Synthesis and characterization of fluorescent starch using fluorescein as fluorophore: potential polymeric temperature/pH indicators

Polymers for Advanced Technologies

Volumn 19, Issue 5, 2008, Pages 385-392

  Guan, Xiaolin ^a   Su, Zhixing ^a  

^a LANZHOU UNIVERSITY   (China)

Author keywords

3 epoxypropoxy fluorescein; Fluorescence; Starch; Temperature pH indicators

Indexed keywords

CHEMILUMINESCENCE; DIMETHYL SULFOXIDE; FLUORESCENCE; FLUORINE CONTAINING POLYMERS; PH EFFECTS; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL);

EPICHLOROHYDRIN; OPTICAL TRANSDUCER; STARCH-BEARING FLUORESCEIN;

STARCH;

CHEMILUMINESCENCE; DIMETHYL SULFOXIDE; FLUORESCENCE; FLUORINE CONTAINING POLYMERS; PH EFFECTS; RING OPENING POLYMERIZATION; STARCH; SYNTHESIS (CHEMICAL);

CATALYST; PH; STARCH; SYNTHESIS; TEMPERATURE EFFECT;

EID: 44649101517     PISSN: 10427147     EISSN: 10991581     Source Type: Journal    
DOI: 10.1002/pat.1021     Document Type: Article

References (27)

1. Chen H, You-Lo H. Dual temperature- and pH-sensitive hydrogels from interpenetrating networks and copolymerization of N-isopropylacrylamide and sodium acrylate. J. Polym. Sci., Part A: Polym. Chem. 2004; 42: 3293-3301.
2. Al-Muallem HA, Wazeer MM, Asrof AS. Synthesis and solution properties of a new pH-responsive polymer containing amino acid residues. Polymer 2002; 43: 4285-4295.
3. Gerhard JM, Otto SW. Optical sensors for a wide pH range based on azo dyes immobilized on a novel support. Anal. Chim. Acta 1994; 292: 41-48.
4. Mitsuishi M, Shinji K, Tokuji M, Yutaka A. Characterization of an ultrathin polymer optode and its application to temperature sensors based on luminescent europium complexs. J. Mater. Chem. 2003; 13(12): 2875-2879.
5. Chen CA, Yeh RH, Lawrence DC. Design and synthesis of a fluorescent reportor of protein kinase activity. J. Am. Chem. Soc. 2002; 124: 3840-3841.
6. Setsukinai K, Urano Y, Kakinuma K, Majima HJ, Nagano T. Development of novel fluorescence probes that can reliably detect reactive oxygen species and distinguish specific species. J. Biol. Chem. 2003, 278: 3170-3175.
7. Martin MF. Spectroscopic behaviour and protolytic equilibrium of fluorescein immobilized in ethyl cellulose. J. Photochem. Photobiol., A: Chem. 1998; 114: 235-239.
8. Mattingly PG. Preparation of 5- and 6-(aminoomethyl) fluorescein. Bioconjugate Chem. 1992; 3: 430-431.
9. Shipchandler MT, Fino JR, Klein LD, Kirkemo CL. 4′-[Aminomethyl]fluorescein and its N-alkyl derivatives: useful reagents in immunodiagnostic techniques. Anal. Biochem. 1987; 162: 89-101.
10. Li XH, Ma HM, Dong SY, Duan XJ, Nie LH, Sun M. Designand synthesis of a novel fluorescein-based fluorescent probe for labeling of histidinein human serum chemical. Chem. J. Chin. Univ. 2003; 24: 1984-1986.
11. Guan XL, Liu XY, Su ZX. Preparation and photophysical behaviors of fluorescent chitosan bearing fluorescein: potential biomaterial as temperature/pH probes. J. Appl. Polym. Sci. 2007; 104: 3960-3966.
12. Andrzej P, Stanislawa KK, Fiedorowicz M. Dihydrazone of dialdehyde starch and its metal complexes. Carbohydr. Polym. 2004; 56: 187-193.
13. Liu P, Su ZX. Surface-initiated atom transfer radical polymerization (SI-ATRP) of n-butyl acrylate from starch granules. Carbohydr. Polym. 2005; 62: 159-163.
14. Chen L, Ma JB, He BL. Synthesis of β-cyclodextrin-immobilized poly(vinyl alcohol) beads as chiral stationary phase for resolution of enantiomers of some organic compounds. Ion Exch. Adsorpt. 1997; 13: 503-507.
15. Wesslen KB, Wesslen B. Synthesis amphiphilic amylase and starch derivatives. Carbohydr. Polym. 2002; 47: 303-311.
16. Dibbern-Brunelli D, de Oliveira MG, Atvars TDZ. Temperature dependence of the photobleaching process of fluorescein in poly(vinyl alcohol). J. Photochem. Photobiol., A: Chem. 1995; 85: 285-289.
17. Swinkles JJM. Sources of starch, its chemistry and physics. In Srarch conversion technology, van Beynum GMA, Roels JA (eds). Marcel Dekker: New York, 1985; 30.
18. Neckers DC, Valders-Aguilera OM. In Advances in Photochemistry, Volman D, Hammond GS, Neckers DC (eds). Vol. 18. Wliey: New York, 1993.
19. Sjoback R, Nygren J, Kubista M. Absorption and fluorescence properties of fluorescein. Spectrochim. Acta, Part A. 1995; 51: L7-L21.
20. Monique MM. Intermolecular hydrogen and temperature effects on internal conversion in xanthene dyes. Chem. Phys. Lett. 1976; 43: 332-337.
21. Tasuku U, Yasuteru U. Rational principles for modulating fluorescence properties of fluorescein. J. Am. Chem. Soc. 2004; 126: 14079-14085.
22. Mehata MS, Joshil HC, Tripathi HB. Edge excitation red shift and charge transfer study of 6-methoxyquinoline in polymer matrices. J. Lumin. 2001; 93: 275-280.
23. Lakowiz JR. Principles of fluorescence spectroscopy (3rd edn). Plenum: New York, 1986.
24. Martins-Franchetti SM, Altvars TDZ. Study of low density polyethylene-poly(vinyl chloride) blend secondary relaxations by photoluminescence. Eur. Polymer. J. 1995; 31: 467-474.
25. Talhavini M, Atvars TDZ. Dye-polymer interactions controlling the kinetics of fluorescein photobleaching reactions in poly(vinyl alcohol). J. Photochem. Photobiol., A: Chem. 1998; 114: 65-73.
26. Monique MM. Hydrogen bond effects on radlationless electronic transitions in xanthene dyes. Chem. Phys. Lett. 1975; 35: 105-111.
27. Martin MM, Lindqvist L. The pH dependence of fluorescein fluorescence. J. Lumin. 1975; 10: 381-390.