Upper-rim CMPO-substituted calix[6]- and calix[8]arene extractants for the An3+/Ln3+ separation from radioactive waste

Radiochimica Acta

Volumn 96, Issue 4-5, 2008, Pages 235-239

  Sansone, F ^a   Galletta, M ^b   Macerata, E ^b   Trivellone, E ^b   Giola, M ^b   Ungaro, R ^a   Bohmer V ^c   Casnati, A ^a   Mariani, M ^b  

^a UNIVERSITY OF PARMA   (Italy)

^b POLITECNICO DI MILANO   (Italy)

^c JOHANNES GUTENBERG UNIVERSITY   (Germany)

Author keywords

Actinides complexation; Actinides lanthanides separation; Calixarenes; CMPO; Multicoordinate ligands; Radioactive waste treatment

Indexed keywords

EID: 44249090066     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2008.1484     Document Type: Article

References (13)

1. Madic, C., Cordier, P. Y.: Process for the selective separation of actinides (III) and lanthanides (III). l'Energie Atomique, Fr and Compagnie General. 97-9452(2313471). 12-5-1997. GB, Chem. Abs. 128:209974. Ref Type: Patent.
2. Choppin, G. R., Nash, K. L.: Actinide separation science. Radiochim. Acta 70/71, 225 (1995).
3. Mathur, J. N., Murali, M. S., Nash, K. L.: Actinide partitioning - a review. Solvent Extr. Ion Exch. 19, 357 (2001).
4. Baldini, L., Casnati, A., Sansone, F., Ungaro, R.: Calixarene-based multivalent ligands. Chem. Soc. Rev. 36, 254 (2007).
5. Dam, H. H., Reinhoudt, D. N., Verboom, W.: Multicoordinate ligands for actinide/lanthanide separations. Chem. Soc. Rev. 36, 367 (2007).
6. Barboso, S., Carrera, A. G., Matthews, S. E., Arnaud-Neu, F., Böhmer, V., Dozol, J. F., Rouquette, H., Schwing-Weill, M. J.: Calix[4]arenes with CMPO functions at the narrow-rim. Synthesis and extraction properties. J. Chem. Soc. Perkin Trans. 2, 719 (1999).
7. Arnaud-Neu, F., Böhmer, V., Dozol, J. F., Grüttner, C., Jakobi, R. A., Kraft, D., Mauprivez, O., Rouquette, H., Schwing-Weill, M. J., Simon, N., Vogt, W.: Calixarenes with diphenylphosphoryl acetamide functions at the upper rim. A new class of highly efficient extractants for lanthanides and actinides. J. Chem. Soc. Perkin Trans. 2, 1175 (1996).
8. Arduini, A., Böhmer, V., Delmau, L., Desreux, J. F., Dozol, J. F., Carrera, M. A. G., Lambert, B., Musigmann, C., Pochini, A., Shivanyuk, A., Ugozzoli, F.: Rigidified calixarenes bearing four carbamoylmethylphosphineoxide or carbamoylmethylphosphoryl functions at the wide rim. Chem. Eur. J. 6, 2135 (2000).
9. Boerrigter, H., Verboom, W., Reinhoudt, D. N.: Novel resorcinarene cavitand-based CMP(O) cation ligands: Synthesis and extraction properties. J. Org. Chem. 62, 7148 (1997).
10. Peters, M. W., Werner, E. J., Scott, M. J.: Enhanced selectivity for actinides over lanthanides with CMPO ligands secured to a C-3-symmetric triphenoxymethane platform. Inorg. Chem. 41, 1707 (2002).
11. Delmau, L. H., Simon, N., Schwing-Weill, M. J., Arnaud-Neu, F., Dozol, J. F., Eymard, S., Tournois, B., Böhmer, V., Grüttner, C., Musigmann, C., Tunayar, A.: 'CMPO-substituted' calix[4]arenes, extractants with selectivity among trivalent lanthanides and between trivalent actinides and lanthanides. Chem. Commun. 1627 (1998).
12. (3+) from radioactive waste. Tetrahedron 62, 6749 (2006).
13. Dudic, M., Colombo, A., Sansone, F., Casnati, A., Donofrio, G., Ungaro, R.: A general synthesis of water soluble upper rim calix[n]arene guanidinium derivatives which bind to plasmid DNA. Tetrahedron 60, 11 613 (2004).