XANES-EXAFS analysis of se solid-phase reaction products formed upon contacting Se(IV) with FeS2 and FeS

Environmental Science and Technology

Volumn 42, Issue 10, 2008, Pages 3595-3601

  Breynaert, E ^a   Bruggeman, C ^a,b   Maes, A ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

^b BELGIAN NUCLEAR RESEARCH CENTRE   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

NEGATIVE IONS; REDUCTION; SORPTION; WASTE DISPOSAL; X RAY ABSORPTION SPECTROSCOPY;

DISSOLVED SULFIDE; OXIDATION STATE;

SELENIUM;

MINERAL; PYRITE; SELENITE; SELENIUM DERIVATIVE; SULFIDE; TROILITE;

NEGATIVE IONS; REDUCTION; SELENIUM; SORPTION; WASTE DISPOSAL; X RAY ABSORPTION SPECTROSCOPY;

ANION; EXPERIMENTAL STUDY; OXIDATION; PYRITE; SELENIUM; SPECIATION (CHEMISTRY); TROILITE; XANES SPECTROSCOPY;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; GEOCHEMISTRY; OXIDATION KINETICS; REDUCTION; SOLID; VALIDATION PROCESS; X RAY ABSORPTION FINE STRUCTURE; X RAY ABSORPTION NEAR EDGE SPECTROSCOPY;

FERROUS COMPOUNDS; FOURIER ANALYSIS; SELENIUM; SPECTRUM ANALYSIS; X-RAYS;

EID: 43749085142     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es071370r     Document Type: Article

References (44)

1. Geering, H. R.; Cary, E. E.; Jones, L. H. P.; Alloway, W. H. Solubility and redox criteria for the possible forms of selenium in soils. Soil Sci. Soc. Am. Proc. 1968, 32, 35-40.
2. Olin, A.; Noläng, B.; Osadchii, E. G.; Öhman, L.-O.; Rosén, E. Chemical Thermodynamics of Selenium; Chemical Thermodynamics Series, Vol. 7; Data Bank, OECD Nuclear Energy Agency: Issy-les-Moulineaux, France, 2005.
3. Baeyens, B.; Maes, A.; Cremers, A.; Henrion, P. N. Radioactive Waste Managment, Harwood Academic: Amsterdam, 1985; Vol. 6, pp 391-408.
4. De Craen, M.; Van Geet, M.; Wang, L.; Put, M. High sulphate concentrations in squeezed boom clay pore water: Evidence of oxidation of clay cores. Phys. Chem. Earth 2004, 29, 91-103.
5. Beaucaire, C.; Pitsch, H.; Toulhoat, P.; Motellier, S.; Louvat, D. Regional fluid characterisation and modelling of water-rock equilibria in the boom clay formation and in the rupelian aquifer at Mol, Belgium. Appl. Geochem. 2000, 15, 667-686.
6. Frankenberger, W. T., Benson, S., Eds. Selenium in the Environment, Marcel Dekker Inc.; New York, 1994.
7. Masscheleyn, P. H.; Delaune, R. D.; Patrick, W. H. Transformations of selenium as affected by sediment oxidation reduction potential and pH. Environ. Sci. Technol. 1990, 24, 91-96.
8. 2, clay minerals and dissolved organic matter. Environ. Pollut. 2005, 137, 209-221.
9. Beauwens, T.; De Canniere, P.; Moors, H.; Wang, L.; Maes, N. Studying the migration behaviour of selenate in boom clay by electromigration. Eng. Geol. 2005, 77, 285-293.
10. Elson, C. M.; MacDonald, A. S. Determination of selenium in pyrite by an ion exchange electrothermal atomic-absorption spectrometric method. Anal. Chim. Acta 1979, 110, 153-156.
11. Velinsky, D. J.; Cutter, G. A. Determination of elemental selenium and pyrite-selenium in sediments. Anal. Chim. Acta 1990, 235, 419-425.
12. Belzile, N.; Chen, Y. W.; Xu, R. R. Early diagenetic behaviour of selenium in freshwater sediments. Appl. Geochem. 2000, 15, 1439-1454.
13. Masscheleyn, P. H.; Delaune, R. D.; Patrick, W. H. Biogeochemical behaviour of selenium in anoxic soils and sediments-An equilibrium thermodynamics approach. J. Environ. Sci. Health, Part A: Environ. Sci. Eng. Toxic Hazard. Subst. Control 1991, 26, 555-573.
14. Yllera de Llano, A.; Bidoglio, G.; Avogadro, A.; Gibson, P. S.; Rivas Romero, P. Redox reactions and transport of selenium through fractured granite. J. Contam. Hydrol. 1996, 21, 129-139.
15. 2-controlled reducing conditions. Radiochim. Acta 2002, 90, 629-635.
16. Myneni, S. C. B.; Tokunaga, T. K.; Brown, G. E. Abiotic selenium redox transformations in the presence of Fe(ii,iii) oxides. Science 1997, 278, 1106-1109.
17. Zingaro, R. A.; Dufner, D. C.; Murphy, A. P.; Moody, C. D. Reduction of oxoselenium anions by iron(ii) hydroxide. Environ. Int. 1997, 23, 299-304.
18. Chirita, P.; Descostes, M. Anoxic dissolution of troilite in acidic media. J. Colloid Interface Sci. 2006, 294, 376-384.
19. Thomas, J. E.; Smart, R. S. C.; Skinner, W. M. Kinetic factors for oxidative and non-oxidative dissolution of iron sulfides. Miner. Eng. 2000, 13, 1149-1159.
20. Mees, D. R.; Pysto, W.; Tarcha, P. J. Formation of selenium colloids using sodium ascorbate as the reducing agent. J. Colloid Interface Sci. 1995, 170, 254-260.
21. Shaker, A. M. Kinetics of the reduction of Se(iv) to Se-sol. J. Colloid Interface Sci. 1996, 180, 225-231.
22. Zhang, H. Y.; Hu, Z. Q.; Lu, K. Transformation from the amorphous to the nanocrystalline state in pure selenium. Nanostruct. Mater. 1995, 5, 41-52.
23. Pejova, B.; Grozdanov, I. Solution growth and characterization of amorphous selenium thin films-Heat transformation to nanocrystalline gray selenium thin films. Appl. Surf. Sci. 2001, 177, 152-157.
24. Eggleston, C.; Ehrhardt, J.; Stumm, W. Surface structural controls on pyrite oxidation kinetics: An xps-ups, stm and modeling study. Am. Mineral. 1996, 81, 1036-1056.
25. Descostes, M.; Mercier, F.; Beaucaire, C.; Zuddas, P.; Trocellier, P. Nature and distribution of chemical species on oxidized pyrite surface: Complementarity of xps and nuclear microprobe analysis. Nucl. Instrum. Methods Phys. Res., Sect. B 2001, 181, 603-609.
26. George, G. N.; Pickering, I. J.; Stanford EXAFSPAK; Synchrotron Radiation Laboratory: Stanford, CA, 1995.
27. Ravel, B.; Newville, M. Athena, artemis, hephaestus: Data analysis for X-ray absorption spectroscopy using ifeffit. J. Synchrotron Radiat. 2005, 12, 537-541.
28. 2-). Spectrochim. Acta, Part B 2004, 59, 1681-1686.
29. Peak, D.; Saha, U. K.; Huang, P. M. Selenite adsorption mechanism on pure and coated montmorillonite: An exafs and xanes spectroscopic study. Soil Sci. Soc. Am. J. 2006, 70, 192-203.
30. Bunker, G. http://gbxafs.iit.edu/training/XANES_intro.pdf.
31. Pickering, I. J.; Brown, G. E.; Tokunaga, T. K. Quantitative speciation of selenium in soils using X-ray absorption spectroscopy. Environ. Sci. Technol. 1995, 29, 2456-2459.
32. Holton, J. M. Xanes measurements of the rate of radiation damage to selenomethionine side chains. J. Synchrotron Radiat. 2007, 14, 51-72.
33. Breynaert, E.; Maes, A. EXAFS and DFT-Mutually enhancing tools for structure identification and elucidation Environ. Sci. Technol., submitted for publication.
34. Zhao, Y. H.; Lu, K.; Liu, T. Exafs study of mechanical-milling-induced solid-state amorphization of Se. J. Non-Cryst. Solids 2004, 333, 246-251.
35. Kolobov, A. V.; Tanaka, K. Nanoscale mechanism of photoinduced metastability and reversible photodarkening in chalcogenide vitreous semiconductors. Semiconductors 1998, 32, 801-806.
36. Zhang, X. D.; Drabold, D. A. Direct molecular dynamic simulation of light-induced structural change in amorphous selenium. Phys. Rev. Lett. 1999, 83, 5042-5045.
37. Keller, R.; Holzapfel, W. B.; Schulz, H. Effect of pressure on atom positions in Se and Te. Phys. Rev. B 1977, 16, 4404-4412.
38. Hägg, G.; Kindström, A. L. Röntgenuntersuchung am system eisen-selen. Z. Phys. Chem. B 1933, 22, 453-464.
39. Wersin, P.; Hochella, M. F.; Persson, P.; Redden, G.; Leckie, J. O.; Harris, D. W. Interaction between aqueous uranium(vi) and sulfide minerals-Spectroscopic evidence for sorption and reduction. Geochim. Cosmochim. Acta 1994, 58, 2829-2843.
40. Rovira, M.; Gimenez, J.; Martinez, M.; Martinez-Llado, X.; de Pablo, J.; Marti, V.; Duro, L. Sorption of selenium(iv) and selenium(vi) onto natural iron oxides: Goethite and hematite J. Hazard. Mater., in press.
41. Martinez, M.; Giménez, J.; de Pablo, J.; Rovira, M.; Duro, L. Sorption of selenium(iv) and selenium(vi) on magnetite. Appl. Surf. Sci. 2006, 252, 3767-3773.
42. Hockin, S. L.; Gadd, G. M. Linked redox precipitation of sulfur and selenium under anaerobic conditions by sulfate-reducing bacterial biofilms. Appl. Environ. Microbiol. 2003, 69, 7063-7072.
43. Wyckoff, R. W. G. Crystal structures 1 (7-83), American Mineralogist Crystal Structure Database, 1963.
44. 2 single crystals by chemical transport reactions. J. Solid State Chem. 1975, 15, 366-368.