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Iodine center in oxygen ligand appended IBX derivatives is known to be involved in oxidation of substrates via single electron transfer (SET) pathways, see:
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Relevant bond dissociation energies (BDE) used for comparing the relative ease of α-H abstraction from benzylic alcohol, non-benzylic alcohol, allylic alcohol and THF are 87.5 ± 1.6 kcal/mol, 93.7 ± 1.8 kcal/mol, 81.6 ± 1.8 kcal/mol, and 92.1 ± 1.6 kcal/ mol, respectively and the BDE values are compiled from:, CRC Press, Boca Raton, Florida
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Relevant bond dissociation energies (BDE) used for comparing the relative ease of α-H abstraction from benzylic alcohol, non-benzylic alcohol, allylic alcohol and THF are 87.5 ± 1.6 kcal/mol, 93.7 ± 1.8 kcal/mol, 81.6 ± 1.8 kcal/mol, and 92.1 ± 1.6 kcal/ mol, respectively and the BDE values are compiled from:. Luo Y.-R. Handbook of Bond Dissociation Energies in Organic Compounds (2003), CRC Press, Boca Raton, Florida
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(2003)
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