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Crystal data for 1: C225H360Mn 38O123P12, M, 7491.51, orthorhombic, space group Pca21, a, 39.306(5) Å, b, 15.355(2) Å, c, 26.803(4) Å, V, 16177(4) Å3, Z, 4, Dc, 1.537 g cm -3, Mo Kα radiation, λ, 0.710 73 Å, T, 110(2) K, 2θmax, 46.7°, 68 829 reflections collected, 23 251 unique (Rint, 0.0783, Final GOF, 1.070, R1, 0.0620, wR2, 0.1383, refine_diff_density_max 1.008, refine_diff_density_min -1.063, b) Crystal data for 2: C297.32-H324Mn 32N4O117P16, M, 8075.41, triclinic, space group P1, a, 18.777(6) Å, b, 20.334(7) Å, c, 25.575(8) Å, α, 79.139(6)°, β, 75.266(6)°, λ, 82.2426
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int = 0.0757). Final GOF = 1.071, R1 = 0.0821, wR2 = 0.2036, refine_diff_density_max 1.383, refine diff_density_min -1.220.
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