Jacobsen catalyst anchored onto an activated carbon as an enantioselective heterogeneous catalyst for the epoxidation of alkenes

Carbon

Volumn 42, Issue 14, 2004, Pages 3027-3030

  Silva, Ana Rosa ^a   Freire, Cristina ^a   De Castro, Baltazar ^a  

^a UNIVERSITY OF PORTO   (Portugal)

Author keywords

A. Activated carbon, Chemically modified carbons; B. Catalyst, Catalyst support; D. Catalytic properties

Indexed keywords

ADSORPTION; CATALYSIS; CATALYST ACTIVITY; COMPLEXATION; GAS CHROMATOGRAPHY; INDUCTIVELY COUPLED PLASMA; MANGANESE; OLEFINS; ORGANIC POLYMERS; OXIDATION; PHENOLS; POROUS MATERIALS; SOLUBILITY; THERMAL EFFECTS; X RAY PHOTOELECTRON SPECTROSCOPY; ZEOLITES;

CATALYST, CATALYST SUPPORT; CATALYTIC PROPERTIES; CHEMICALLY MODIFIED CARBONS; EPOXIDATION;

ACTIVATED CARBON;

EID: 4444238097     PISSN: 00086223     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbon.2004.06.037     Document Type: Article

References (15)

1. Jacobsen EN, Wu MH. In: Pfaltz A, Wu EN, Yamamoto H, editors. Comprehensive asymmetric catalysis. Berlin: Springer-Verlag; 1999. p. 649-77.
2. Katsuki T. Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts. Coord Chem Rev 1995;140:189-214.
3. Fan Q-H, Li Y-M, Chan ASC. Recoverable catalysts for asymmetric organic synthesis. Chem Rev 2002;102(10):3385-466.
4. Rodríguez-Reinoso F. The role of carbon materials in heterogeneous catalysis. Carbon 1998;36(3):159-75.
5. Figueiredo JL, Pereira MFR, Freitas MMA, Órfão JJM. Modification of the surface chemistry of activated carbons. Carbon 1999;37(9):1379-89.
6. Silva AR, Freire C, de Castro B, Freitas MMA, Figueiredo JL. Anchoring of a nickel(II) Schiff base complex onto activated carbon mediated by cyanuric chloride. Micropor Mesopor Mater 2001;46(2-3):211-21.
7. Silva AR, Martins M, Freitas MMA, Valente A, Freire C, de Castro B, et al. Immobilisation of amine-functionalised nickel(II) Schiff base complexes onto activated carbon treated with thionyl chloride. Micropor Mesopor Mater 2002;55(3):275-84.
8. Silva AR, Freire C, de Castro B, Freitas MMA, Figueiredo JL. Heterogenization of a functionalized copper(II) Schiff base complex by direct immobilization onto an oxidized activated carbon. Langmuir 2002; 18(21):8017-24.
9. Silva AR, Martins M, Freitas MMA, Figueiredo JL, Freire C, de Castro B. Anchoring of copper(II) acetylacetonate onto an activated carbon functionalised with a triamine. Eur J Inorg Chem 2004(10):2027-35.
10. Silva AR, Vital J, Figueiredo JL, Freire C, de Castro B, Activated carbons with immobilised manganese(III) salen complexes as heterogeneous catalysts in the epoxidation of olefins: influence of support and ligand functionalisation on selectivity and reusability. New J Chem 2003;27(10):1511-7.
11. Silva AR, Figueiredo JL, Freire C, de Castro B. Manganese(III) salen complexes anchored onto activated carbon as heterogeneous catalysts for the epoxidation of olefins, Micropor Mesopor Mater 2004;68(1-3):83-9.
12. Xiang S, Zhang Y, Xin Q, Li C. Enantioselective epoxidation of olefins catalyzed by Mn (salen)/MCM-41 synthesized with a new anchoring method. Chem Commun 2002(22):2696-7.
13. Palucki M, Pospisil PJ, Zhang W, Jacobsen EN. Highly enantio-selective, low-temperature epoxidation of styrene. J Am Chem Soc 1994;116(20):9333-4.
14. Song CE, Roh EJ, Yu BM, Chi DY, Kim SC, Lee K-J. Heterogeneous asymmetric epoxidation of alkenes catalysed by a polymer-bound (pyrrolidine salen)manganese(III) complex. Chem Commun 2000(7):615-6.
15. Bigi F, Moroni L, Maggi R, Sartori G. Heterogeneous enantio-selective epoxidation of olefins catalysed by unsymmetrical (salen)Mn(III) complexes supported on amorphous or MCM-41 silica through a new triazine-based linker. Chem Commun 2002:716-7.