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53
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4444368078
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note
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-2 M in 2-methyltetrahydrofuran, a quantum yield for the disappearance of 1 upon irradiation with the uranium glass-filtered radiation of a medium pressure Hg lamp of 9.4 was estimated by uranyl oxalate actinometry.
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54
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2c and hence we assume that those carbenes can exist in a perturbed structure on the soft energy surface. This has been shown by in situ X-ray crystallographic observation of triplet bis(2,4,6- trichlorophenyl)carbene trapped in a crystal. In this case, the observed structure of triplet carbene is different from the DFP optimized one and is corresponding to a non-global minimum on very shallow potentials. Such perturbation is ascribable to the steric effect in a crystalline lattice. See, M. Kawano, K. Hirai, H. Tomioka, and Y. Ohashi, J. Am. Chem. Soc., 123, 6904 (2001).
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