Hydroperoxide oxidation: Unexpected C-C bond cleavage in branched alkanes and oxidation of molecular nitrogen

Comptes Rendus Chimie

Volumn 7, Issue 8-9, 2004, Pages 833-844

  Gekhman, Alexander E ^a   Stolyarov, Igor P ^a   Moiseeva, Natalia I ^b   Moiseev, Ilya I ^a  

^a KURNAKOV INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Russian Federation)

^b SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

Branched alkanes; C C bond cleavage; Cyclohexane; Hydrogen peroxide; Hydroxylation; Ketonization; Linear alkanes; Molecular nitrogen; Oxidation; Vanadium(V)

Indexed keywords

ACETIC ACID; ALCOHOL; ALKANE DERIVATIVE; BUTANE; CARBON; HYDROGEN PEROXIDE; HYDROPEROXIDE; KETONE; NITROGEN; OCTANE; OXYGEN; OZONE; VANADIUM;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; FENTON REACTION; HYDROXYLATION; MASS SPECTROMETRY; OXIDATION; TRANSPORT KINETICS;

EID: 4444294100     PISSN: 16310748     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.crci.2004.06.001     Document Type: Article

References (38)

1. Fenton H.J. J. Chem. Soc. 65 1894 899
2. Sheldon R.A. Kochi J.K. Metal-catalyzed oxidations of organic compounds 1981 Academic Press New York chapter 9
3. Edwards J.O. Edwards J.O. (Ed.), Peroxide Reaction Mechanisms 1962 Wiley New York 67
4. Edwards J.O. Curci R. Strukul G. Catalytic oxidations with hydrogen peroxide as oxidant 1992 Kluwer Academic Dordrecht
5. Syrkin Ya.K. Moiseev I.I. Usp. Khim. 29 4 1960 425 (in Russian)
6. Makarov A.P. Gekhman A.E. Nekipelov V.M. Talsi E.P. Ya. Polotnyuk O. Zamaraev K.I. Moiseev I.I. Bull. Acad. Sci. USSR, Div. Chem. Sci. 34 1985 544 (English translation)
7. Gekhman A.E. Makarov A.P. Nekipelov V.M. Talsi E.P.Ya. Polotnyuk O. Zamaraev K.I. Moiseev I.I. Bull. Acad. Sci. USSR, Div. Chem. Sci. 34 1985 1764 (English translation)
8. Moiseeva N.I. Gekhman A.E. Moiseev I.I. Gazz. Chim. Ital. 122 1992 187
9. Moiseeva N.I. Gekhman A.E. Moiseev I.I. J. Mol. Catal. A: Chem. 117 1997 39
10. Moiseev I.I. Murahashi S.-I. Davies S.G. Chemistry for the 21st Century 1999 Blackwell Science Oxford 343
11. Moiseeva N.I. Gekhman A.E. Minin V.V. Larin G.E. Bashtanov M.E. Krasnovskii A.A. Moiseev I.I. Kinet. Catal. (Russ.) 41 2 2000 170 (Engl. Transl.)
12. Makarov A.P. Gekhman A.E. Ya. Polotnyuk O. Moiseev I.I. Bull. Acad. Sci. USSR Div. Chem. Sci. 34 1985 694 (English Translation)
13. Gekhman A.E. Stolarov I.P. Moiseeva N.I. Rubaijlo V.L. Vargaftik M.N. Moiseev I.I. Inorg. Chim. Acta 275-276 1998 453
14. Gekhman A.E. Moiseeva N.I. Moiseev I.I. Doklady Chemistry 349 (1-3) 1996 165 (English Translation)
15. Gekhman A.E. Amelichkina G.E. Moiseeva N.I. Vargaftik M.N. Moiseev I.I. J. Mol. Catal. A: Chem. 162 2000 111
16. Gekhman A.E. Amelichkina G.E. Moiseeva N.I. Vargaftik M.N. Moiseev I.I. Kinetics and Catalysis (Russ.) 42 4 2001 496 (English Translation)
17. Moiseev I.I. Shishkin D.I. Gekhman A.E. New J. Chem. 13 (10-11) 1989 683
18. Lubeck A.J. Sutton D.L. J. High Resolut. Chromatogr. 3 1983 328
19. Vargaftik M.N. Stolarov I.P. Moiseev I.I. J. Chem. Soc., Chem. Commun. 1990 1049
20. Stolarov I.P. Vargaftik M.N. Shishkin D.I. Moiseev I.I. J. Chem. Soc., Chem. Commun. 1991 938
21. Mimoun H. Saissine L. Daire E. Rostel M. Fisher J. Weiss R. J. Am. Chem. Soc. 105 1983 3101
22. Shilov A.E. Activation of Saturated Hydrocarbons by Transition Metal Complexes 1984 Reidel Dordrecht
23. Emanuel N.M. Denisov E.T. Maizus Z.K. Liquid-Phase Oxidation of Hydrocarbons 1967 Plenum Press New York 132
24. Shatenshtein A.I. Theory of Acids and Bases (Russ.) 1949 Goskhimidat Moscow 246
25. Usanovich M.I. Wiss. Fortschr. 14 1964 499
26. Barin J. Knacke O. Thermodynamical Properties of Inorganic Substances 1973 Springer-Verlag Berlin
27. Gekhman A.E. Stolyarov I.P. Shestakov A.F. Shilov A.E. Moiseev I.I. Russ. Chem. Bull. 52 3 2003 768
28. Fergusson J.E. Wilkins C.J. J. Chem. Soc. 1962 2136
29. Vol'nov I.I. Peroxocomplexes of Vanadium, Niobium and Tantalum 1987 Nauka Moscow (in Russian)
30. Conte V. Di Furia F. Modena G. Ando W. Organic Peroxides 1992 J.Wiley & Sons Chichester, N.Y. 559
31. Strukul G. Strukul G. Catalytic Oxidations with Hydrogen Peroxide as Oxidant 1992 Kluwer Academic Publishers Dordrecht
32. Di Furia F. Modena G. Rev. Chem. Intermed. 6 1985 51
33. Butler A. Clague M.J. Meister G.E. Chem. Rev. 94 1994 625
34. Muzart J. Chem. Rev. 92 1992 113
35. Dickman M.H. Pope M.T. Chem. Rev. 94 1994 569
36. Xiao J. Santasiero B.D. Vaartstra B.A. Cowie M. J. Am. Chem. Soc. 115 1993 3212 and references therein
37. Conte V. Di Furia F. Moro S. J. Mol. Catal. A 117 1997 139
38. Moiseev I.I. J. Mol. Catal. A: Chem. 127 1997 1