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Volumn 77, Issue 8, 2004, Pages 1509-1522

Di(9-anthryl)carbene revisited. Product analysis and spectroscopic studies

Author keywords

[No Author keywords available]

Indexed keywords

LASER FLASH PHOTOLYSIS; PHOTOSTABILITY; TETRAMERS; TRANSIENT SPECIES;

EID: 4444286640     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.77.1509     Document Type: Article
Times cited : (11)

References (63)
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    • (1971) "Carbene Chemistry," 2nd Ed.
    • Kirmse, W.1
  • 2
    • 0003428791 scopus 로고
    • ed by R. A. Moss and M. Jones, Jr., Wiley, New York
    • b) "Carbenes," ed by R. A. Moss and M. Jones, Jr., Wiley, New York (1973 and 1975), Vols. 1 and 2.
    • (1973) Carbenes , vol.1-2
  • 3
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    • ed by M. Regitz, Thieme, Stuttgart
    • c) "Carbene-(oide), Carbine," ed by M. Regitz, Thieme, Stuttgart (1989).
    • (1989) Carbene-(oide), Carbine
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    • 0001328124 scopus 로고
    • ed by M. Jones, Jr. and R. A. Moss, Wiley, New York
    • b) A. M. Trozzolo and E. Wasserman, "Carbenes," ed by M. Jones, Jr. and R. A. Moss, Wiley, New York (1975), Vol. 2, pp. 185-206.
    • (1975) Carbenes , vol.2 , pp. 185-206
    • Trozzolo, A.M.1    Wasserman, E.2
  • 14
    • 0000206452 scopus 로고    scopus 로고
    • Review for persistent triplet carbenes, see: a) H. Tomioka, Acc. Chem. Res., 30, 315 (1997).
    • (1997) Acc. Chem. Res. , vol.30 , pp. 315
    • Tomioka, H.1
  • 15
    • 0000491883 scopus 로고    scopus 로고
    • ed by U. Brinker, JAI Press, Greenwich, CT
    • b) H. Tomioka, "Advances in Carbene Chemistry," ed by U. Brinker, JAI Press, Greenwich, CT (1998), Vol. 2, pp. 175-214.
    • (1998) Advances in Carbene Chemistry , vol.2 , pp. 175-214
    • Tomioka, H.1
  • 16
    • 0042999944 scopus 로고    scopus 로고
    • ed by G. Bertrand, Fontis Media S. A., Lausanne
    • c) H. Tomioka, "Carbene Chemistry," ed by G. Bertrand, Fontis Media S. A., Lausanne (2002) pp. 103-152.
    • (2002) Carbene Chemistry , pp. 103-152
    • Tomioka, H.1
  • 17
    • 0002811632 scopus 로고
    • ed by U. Brinker, JAI Press, Greenwich, CT
    • See for reviews: a) W. Kirmse, "Advances in Carbene Chemistry," ed by U. Brinker, JAI Press, Greenwich, CT (1994), pp. 1-57.
    • (1994) Advances in Carbene Chemistry , pp. 1-57
    • Kirmse, W.1
  • 18
    • 4444289606 scopus 로고    scopus 로고
    • ed by U. Brinker, JAI Press, Greenwich, CT
    • b) W. Kirmse, "Advances in Carbene Chemistry," ed by U. Brinker, JAI Press, Greenwich, CT (2001), Vol. 3, pp. 1-51.
    • (2001) Advances in Carbene Chemistry , vol.3 , pp. 1-51
    • Kirmse, W.1
  • 20
    • 0002045251 scopus 로고
    • ed by U. Brinker, JAI Press, Greenwich, CT
    • b) J. E. Jackson and M. S. Platz, "Advances in Carbene Chemistry," ed by U. Brinker, JAI Press, Greenwich, CT (1994), Vol. 1, pp. 87-160.
    • (1994) Advances in Carbene Chemistry , vol.1 , pp. 87-160
    • Jackson, J.E.1    Platz, M.S.2
  • 52
    • 4444294662 scopus 로고    scopus 로고
    • note
    • -4 M.
  • 53
    • 4444368078 scopus 로고    scopus 로고
    • note
    • -2 M in 2-methyltetrahydrofuran, a quantum yield for the disappearance of 1 upon irradiation with the uranium glass-filtered radiation of a medium pressure Hg lamp of 9.4 was estimated by uranyl oxalate actinometry.
  • 57
    • 4444348298 scopus 로고    scopus 로고
    • in press
    • 2) singlet lies 15 kcal/mol above the triplet. See, C. Trindle, J. Org. Chem., in press.
    • J. Org. Chem.
    • Trindle, C.1
  • 58
    • 0034830280 scopus 로고    scopus 로고
    • 2c and hence we assume that those carbenes can exist in a perturbed structure on the soft energy surface. This has been shown by in situ X-ray crystallographic observation of triplet bis(2,4,6- trichlorophenyl)carbene trapped in a crystal. In this case, the observed structure of triplet carbene is different from the DFP optimized one and is corresponding to a non-global minimum on very shallow potentials. Such perturbation is ascribable to the steric effect in a crystalline lattice. See, M. Kawano, K. Hirai, H. Tomioka, and Y. Ohashi, J. Am. Chem. Soc., 123, 6904 (2001).
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 6904
    • Kawano, M.1    Hirai, K.2    Tomioka, H.3    Ohashi, Y.4
  • 59
    • 4444264413 scopus 로고
    • Doctoral Dissertation, Massachusetts Institute of Technology
    • J. G. Jewett, Doctoral Dissertation, Massachusetts Institute of Technology (1962); V. P. Abbeg, Doctoral Dissertation, Massachusetts Institute of Technology (1967); N. M. Weinshenker, Doctoral Dissertation, Massachusetts Institute of Technology (1968).
    • (1962)
    • Jewett, J.G.1
  • 60
    • 4444258284 scopus 로고
    • Doctoral Dissertation, Massachusetts Institute of Technology
    • J. G. Jewett, Doctoral Dissertation, Massachusetts Institute of Technology (1962); V. P. Abbeg, Doctoral Dissertation, Massachusetts Institute of Technology (1967); N. M. Weinshenker, Doctoral Dissertation, Massachusetts Institute of Technology (1968).
    • (1967)
    • Abbeg, V.P.1
  • 61
    • 4444281245 scopus 로고
    • Doctoral Dissertation, Massachusetts Institute of Technology
    • J. G. Jewett, Doctoral Dissertation, Massachusetts Institute of Technology (1962); V. P. Abbeg, Doctoral Dissertation, Massachusetts Institute of Technology (1967); N. M. Weinshenker, Doctoral Dissertation, Massachusetts Institute of Technology (1968).
    • (1968)
    • Weinshenker, N.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.