Influence of photoinitiator type on the rate of polymerization, degree of conversion, hardness and yellowing of dental resin composites

Dental Materials

Volumn 24, Issue 9, 2008, Pages 1169-1177

  Schneider, Luis Felipe J ^a   Pfeifer, Carmem S C ^b   Consani, Simonides ^a   Prahl, Scott A ^c   Ferracane, Jack L ^d  

^a UNIVERSITY OF CAMPINAS   (Brazil)

^b UNIVERSITY OF SÃO PAULO   (Brazil)

^c Oregon Health and Science University Department of Biomedical Engineering   (United States)

^d OREGON HEALTH AND SCIENCE UNIVERSITY   (United States)

Author keywords

Camphorquinone; Color; Molar extinction coefficient; Photoinitiators; Photon absorption; Polymerization; Reaction kinetics; Resin composite

Indexed keywords

CHEMICAL REACTIONS; DENTAL MATERIALS; MONOMERS; POLYMERIZATION; POLYMERS; RESINS;

DEGREE OF CONVERSION (DC); DENTAL RESIN COMPOSITES; PHOTOINITIATOR (PI); RATE OF POLYMERIZATION;

DENTAL COMPOSITES;

1 PHENYL 1,2 PROPANEDIONE; 1-PHENYL-1,2-PROPANEDIONE; 4 AMINOBENZOIC ACID; BIOMEDICAL AND DENTAL MATERIALS; BISPHENOL A BIS(2 HYDROXYPROPYL) ETHER DIMETHACRYLATE; CAMPHOROQUINONE; CHALCONE DERIVATIVE; DRUG DERIVATIVE; ETHYL 4 N,N DIMETHYLAMINOBENZOATE; ETHYL 4-N,N-DIMETHYLAMINOBENZOATE; MACROGOL DERIVATIVE; POLYMER; POLYMETHACRYLIC ACID DERIVATIVE; RESIN; TERPENE; TRIETHYLENE GLYCOL DIMETHACRYLATE; UNCLASSIFIED DRUG;

ABSORPTION; ARTICLE; CHEMISTRY; COLOR; COMPARATIVE STUDY; DIFFERENTIAL SCANNING CALORIMETRY; HARDNESS; HUMAN; INFRARED SPECTROSCOPY; MATERIALS TESTING; RADIATION DOSE; RADIATION EXPOSURE; ULTRAVIOLET SPECTROPHOTOMETRY;

4-AMINOBENZOIC ACID; ABSORPTION; BISPHENOL A-GLYCIDYL METHACRYLATE; CALORIMETRY, DIFFERENTIAL SCANNING; CHALCONES; COLOR; COMPOSITE RESINS; DENTAL MATERIALS; HARDNESS; HUMANS; MATERIALS TESTING; POLYETHYLENE GLYCOLS; POLYMERS; POLYMETHACRYLIC ACIDS; RADIATION DOSAGE; SPECTROPHOTOMETRY, ULTRAVIOLET; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; TERPENES;

EID: 43449084589     PISSN: 01095641     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.dental.2008.01.007     Document Type: Article

References (40)

1. Venhoven B.A., de Gee A.J., and Davidson C.L. Light initiation of dental resins: dynamics of the polymerization. Biomaterials 17 (1996) 2313-2318
2. Stansbury J.W. Curing dental resins and composites by photopolymerization. J Esthet Dent 12 (2000) 300-308
3. Jakubiak J., Allonas X., Fouassier J.P., Sionkowska A., Andrzejewska E., Linden L.A., and Rabek J.F. Camphorquinone-amines photoinitating systems for the initiation of free radical polymerization. Polymer 44 (2003) 5219-5226
4. Tsai L., and Charney E. The triplet states of α-dicarbonyls. J Phys Chem 73 (1969) 2462-2463
5. Shintani H., Inoue T., and Yamaki M. Analysis of camphorquinone in visible light-cured composite resins. Dent Mater 1 (1985) 124-126
6. Alvim H.H., Alecio A.C., Vasconcellos W.A., Furlan M., de Oliveira J.E., and Saad J.R. Analysis of camphorquinone in composite resins as a function of shade. Dent Mater 23 (2007) 1245-1249
7. Peutzfeldt A., and Asmussen E. Hardness of restorative resins: effect of camphorquinone, amine, and inhibitor. Acta Odontol Scand 47 (1989) 229-231
8. Cook W.D. Photopolymerization kinetics of dimethacrylates using the camphorquinone/amine initiator system. Polymer 33 (1992) 600-609
9. Yoshida K., and Greener E.H. Effect of photoinitiator on degree of conversion of unfilled light-cured resin. J Dent 22 (1994) 296-299
10. Rueggeberg F.A., Ergle J.W., and Lockwood P.E. Effect of photoinitiator level on properties of a light-cured and post-cure heated model resin system. Dent Mater 13 (1997) 360-364
11. Kalliyana Krishnan V., and Yamuna V. Effect of initiator concentration, exposure time and particle size on the filler upon mechanical properties of a light-curing radiopaque dental composite. J Oral Rehabil 25 (1998) 747-751
12. Moin Jan C., Nomura Y., Urabe H., Okazaki M., and Shintani H. The relationship between leachability of polymerization initiator and degree of conversion of visible light-cured resin. J Biomed Mater Res 58 (2001) 42-46
13. Schroeder W.F., and Vallo C.I. Effect of different photoinitiator systems on conversion profiles of a model unfilled light-cured resin. Dent Mater 23 (2007) 1313-1321
14. Jakubiak J., Sionkowska A., Lindén L.A., and Rabek J.F. Isothermal photo differential scanning calorimetry. Crosslinking polymerization of multifunctional monomers in presence of visible light photoinitiators. J Therm Anal Calorim 65 (2001) 435-443
15. Taira M., Urabe H., Hirose T., Wakasa K., and Yamaki M. Analysis of photo-initiators in visible-light-cured dental composite resins. J Dent Res 67 (1988) 24-28
16. Park Y.J., Chae K.H., and Rawls H.R. Development of a new photoinitiation system for dental light-cure composite resins. Dent Mater 15 (1999) 120-127
17. Janda R., Roulet J.-F., Kaminsky M., Steffin G., and Latta M. Color stability of resin matrix restorative materials as a function of the method of light activation. Eur J Oral Sci 112 (2004) 280-285
18. Janda R., Roulet J.-F., Latta M., Kaminsky M., and Rüttermann St. Effect of exponential polymerization on color stability of resin-based filling materials. Dent Mater 23 (2007) 696-704
19. Neumann M.G., Miranda Jr. W.G., Schmitt C.C., Rueggeberg F.A., and Correa I.C. Molar extinction coefficients and the photon absorption efficiency of dental photoinitiators and light curing units. J Dent 33 (2005) 525-532
20. Neumann M.G., Schmitt C.C., Ferreira G.C., and Correa I.C. The initiating radical yields and the efficiency of polymerization for various dental photoinitiators excited by different light curing units. Dent Mater 22 (2006) 576-584
21. Sun G.J., and Chae K.H. Properties of 2,3-butanedione and 1-phenyl-1,2-propanedione as a new photosensitizers for visible light cured dental resin composites. Polymer 41 (2000) 6205-6212
22. Asmussen E., and Peutzfeldt A. Influence of composition on rate of polymerization contraction of light-curing resin composites. Acta Odontol Scand 60 (2002) 146-150
23. Emami N., and Söderholm K.J. Influence of light-curing procedures and photo-initiator/co-initiator composition on the degree of conversion of light-curing resins. J Mater Sci Mater Med 16 (2005) 47-52
24. Ogunyinka A., Palin W.N., Shortall A.C., and Marquis P.M. Photoinitiation chemistry affects light transmission and degree of conversion of curing experimental dental resin composites. Dent Mater 23 (2007) 807-813
25. Watts D.C. Reaction kinetics and mechanics in photo-polymerised networks. Dent Mater 21 (2005) 27-35
26. Lu H., Stansbury J.W., and Bowman C.N. Impact of curing protocol on conversion and shrinkage stress. J Dent Res 84 (2005) 822-826
27. Lovell L.G., Liu H., Elliott J.E., Stansbury J.W., and Bowmann C.N. The effect of cure rate on the mechanical properties of dental resins. Dent Mater 17 (2000) 504-511
28. Asmussen E., and Peutzfeldt A. Influence of pulse-delay curing on softening of polymer structures. J Dent Res 80 (2001) 1570-1573
29. Feng L., and Suh B.I. A mechanism on why slower polymerization of a dental composite produces lower contraction stress. J Biomed Mater Res B Appl Biomater 78 (2006) 63-69
30. Chen Y.C., Ferracane J.L., and Prahl S.A. A pilot study of a simple photon migration model for predicting depth of cure in dental composite. Dent Mater 21 (2005) 1075-1086
31. Chen Y.C., Ferracane J.L., and Prahl S.A. Quantum yield of conversion of the photoinitiator camphorquinone. Dent Mater 23 (2007) 655-664
32. Vaidyanathan J., Vaidyanathan T.K., Wang Y., and Viswanadhan T. Thermoanalytical characterization of visible light cure dental composites. J Oral Rehabil 19 (1992) 49-64
33. Rueggeberg F.A., Hashinger D.T., and Fairhurst C.W. Calibration of FTIR conversion analysis of contemporary dental resin composites. Dent Mater 6 (1990) 241-249
34. Schroeder W.F., Cook W.D., and Vallo C.I. Photopolymerization of N,N-dimethylaminobenzyl alcohol as amine co-initiator for light-cured dental resins. Dent Mater. 24 (2008) 686-693
35. Lovell L.G., Stansbury J.W., Syrpes D.C., and Bowman C.N. Effects of composition and reactivity on the reaction kinetics of dimethacrylate/dimethacrylate copolymerization. Macromolecules 32 (1999) 3913-3921
36. Floyd C.J., and Dickens S.H. Network structure of Bis-GMA- and UDMA-based resin systems. Dent Mater 22 (2006) 1143-1149
37. Stansbury J.W., and Dickens S.H. Network formation and compositional drift during photo-initiated copolymerization of dimethacrylate monomers. Polymer 42 (2001) 6363-6369
38. Lim B.S., Ferracane J.L., Sakaguchi R.L., and Condon J.R. Reduction of polymerization contraction stress for dental composites by two-step light-activation. Dent Mater 18 (2002) 436-444
39. Pfeifer C.S., Braga R.R., and Ferracane J.L. Pulse-delay curing: influence of initial irradiance and delay time on shrinkage stress and microhardness of restorative composites. Oper Dent 31 (2006) 610-615
40. Engelmann J., Volk J., Leyhausen G., and Geurtsen W. ROS Formation and glutathione levels in human oral fibroblasts exposed to TEGDMA and camphorquinone. J Biomed Mater Res B Appl Biomater 75 (2005) 272-276