-1067
19. -. Kinetic determination of the enthalpy and entropy of solvation of the hydrated electron. J. Phys. Chem. 89 (1985) 5271-5274
20. Hochanadel C.J. Effects of cobalt γ-radiation on water and aqueous solutions. J. Phys. Chem. 56 5 (1952) 587-594
21. -, in aqueous alkaline solutions. J. Phys. Chem. 86 (1982) 2069-2072
22. Jenks, G.H., 1965. Effect of reactor operations HFRJ coolant. ORNZ-3846.
23. Jenks, G.H., Griess J.C., 1967. Water chemistry in pressurized and boiled water power reactors. ORNZ-4173.
24. Kabakchi S.A., Shubin V.N., and Dolin P.I. Effect of pH on the stationary concentration of radiolysis products of aqueous solution of oxygen. High Energ. Chem. 1 2 (1967) 148-153
25. Neta P., Huie R.E., and Ross A.B. Rate constants for reactions of inorganic radicals in aqueous solution. J. Phys. Chem. Ref. Data 17 3 (1988) 1027-1284
26. Pikaev, A.K., Kabakchi, S.A., Makarov, I.E., 1988. Vysokotemperaturnyi radiolis vody i vodnukh rastvorov. Energoatomizdat, Moscow.
27. Schwarz H.A. A determination of some rate constants for the radical processes in radiation chemistry of water. J. Phys. Chem. 66 (1962) 255-262
28. -, in strong alkaline solution. J. Phys. Chem. 86 (1982) 2066-2069
29. - and H with ozone in aqueous solutions. J. Phys. Chem. 87 (1983) 1951-1954
30. Sehested K., Holcman J., Bjergbakke E., and Hart E.J. A pulse radiolytic study of the reaction hydroxyl+ozone in aqueous medium. J. Phys. Chem. 88 (1984) 4144-4147
31. Sweet J.P., and Thomas J.K. Absolute rate constants for H atom reactions in aqueous solutions. J. Phys. Chem. 68 (1964) 1363-1368
32. - radicals with hydrogen peroxide. The Haber Weiss reaction. J. Am. Chem. Soc. 101 1 (1979) 58-62
33. Willis C., Boyd A.W., Rothwell A.E., and Miller B.A. Experimental and calculated yields in the radiolysis water at very high dose rates. Int. J. Radiat. Phys. Chem. 1 3 (1969) 373-381