N,N'-disubstituted methylenediimidazolium salts: A versatile guest for various macrocycles

Journal of Organic Chemistry

Volumn 73, Issue 10, 2008, Pages 3784-3790

  Noujeim, Nadim ^a   Leclercq, Loïc ^a   Schmitzer, Andreea R ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; INCLUSIONS; SALTS; SOLUBILITY; SOLVENTS;

BINDING PARAMETERS; IMIDAZOLIUM SUBSTITUENTS; INCLUSION COMPLEXES; MACROCYCLIC HOSTS;

AROMATIC COMPOUNDS;

CALIXARENE; CROWN ETHER; CUCURBIT[7]URIL; CYCLODEXTRIN; DIBENZO 24 CROWN 8 ETHER; IMIDAZOLE DERIVATIVE; MACROCYCLIC COMPOUND; METHYLENEDIIMIDAZOLIUM SALT; TETRAPROPOXYCALIX[4]ARENE;

ARTICLE; COMPLEX FORMATION; ELECTRICITY; MASS SPECTROMETRY; MOLECULAR MODEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUCLEAR OVERHAUSER EFFECT; PHYSICAL CHEMISTRY; SOLUBILITY;

IMIDAZOLES; MACROCYCLIC COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; REFERENCE STANDARDS; SALTS; STEREOISOMERISM;

EID: 43449087026     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo702683c     Document Type: Article

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46. The ratio [bound imidazolium]/[unbound imidazolium] can be directly derived from the association constant for the formation of a 1:1 complex in the case of a slow complexation in the NMR time scale. See Supporting Information for details.