Copper(II) and cadmium(II) sorption onto ferrihydrite in the presence of phthalic acid: Some properties of the ternary complex

Environmental Science and Technology

Volumn 42, Issue 11, 2008, Pages 4008-4013

  Song, Yantao ^a   Swedlund, Peter J ^a   Singhal, Naresh ^a  

^a UNIVERSITY OF AUCKLAND   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CADMIUM; COMPLEXATION; MATHEMATICAL MODELS;

DIFFUSE LAYER MODEL (DLM); PHTHALIC ACID;

COPPER;

CADMIUM; CATION; COPPER; DIPROTIC ACID; FERRIC HYDROXIDE; INORGANIC ACID; LIGAND; PHTHALIC ACID; TERNARY COMPLEX FACTOR;

ADSORPTION; CADMIUM; COMPLEXATION; COPPER; MATHEMATICAL MODELS;

ADSORPTION; CADMIUM; CATION; COPPER; FERRIHYDRITE; GOETHITE; ORGANIC ACID;

ADSORPTION; ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; DIFFUSE LAYER MODEL; MODEL;

ADSORPTION; CADMIUM; COPPER; FERRIC COMPOUNDS; MODELS, CHEMICAL; PHTHALIC ACIDS;

EID: 44449086021     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es702509q     Document Type: Article

References (28)

1. Young, L. B.; Harvey, H. H. The relative importance of manganese and iron oxides and organic matter in the sorption of trace metals by surficial lake sediments. Geochim. Cosmochim. Acta 1992, 56, 1175-1186.
2. Weng, L.; Temminghoff, E. J. M.; Lofts, S.; Tipping, E.; Van Riemsdijk, W. H. Complexation with dissolved organic matter and solubility control of heavy metals in a sandy soil. Environ. Sci. Technol. 2002, 36, 4804-4810.
3. Weng, L. P.; Hiemstra, T.; Van Riemsdijk, W. H.; Koopal, L. K.; Meeussen, J. C. L. Interactions of calcium and fulvic acid at the goethite-water interface. Geochim. Cosmochim. Acta 2005, 69, 325-339.
4. Klavins, M.; Eglite, L.; Serzane, J. Methods for analysis of aquatic humic substances. Crit. Rev. Anal. Chem. 1999, 29, 187-193.
5. 2+ on goethite. Geochim. Cosmochim. Acta 1996, 60, 291-304.
6. Ali, M. A.; Dzombak, D. A. Interactions of copper, organic acids, and sulfate in goethite suspensions. Geochim. Cosmochim. Acta 1996, 60, 5045-5053.
7. Evanko, C. R.; Dzombak, D. A. Surface complexation modeling of organic acid sorption to goethite. J. Colloid Interface Sci. 1999, 214, 189-206.
8. Filius, J. D.; Hiemstra, T.; Van Riemsdijk, W. H. Adsorption of small weak organic acids on goethite: modeling of mechanisms. J. Colloid Interface Sci. 1997, 195, 368-380.
9. Hanna, K. Sorption of two aromatic acids onto iron oxides: Experimental study and modeling. J. Colloid Interface Sci. 2007, 309, 419-428.
10. Hwang, Y. S.; Liu, J.; Lenhart, J. J.; Hadad, C. M. Surface complexes of phthalic acid at the hematite/water interface. J. Colloid Interface Sci. 2007, 307, 124-134.
11. Boily, J.-F.; Sjöberg, S.; Persson, P. Structures and stabilities of Cd(II) and Cd(II)-phthalate complexes at the goethite-water interface. Geochim. Cosmochim. Acta 2005, 69, 3219-3235.
12. Tejedor-Tejedor, M. I.; Yost, E. C.; Anderson, M. A. Characterization of benzoic and phenolic complexes at the goethite/aqueous solution interface using cylindrical internal reflection Fourier transform infrared spectroscopy. II: Bonding structures. Langmuir 1992, 8, 525-533.
13. Buerge-Weirich, D.; Hari, R.; Xue, H.; Behra, P.; Sigg, L. Adsorption of Cu, Cd, and Ni on goethite in the presence of natural groundwater ligands. Environ. Sci. Technol. 2002, 36, 328-336.
14. Ali, M. A; Dzombak, D. A. Competitive sorption of simple organic acids and sulfate on goethite. Environ. Sci. Technol. 1996, 30, 1061-1071.
15. Boily, J.-F.; Sjöberg, S.; Persson, P. Benzenecarboxylate surface complexation at the goethite (α-FeOOH)/water interface: II. Linking IR spectroscopic observations to mechanistic surface complexation models for phthalate, trimellitate, and pyromellitate. Geochim. Cosmochim. Acta 2000, 64, 3453-3470.
16. Peak, D.; Ford, R. G.; Sparks, D. L. An in situ ATR-FTIR investigation of sulfate bonding mechanisms on goethite. J. Colloid Interface Sci. 1999, 218, 289-299.
17. Elzinga, E. J.; Peak, D.; Sparks, D. L. Spectroscopic studies of Pb(II)-sulfate interactions at the goethite-water interface. Geochim. Cosmochim. Acta 2001, 65, 2219-2230.
18. Ostergren, J. D.; Brown, G. E. J.; Parks, G. A.; Persson, P. Inorganic ligand effects on Pb(II) sorption to goethite (α-FeOOH) II sulfate. J. Colloid Interface Sci. 2000, 225, 483-493.
19. Spadini, L.; Charlet, L.; Manceau, A.; Schindler, P. W.; Ragnarsdottir, K. V. Hydrous ferric oxide: Evaluation of Cd-HFO surface complexation models combining CdK EXAFS data, potentiometric titration results, and surface site structures identified from mineralogical knowledge. J. Colloid Interface Sci. 2003, 266, 1-18.
20. Trivedi, P.; Dyer, J. A.; Sparks, D. L. Lead sorption onto ferrihydrite. 1. A macroscopic and spectroscopic assessment. Environ. Sci. Technol. 2003, 37, 908-914.
21. Lackovic, K.; Angove, M. J.; Wells, J. D.; Johnson, B. B. Modelling the adsorption of Cd(II) onto goethite in the presence of citric acid. J. Colloid Interface Sci. 2004, 269, 37-45.
22. 4 on ferrihydrite and schwertmannite. Appl. Geochem. 2001, 16, 503-511.
23. 4 on the ferrihydrite adsorption of Co, Pb and Cd: ternary complexes and site heterogeneity. Appl. Geochem. 2003, 18, 1671-1689.
24. Dzombak, D. A.; Morel, F. M. M. Surface Complexation Modeling: Hydrous Ferric Oxide; John Wiley & Sons: New York, 1990.
25. Schwertman, U.; Cornell, R. M. Iron oxide in the laboratory: preparation and characterization, 1st ed.; VCH: New York, 1991.
26. Gustafsson, J. P. Visual MINTEQ, ver. 2.51; 2006.
27. Herbelin, A. L.; Westall, J. C. FITEQL: A computer program for determination of chemical equilibrium constants from experimental data, Version 4.0; Chemistry Department, Oregon State University: Corvallis, OR, 1999.
28. Swedlund, P. J.; Webster, J. G. Adsorption and polymerisation of silicic acid on ferrihydrite, and its effect on arsenic adsorption. Water Res. 1999, 33, 3413-3422.