Removal and recovery of nitriles from gaseous streams: An IR study of acetonitrile adsorption on and desorption from inorganic solids

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 320, Issue 1-3, 2008, Pages 205-212

  Busca, Guido ^a   Montanari, Tania ^a   Bevilacqua, Maria ^a   Finocchio, Elisabetta ^a  

^a UNIVERSITY OF GENOA   (Italy)

Author keywords

Acetonitrile separation; Adsorption; Alumina adsorbents; Clay adsorbents; Hydrocarbon purification; Infrared spectroscopy; Nitrile adsorption; Oxide adsorbents; Silica adsorbents; Zeolite adsorbents

Indexed keywords

ACETONITRILE; ADSORPTION; DESORPTION; INFRARED SPECTROSCOPY; PURIFICATION; RECOVERY; REMOVAL; ZEOLITES;

ACETONITRILE SEPARATION; ALUMINA ADSORBENTS; CLAY ADSORBENTS; HYDROCARBON PURIFICATION; OXIDE ADSORBENTS; ZEOLITE ADSORBENTS;

NITRILE RESINS;

ACETONITRILE; ALKALI METAL; ALUMINUM OXIDE; LEWIS ACID; METAL OXIDE; NITRILE; SILICON DIOXIDE; ZEOLITE;

ADSORPTION; ANALYTIC METHOD; ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION; CLAY; DESORPTION; HYDROGEN BOND; INFRARED SPECTROSCOPY; PRIORITY JOURNAL; TEMPERATURE;

EID: 43449116348     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2008.01.048     Document Type: Article

References (31)

1. P. Pollak G. Romeder F. Hagedorn H.-P. Gelbke Nitriles Ullmann's Encyclopedia of Industrial Chemistry, Copyright© 2002 2002 Wiley-VCH Verlag GmbH & Co. KGaA
2. K. Weissermel H.J. Arpe Industrial Organic Chemistry third ed. 1997 VCH Weinheim p. 307
3. N.L. Morrow The industrial production and use of 1,3-butadiene Environ. Health Persp. 86 7 1990 8
4. http://www.atsdr.cdc.gov/toxpro2.html .
5. 3CN) in the atmosphere J. Geophys. Res. 108 2003 4329
6. M. Di Girolamo M. Marchionna Acidic and basic ion exchange resins for industrial applications J. Mol. Catal. A: Chem. 177 2001 33 40
7. F. Ancillotti V. Fattore Oxygenate fuels: market expansion and catalytic aspect of synthesis Fuel Process. Technol. 57 1998 163 194
8. G. Busca Acid catalysts in industrial hydrocarbon chemistry Chem. Rev. 107 2007 5366 5410
9. M. Marchionna M. Di Girolamo R. Patrini Light olefins dimerization to high quality gasoline components Catal. Today 65 2001 397 403
10. M. Quiroga M.R. Capeletti N. Figoli U. Sedran Catalyst deactivation by acetonitrile in MTBE synthesis Appl. Catal. A Gen. 177 1999 37 42
11. S.J. Frey; P.R. Cottrell, D.A. Hamm, Process for removal of nitriles from etherification feedstocks, US Patent 5,672,772 assigned to UOP.
12. 5 nuts: 2. Via catalytic hydrogenation Ind. Eng. Chem. Res. 41 2002 5385 5392
13. 5 cuts: 1. Adsorption Adsorpt. Sci. Technol. 23 2005 813 825
14. Almatis, Technical bulletin http://www.coastalchem.com/PDFs/Alcoa/Applications%20for%20Selective%20Adsorbents%20in%20Etherification%20Processes.pdf .
15. Adsorbents for the Motor Fuel HF Alkylation Process, http://www.uop.com/adsorbents/7052.html .
16. R.J. Schmidt, A.S. Zarchy, G.J. Gajda, G.B. Woodle, D.-Y. Jan, Process and apparatus for the removal of nitrogen compounds from a fluid stream, World Patent WO/2005/061420 to UOP.
17. NiGuard1, http://www.uop.com/objects/NiGuard1.pdf .
18. G. Busca Infrared studies of the reactive adsorption of organic molecules over metal oxides and of the mechanisms of their heterogeneously-catalyzed oxidation Catal. Today 27 1996 457 496
19. G. Busca, Use of infrared spectroscopy methods in the field of heterogeneous catalysis by metal oxides, in: S.D. Jackson, J.S.J. Hargreaves (Eds.), Oxides and Oxidation Catalysis, Wiley, in press
20. T. Armaroli E. Finocchio G. Busca S. Rossini A FT-IR study of the adsorption of C5 olefinic compounds on NaX zeolite Vibrat. Spectrosc. 20 1999 85 94
21. G. Bagnasco M. Turco G. Busca T. Armaroli A. Nastro P. De Luca Characterization of structural and gas adsorption properties of ETS-10 molecular sieve Adsorpt. Sci. Technol. 21 2003 683 696
22. 2 on LTA zeolites: an IR investigation Vibrat. Spectrosc. 46 2008 45 51
23. I. Salla T. Montanari P. Salagre Y. Cesteros G. Busca Fourier transform infrared spectroscopic study of the adsorption of CO and nitriles on Na-mordenite: evidence of a new interaction J. Phys. Chem., B 109 2005 915 922
24. H. Knözinger P. Ratnasamy Catalytic aluminas: surface models and characterization of surface sites Catal. Rev. Sci. Eng. 17 1978 31 70
25. J.F. Lambert M. Che The molecular approach to supported catalysts synthesis: state of the art and future challenges J. Mol. Catal. A Chem. 162 2000 5 18
26. H. Knözinger H. Krietenbrink Infrared spectroscopic study of the adsorption of nitriles on aluminium oxide. Fermi resonance in coordinated acetonitrile J. Chem. Soc. Faraday Trans. I 71 1975 2421 2430
27. J.C. Lavalley Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules Catal. Today 27 1996 377 401
28. E. Finocchio G. Busca S. Rossini U. Cornaro V. Piccoli R. Miglio FT-IR characterization of silicated aluminas, active olefin skeletal isomerization catalysts Catal. Today 33 1997 335 352
29. S. DelMastro G. Gozzellino D. Mazza M. Vallino G. Busca V. Lorenzelli Characterization of microporous amorphous alumina-boria J. Chem. Soc., Faraday Trans. I 88 1992 2065 2070
30. G. Busca G. Ramis V. Lorenzelli P.F. Rossi A. La Ginestra P. Patrono Phosphoric acid on oxide carriers. Part 1. Characterization of silica, alumina and titania impregnated by phosphoric acid Langmuir 5 1989 911 916
31. A. Gutierrez-Alejandre P. Castillo J. Ramirez G. Ramis G. Busca Redox and acid reactivity of wolframyl centers on oxide carriers: Bronsted, Lewis and redox sites Appl. Catal. A Gen. 216 2001 181 194