Characterization of (Fe′Zr,Ti - VO ••)• defect dipoles in (La,Fe)-codoped PZT 52.5/47.5 piezoelectric ceramics by multifrequency electron paramagnetic resonance spectroscopy

IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control

Volumn 55, Issue 5, 2008, Pages 1061-1068

  Erdem, Emre ^a   Eichel, Rüdiger A ^a   Kungl, Hans ^b   Hoffmann, Michael J ^b   Ozarowski, Andrew ^c   Van Tol, Johan ^c   Brunel, Louis Claude ^c  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF KARLSRUHE   (Germany)

^c FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC DIPOLE MOMENTS; IRON COMPOUNDS; OXYGEN VACANCIES; PARAMAGNETIC RESONANCE;

DEFECT DIPOLES; FERROELECTRIC AGING; INTERNAL BIAS FIELD;

PIEZOELECTRIC CERAMICS;

LEAD; LEAD TITANATE ZIRCONATE; TITANIUM; ZIRCONIUM;

ARTICLE; ARTIFICIAL MEMBRANE; CERAMICS; CHEMISTRY; CRYSTALLIZATION; ELECTRIC CONDUCTIVITY; ELECTRON SPIN RESONANCE; MATERIALS TESTING; METHODOLOGY;

CERAMICS; CRYSTALLIZATION; ELECTRIC CONDUCTIVITY; ELECTRON SPIN RESONANCE SPECTROSCOPY; LEAD; MATERIALS TESTING; MEMBRANES, ARTIFICIAL; TITANIUM; ZIRCONIUM;

EID: 44249113842     PISSN: 08853010     EISSN: None     Source Type: Journal    
DOI: 10.1109/TUFFC.2008.757     Document Type: Conference Paper

References (44)

1. P. V. Lambeck G. H. Jonker The nature of domain stabilization in ferroelectric perovskites J. Phys. Chem. Solids 47 453 461 1986
2. B. Jaffe W. R. Cook H. Jaffe Piezoelectric Ceramics 1971 Academic Press London
3. M. J. Hoffmann H. Kungl High strain lead-based perovskite ferroelectrics C'urr. Op. Solid State Mat. Sci. 8 51 57 2004
4. H. Neumann G. Arlt Dipole orientation in Cr-modified BaTiO3 ceramics Ferroelectrics 76 303 310 1987
5. K. Carl K. H. Härdtl Electrical after effects in Pb(Ti,Zr)O3 ceramics Ferroelectrics 17 473 1978
6. S. Takahashi Effects of impurity doping in lead zirconatetitanate ceramics Ferroelectrics 41 143 1982
7. G. Arlt H. Neumann The role of domain walls on the dielectric, elastic and piezoelectric properties of ferroelectric ceramics Ferroelectrics 76 451 1987
8. R.-A. Eichel Defect structure of oxide ferroelectrics—Valence state, site of incorporation, mechanisms of charge compensation and internal bias fields J. Electroceram. 19 9 21 2007
9. R.-A. Eichel Characterization of defect structure in acceptor-modified piezoelectric ceramics by multifrequency and multipulse electron paramagnetic resonance spectroscopy J. Am. Ceram. Soc. 91 691 701 2008
10. H. Meštrić R.-A. Eichel K.-P. Dinse A. Ozarowski J. van Tol L. C. Brunei High-frequency electron paramagnetic resonance investigation of the Fe3+ impurity center in polycrystalline PbTiO3 in its ferroelectric phase J. Appl. Phys. 96 7440 7444 2004
11. H. Meštrić R.-A. Eichel T. Kloss K.-P. Dinse S. Laubach S. Laubach P. C. Schmidt Iron-oxygen vacancy defect centers in PbTiO3: Newman superposition model analysis and density functional calculations Phys. Rev. B 71 2005
12. R.-A. Eichel H. Meštrić K.-P. Dinse A. Ozarowski J. van Tol L. C. Brunel H. Kungl M. J. Hoffmann High-field/high-frequency EPR of paramagnetic functional centers in Cu2+-and Fe3+-modified polycrystalline Pb[Zrx Ti1-x ]O3 ferroelectrics Magn. Reson. Chem. 43 S166 S176 2005
13. H. Meštrić R.-A. Eichel K.-P. Dinse A. Ozarowski J. van Tol L. C. Brunel H. Kungl M. J. Hoffmann K. A. Schönau M. Knapp H. Fuess Iron-oxygen vacancy defect association in polycrystalline iron-modified PbZrO3 antiferroelectrics: Multifrequency electron paramagnetic resonance and Newman superposition model analysis Phys. Rev. B 73 2006
14. E. Erdem R. Böttcher H. C. Semmelhack H. J. Gläsel E. Hartmann Multi-frequency EPR studyof Cr3+ doped lead titanate (PbTiO3) nanopowders Phys. Stat. Sol. (b) 239 R7 R9 2003
15. R.-A. Eichel H. Kungl M. J. Hoffmann Determination of fimctional center local environment in copper-modified Pb[Zr0.54Ti0.46]O3 ceramics J. Appl. Phys. 95 8092 8096 2004
16. R.-A. Eichel K.-P. Dinse H. Kungl M. J. Hoffmann A. Ozarowski J. van Tol L. C. Brunel Exploring the morphotropic phase boundary in copper(II)-modifed Pb[Zro.54Ti0.46]O3 ferroelectrics Appl. Phys. A 80 51 54 2005
17. M. Hammer M. J. Hoffmann Sintering model for mixed-oxide-derived lead zirconate titanate ceramics J. Amer. Ceram. Soc. 81 3277 3284 1998
18. E. Erdem R.-A. Eichel H. Kungl M. J. Hoffmann A. Ozarowski H. van Tol L. C. Brunel Local symmetryreduction in tetragonal (La,Fe)-codoped Pb[Zr0.4Ti0.6]O3 piezoelectric ceramics Physica Scripta T129 12 16 2007
19. J. van Tol L. C. Brunel R. J. Wylde A quasioptical transient electron spin resonance spectrometer operating at 120 and 240 GHz Rev. Sci. Instrum. 76 2005
20. A. Abragam B. Bleaney Electron Paramagnetic Resonance of Transition Ions 1970 Clarendon Oxford
21. C. Rudowicz Magn. Reson. Rev. 13 1 89 1987
22. V. G. Grachev Correct expression for generalized spin-Hamiltonian of non-cubic paramagnetic center Sov. Phys. JETP 65 1029 1035 1987
23. D. J. Newman B. Ng The superposition model of crystal fields Rep. Prog. Phys. 52 699 763 1989
24. S. C. Chen D. J. Newman The orbit-lattice interaction for lanthanide ions: superposition model analysis for arbitrary symmetry Aust. J. Phys. 35 133 145 1982
25. C. Rudowicz Transformation relations for the conventional and normalised Stevens operator equivalents J. Phys. C: Solid State Phys. 18 1415 1430 1985
26. K. S. Misra Angular variation of electron paramagnetic resonance spectrum: Simulation of a polycrystalline EPR spectrum J. Magn. Res. 137 8392 1999
27. E. Siegel K. A. Muller Structure of transition-metal-oxygen-vacancy pair centers Phys. Rev. B 19 109 1979
28. D. J. Newman E. Siegel Superposition model analysis of Fe3+ and Mn2+ spin-Hamiltonian parameters J. Phys. C 9 4285 1976
29. B. Noheda J. A. Gonzalo L. E. Cross R. Guo S. E. Park D. E. Cox G. Shirane Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of Pb[Zr0.52Ti0.48]O3 Phys. Rev. B 61 8687 8695 2000
30. G. Arlt H. Neumann Internal bias in ferroelectric ceramics: Origin and time dependence Ferroelectrics 87 109 120 1988
31. G. Arlt P. Sasko Domain configuration and equilibrium size of domains in BaTiOs ceramics J. Appl. Phys. 51 4956 1980
32. G. Arlt D. Hennings G. de With Dielectric properties of fine-grained barium titanate ceramics J. Appl. Phys. 58 1619 1985
33. G. Arlt Microstructure and domain effects in ferroelectric ceramics Ferroelectrics 91 3 7 1989
34. H. Neumann Das innere Feld in akzeptor-dotierter Bariumtitanat Keramik 1988 RWTH-Rheinisch Westfälische Technische Hochschule Germany, Aachen
35. K. W. Plessner Ageing of the dielectric properties of barium titanate ceramics Proc. Phys. Soc. 73 1261 Proc. Phys. Soc. 1956
36. B. Lewis Proc. Phys. Soc. 73 17 Proc. Phys. Soc. 1960
37. A. Miserova Aging of barium titanate single crystals Sol. State Phys. 2 1276 1960
38. S. Pöykkö D. J. Chadi Dipolar defect model for fatigue in ferroelectric perovskites Phys. Rev. Lett. 83 1231 1999
39. G. E. Pike W. L. Warren D. Dimos B. A. Tuttle R. Ramesh J. Lee V. G. Keramidas J. T. Evans Voltage offsets in (Pb,La)(Zr,Ti)O3 thin films Appl. Phys. Lett. 66 484 1995
40. A. K. Tagantsev I. Stolichnov E. L. Colla N. Setter Polarization fatigue in ferroelectric films: Basic experimental findings, phenomenological scenarios, and microscopic features J. Appl. Phys. 90 1387 1402 2001
41. U. Robels C. Zadon G. Arlt Linearization of dielectric nonlinearity by internal bias fields Ferroelectrics 133 163 168 1992
42. X. Ren Large electric-field-induced strain in ferroelectric crystals by point-defect mediated reversible domain switching Nature Mater. 3 91 94 2004
43. W. L. Warren D. Dimos G. E. Pike K. Vanheusden R. Ramesh Alignment of defect dipoles in polycrystalline ferroelectrics Appl. Phys. Lett. 67 1689 1691 1995
44. W. L. Warren G. E. Pike K. Vanheusden D. Dimos B. A. Tuttle J. Robertson Defect-dipole alignment and tetragonal strain in ferroelectrics J. Appl. Phys. 79 9250 9257 1996