Supercritical fluid assisted, integrated process for the synthesis and separation of different lipid derivatives

Journal of Separation Science

Volumn 31, Issue 8, 2008, Pages 1346-1351

  Weber, Andreas ^a   Catchpole, Owen ^b   Eltringham, Wayne ^b  

^a Goshen Biotech Inc   (South Korea)

^b CALLAGHAN INNOVATION   (New Zealand)

Author keywords

Alcoholysis; Enzyme; Supercritical

Indexed keywords

DERIVATIVES; ENZYMES; ESTERIFICATION; LIPIDS; REACTION RATES; SEPARATION;

ETHYL ESTERS; GLYCERIDES;

SUPERCRITICAL FLUID EXTRACTION;

ACYLGLYCEROL; CARBON DIOXIDE; CORN OIL; FISH OIL; LIPID; MONOUNSATURATED FATTY ACID; POLYUNSATURATED FATTY ACID; TRIACYLGLYCEROL;

ALCOHOLYSIS; ARTICLE; ATMOSPHERIC PRESSURE; CONTROLLED STUDY; ESTERIFICATION; INTERMETHOD COMPARISON; LIPID ANALYSIS; PRIORITY JOURNAL; SEPARATION TECHNIQUE; SUPERCRITICAL FLUID; SUPERCRITICAL FLUID EXTRACTION; SYNTHESIS;

CARBON DIOXIDE; CHROMATOGRAPHY, SUPERCRITICAL FLUID; CORN OIL; EQUIPMENT DESIGN; ESTERIFICATION; ESTERS; FATTY ACIDS; FISH OILS; GLYCERIDES; LIPIDS; PRESSURE; TEMPERATURE; TIME FACTORS; TRIGLYCERIDES;

ZEA MAYS;

EID: 44349084152     PISSN: 16159306     EISSN: 16159314     Source Type: Journal    
DOI: 10.1002/jssc.200800082     Document Type: Article

References (15)

1. Sharma, R., Chisti, Y., Banerjee, U. C., Production, purification, characterization, and applications of lipases. Biotechnol. Adv. 2001, 19, 627-662.
2. Paiva, A. L., Malcata, F. X., Integration of reaction and separation with lipases: An overview. J. Mol. Catal., B Enzym. 1997, 3, 99-109.
3. Woolley, P., Peterson, S. B. (Eds.), Lipases - Their Structure, Biochemistry and Applications. Cambridge University Press, Cambridge 1994.
4. Bornscheuer, U. T. (Ed.), Enzymes in Lipid Modification. Wiley-VCH, Weinheim 2000.
5. Torres, C. F., Moeljadi, M., Hill, C. G., Jr., Lipase-catalyzed ethanolysis of fish oils: Multi-response kinetics. Biotechnol. Bioeng. 2003, 83, 274-281.
6. Shimada, Y., Sugihara, A., Tominaga, Y., Enzymatic purification of polyunsaturated fatty acids. J. Biosci. Bioeng. 2001, 91, 529-538.
7. Gunnlaugsdottir, H., Jaremo, M., Sivik., B., Process parameters influencing ethanolysis of cod liver oil in supercritical carbon dioxide. J. Supercrit. Fluids 1998, 12, 85-93.
8. Shimada, Y., Watanabe, Y., Sugihara, A., Tominaga, Y., Enzymatic alcoholysis for biodieselfuel production and application of the reaction to oil processing. J. Mol. Catal., B Enzym. 2002, 17, 133-142.
9. King, J. W., Sable-Demessie, E., Temelli, F., Teel, J. A., Thermal gradient fractionation of glyceride mixtures under supercritical fluid conditions. J. Supercrit. Fluids 1997, 10, 127-137.
10. Gironi, F., Maschietti, M., Semi-batch fractionation of fatty acids ethyl esters by means of supercritical carbon dioxide. 7th Italian Conference on Supercritical Fluids and Their Applications, I.S.A.S.F., June 13th-16th 2004.
11. Knez, Z., Habulin, M., Primožičk, M., Enzymatic reactions in dense gases. Biochem. Eng. J., 2005, 27, 120-126.
12. Holcapek, M., Jandera, P., Fischer, J., Prokes, B., Analytical monitoring of the production of biodiesel by high-performance liquid chromatography with various detection methods. J. Chromatogr. A 1999, 858, 13-31.
13. Weber, A., Chun, B.-S., Lee, E.-H., Shin, S.-K., Supercritical fluid assisted, integrated process for by-products from fat and lipid production. Chem. Eng. Technol. 2007, 30, 732.
14. Goddard, R., Bosley, J., Al-Duri, B., Esterification of oleic acid and ethanol in plug flow (packed bed) reactor under supercritical conditions - investigation of kinetics. J. Supercrit. Fluids 2000, 18, 121-130.
15. Ramamurthi, S., McCurdy, A. R., Lipase-catalysed esterification of oleic acid and methanol in hexane - a kinetic study. J. Am. Oil Chem. Soc. 1994, 71, 927-930.