α-Hydroxy ketones in high enantiomeric purity from asymmetric oxidation of enol phosphates with (salen) manganese(III) complex

Tetrahedron Asymmetry

Volumn 15, Issue 17, 2004, Pages 2599-2602

  Krawczyk, Ewa ^a   Koprowski, Marek ^a   Skowrońska, Aleksandra ^a   Łuczak, Jerzy ^a  

^a CENTRE OF MOLECULAR AND MACROMOLECULAR STUDIES   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

KETONE DERIVATIVE; MANGANESE DERIVATIVE; PHOSPHATE;

ARTICLE; CATALYSIS; ENANTIOMER; ENANTIOSELECTIVITY; OXIDATION; PRIORITY JOURNAL;

EID: 4444362795     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetasy.2004.07.035     Document Type: Article

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34. 3 was added, the organic layer was separated, washed with water, and dried. After removal of the solvent, the residue was subjected to silica gel column chromatography with hexane-ethyl acetate (3:1 v/v) as the eluent, to afford pure, optically active α-hydroxy ketones 4
35. +) 213.09155. Found 213.09102
36. HPLC conditions: For entries 1, 2, 5, 8: Chiralcel OD, 5% i-PrOH in hexane, 0.4 mL/min; For entry 3: Chiralcel OD, 4% i-PrOH in hexane, 0.4 mL/min; For entry 4: Chiralcel OD, 3% i-PrOH in hexane, 0.3 mL/min; For entry 6: Chiralcel OD, 0.25% i-PrOH in hexane, 0.3 mL/min; For entry 7: Chiralcel OD, 0.5% i-PrOH in hexane, 0.5 mL/min. All runs were carried out at room temperature
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