Why does cyanide pretend to be a weak field ligand in [Cr(CN) 5]3-?

Inorganic Chemistry

Volumn 47, Issue 10, 2008, Pages 4413-4420

  Lord, Richard L ^a   Baik, Mu Hyun ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; CYANIDE; ION; LIGAND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTRON;

CHROMIUM COMPOUNDS; CYANIDES; ELECTRONS; IONS; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE;

EID: 44349131559     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic8000653     Document Type: Article

References (36)

1. Gütlich, P.; Goodwin, H. A. Spin Crossover in Transition Metal Compounds; Springer: Berlin, 2004.
2. Cotton, F. A.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry; Wiley: New York, 1999.
3. Tanabe, Y.; Sugano, S. J. Phys. Soc. Jpn. 1954, 9, 753-766.
4. Tanabe, Y.; Sugano, S. J. Phys. Soc. Jpn. 1954, 9, 766-779.
5. Eaton, J. P.; Nicholls, D. Transition Met. Chem. 1981, 6, 203-206.
6. Nelson, K. J.; Giles, I. D.; Shum, W. W.; Arif, A. M.; Miller, J. S. Angew. Chem., Int. Ed. 2005, 44, 3129-3132.
7. Meyer, H.-J.; Pickardt, J. Acta Crystallogr. C 1988, 44, 1715-1717.
8. Razak, I. A.; Shanmuga Sundara, R. S.; Fun, H.-K.; Tong, Y.-X.; Lu, Z.-L.; Kang, B.-S. Acta Crystallogr. C 2000, 56, 291-292.
9. Soria, D. B.; Piro, O. E.; Varetti, E. L.; Aymonino, P. J. J. Chem. Crystallog. 2001, 31, 471-477.
10. Antipin, M. Y.; Ilyukhin, A. B.; Kotov, V. Y. Mendeleev Commun. 2001, 210-211.
11. Antipin, M. Y.; Ilyukhin, A. B.; Kotov, V. Y.; Lokshin, B. V.; Seifer, G. B.; Chuvaev, V. F.; Yaroslavtsev, A. B. Russ. J. Inorg. Chem. 2002, 47, 1031-1037.
12. Ferlay, S.; Bulach, V.; Felix, O.; Hosseini, M. W.; Planeix, J. M.; Kyritsakas, N. CrystEngComm 2002, 447-453.
13. Kotov, V. Y.; Ilyukhin, A. B. Mendeleev Commun. 2003, 169-170.
14. Malarova, M.; Kuchar, J.; Cernak, J.; Massa, W. Acta Crystallogr. C 2003, 59, M280-M282.
15. Bie, H. Y.; Lu, J.; Yu, J. H.; Sun, Y. H.; Zhang, X.; Xu, J. Q.; Pan, L. Y.; Yang, Q. X. J. Coord. Chem. 2004, 57, 1603-1609.
16. Deeth, R. J. Eur. J. Inorg. Chem. 2006, 2551-2555.
17. Parr, R. G.; Yang, W. Density Functional Theory of Atoms and Molecules; Oxford University Press: New York, 1989.
18. Baerends, E. J.; Gritsenko, O. V. J. Phys. Chem. A 1997, 101, 5383-5403.
19. Klamt, A.; Schüürmann, G. J. Chem. Soc., Perkin Trans. 2 1993, 799-805.
20. Amsterdam Density Functional, version 2005.01; Vrije Universiteit Amsterdam: Amsterdam, The Netherlands, 2005.
21. Reiher, M.; Salomon, O.; Hess, B. A. Theor. Chem. Acc. 2001, 107, 48-55.
22. Salomon, O.; Reiher, M.; Hess, B. A. J. Chem. Phys. 2002, 117, 4729-4737.
23. Swart, M.; Groenhof, A. R.; Ehlers, A. W.; Lammertsma, K. J. Phys. Chem. A 2004, 108, 5479-5483.
24. Becke, A. D. J. Chem. Phys. 1993, 98, 5648-5652.
25. Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B 1988, 37, 785-789.
26. Van Lenthe, E.; E, J. B. J. Comput. Chem. 2003, 24, 1142-1156.
27. van Lenthe, E.; van Leeuwen, R.; Baerends, E. J.; Snijders, J. G. Int. J. Quantum Chem. 1996, 57, 281-293.
28. van Lenthe, E.; Baerends, E. J.; Snijders, J. G. J. Chem. Phys. 1993, 99, 4597-4610.
29. Pye, C. C.; Ziegler, T. Theor. Chem. Acc. 1999, 101, 396-408.
30. Ziegler, T.; Rauk, A. Theor. Chim. Acta 1977, 46, 1-10.
31. Velde, G. T.; Bickelhaupt, F. M.; Baerends, E. J.; Guerra, C. F.; Van Gisbergen, S. J. A.; Snijders, J. G.; Ziegler, T. J. Comput. Chem. 2001, 22, 931-967.
32. Albright, T. A.; Burdett, J. K.; Whangbo, M.-H. Orbital Interactions in Chemistry; John Wiley & Sons: New York, 1985.
33. Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press Inc.: London, 1976.
34. Hume, D. N.; Kolthoff, I. M. J. Am. Chem. Soc. 1943, 65, 1897-1901.
35. Jeftic, L.; Feldberg, S. W. J. Phys. Chem. 1971, 75, 2381.
36. Feldberg, S. W.; Jeftic, L. J. Phys. Chem. 1972, 76, 2439.