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Volumn 10, Issue 5, 2008, Pages 845-848

Three new polyketide-terpenoid hybrids from Penicillium sp

Author keywords

[No Author keywords available]

Indexed keywords

22 EPOXYBERKELEYDIONE; 22-EPOXYBERKELEYDIONE; BERKELEYDIONE; BERKELEYTRIONE; MACROLIDE; MINIOLUTELIDE A; MINIOLUTELIDE B; TERPENE;

EID: 43549123366     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol7029867     Document Type: Article
Times cited : (43)

References (12)
  • 2
    • 58149184299 scopus 로고    scopus 로고
    • 22-Epoxyberkeleydione (1, colorless amorphous; [α]25D +80.3 (c 0.11. MeOH, UV (MeOH) λmax (log ε) 211 (3.42) nni; CD (MeOH) Δε231 +7.27, Δε 268, 1.67, Δε311 +1.47; IR (neat) νmax 3508, 2987, 2951, 1732, 1714, 1240, 1122 cm-1;, )-HRESIMS m/z [M, Na, 495.1989 calcd for C 26H32O8Na, 495.1995
    • 8Na, 495.1995).
  • 5
    • 58149180563 scopus 로고    scopus 로고
    • MM2 calculation was performed using CS Chem3D Pro 9.0.1.
    • MM2 calculation was performed using CS Chem3D Pro 9.0.1.
  • 6
    • 58149198174 scopus 로고    scopus 로고
    • Miniolutelide A (3, colorless prism (MeOH/H2O, mp 186.5-187.2 °C; [α]23D +77.3 (c 0.23, CHC13, UV (EtOH) λmax (log ε) 268 (3.95) nm; CD (MeOH) Δε268 +18.62; IR (neat) νmax 3419, 2985, 1790, 1755, 1695, 1261, 1165. 1120. 974 cm-1; 1H NMR (C6D6, 400 MHz) δH 6.47 (1H. d, J, 1.3 Hz, H-13, 5.78 (1H, t, J, 1.7 Hz, H-14, 5.76 (1H, br s, H-2, 5.15 (1H, s, H-23, 4.10 (1H, q.J= 6.6 Hz. H-9, 3.36 (3H. s, OMe, 2.61 (1H, s. H-11, 2.23 (1H, m, H-5, 2.18 (1H, q, J= 6.8 Hz. H-4, 1.93 (1H, dd, J, 13.5, 2.2 Hz, H-6β, 1.45 (3H, d, J, 6.6 Hz, H-21, 1.33 (311, s, H-18, 1.29 (1H, s, 22-OH, 1.15 (3H, s. H-17, 0.90 (1H. t. J, 13.5 Hz, H-6α, 0.85 (3H, s, H-24, 0.82 (3H, s, H-19, 0.68 (3H. d, J, 6.8 Hz, H-25, 13C NMR C 6
    • 10Na, 527.1893).
  • 7
    • 58149191864 scopus 로고    scopus 로고
    • 10Na, 527.1893).
    • 10Na, 527.1893).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.