Mechanism of interconversion of the silica-supported tin alkyl complexes (ΞSiO)3-nSn (n-C4H9)n+1, n = 0, 1, 2. Synthesis and characterization of the tin-containing polyhedral oligo-silsesquioxanes [(c-C5H9)7 Si8O12(CH3)2Sn(n-C4H9)3], [(c-C5H9)7Si7O11(OH)Sn(n-C4H9)2] and [(c-C5H9)7Si7 O12Sn(n-C4H9)] as possible models for the expected surface structures

Comptes Rendus Chimie

Volumn 7, Issue 8-9, 2004, Pages 785-796

  Nédez, Christophe ^a   Dufaud, Véronique ^a   Lefebvre, Frédéric ^a   Basset, Jean Marie ^a   Fenêt, Bernard ^a  

^a CPE LYON   (France)

Author keywords

Alkyltin; Silica; Silsesquioxanes; Solid state NMR; Thermolysis

Indexed keywords

BUTANE; BUTYLTIN DERIVATIVE; CARBON 13; HYDROXYL GROUP; ORGANOMETALLIC COMPOUND; ORGANOTIN COMPOUND; SILICON DERIVATIVE; SILICON DIOXIDE; TIN;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; DEALKYLATION; DECOMPOSITION; ELIMINATION REACTION; EXPERIMENTAL MODEL; HYDROLYSIS; HYDROXYLATION; INFRARED SPECTROSCOPY; MOLECULAR MODEL; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SURFACE PROPERTY; SYNTHESIS;

EID: 4444231279     PISSN: 16310748     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.crci.2003.09.013     Document Type: Article

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