Coil-globule transition of pyrene-labeled polystyrene in cyclohexane: Determination of polymer chain radii by fluorescence

Journal of Physical Chemistry B

Volumn 108, Issue 32, 2004, Pages 12009-12015

  Piçarra, Susana ^a,b   Duhamel, Jean ^c   Fedorov, A ^a   Martinho, J M G ^a  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

^b INSTITUTO POLITÉCNICO DE SETÚBAL   (Portugal)

^c UNIVERSITY OF WATERLOO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BANDWIDTH; FLUORESCENCE; FLUOROMETERS; LIGHT SCATTERING; MOLECULAR WEIGHT; MONOCHROMATORS; MONOMERS; PHASE DIAGRAMS; PHOTOMULTIPLIERS; SUPERCONDUCTING TRANSITION TEMPERATURE; TEMPERATURE CONTROL;

COIL-GLOBULE TRANSITIONS; CYCLOHEXANES; EXCIMER FORMATION; POLYMER CHAIN RADII; POLYMER CHAINS;

POLYSTYRENES;

EID: 4344692189     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp048616o     Document Type: Article

References (50)

1. Stockmayer, W. H. Makromol. Chem. 1960, 35, 54.
2. Doniach, S.; Garel, T.; Orland, H. J. Chem. Phys. 1996, 105, 1601.
3. Chan, H. S.; Dill, K. A. Phys. Today 1993, 24.
4. Takahashi, M.; Yoshikawa, K.; Vasilevskaya, V. V.; Khokhlov, A. R. J. Phys. Chem. B 1997, 101, 9396.
5. Grosberg, A. Y.; Khokhlov, A. R. Statistical Physics of Macromolecules; AIP Press: New York, 1994.
6. Mazur, J.; McIntyre, D. Macromolecules 1975, 8, 464.
7. Swislow, G.; Sun, S.-T.; Nishio, I.; Tanaka, T. Phys. Rev. Lett. 1980, 44, 796.
8. Sun, S.-T.; Nishio, I.; Swislow, G.; Tanaka, T. J. Chem. Phys. 1980, 73, 5971.
9. Taylor, L. D.; Cerenkowski, L. D. J. Polym. Sci. 1975, 13, 2551.
10. Wu, C.; Zhou, S. Macromolecules 1995, 28, 8381.
11. Wu, C.; Qiu, X. Phys. Rev. Lett. 1998, 80, 620.
12. Park, I. H.; Wang, Q.-W.; Chu, B. Macromolecules 1987, 20, 1965.
13. Park, I. H.; Fetters, L.; Chu, B. Macromolecules 1988, 21, 1178.
14. Chu, B.; Wang, Z. Macromolecules 1989, 22, 380.
15. Piçarra, S.; Gomes, P. T.; Martinho, J. M. G. Macromolecules 2000, 33, 3947.
16. Farinha, J. P. S.; Piçarra, S.; Miesel, K.; Martinho, J. M. G. J. Phys. Chem. B 2001, 105, 10536.
17. Piçarra, S.; Relógio, P.; Afonso, C.; Martinho, J. M. G.; Farinha, J. P. S. Macromolecules 2003, 36, 8119; 2004, 37, 1670.
18. Piçarra, S.; Relógio, P.; Afonso, C.; Martinho, J. M. G.; Farinha, J. P. S. Macromolecules 2003, 36, 8119; 2004, 37, 1670.
19. Mathew, A. K.; Siu, H.; Duhamel, J. Macromolecules 1999, 32, 7100.
20. Marquardt, D. W. J. Soc. Ind. Appl. Math. 1963, 11, 431.
21. Birks, J. B. Photophysics of Aromatic Molecules; Wiley-Interscience: London, 1970; p 19.
22. Yamanaka, T.; Takahashi, Y.; Kitamura, T.; Uchida, K. Chem. Phys. Lett. 1990, 172, 29.
23. Ilharco, L. M.; Martinho, J. M. G. Langmuir 1999, 15, 7490.
24. Ilharco, L. M.; Martins, C.; Fedorov, A.; Martinho, J. M. G. Chem. Phys. Lett. 1997, 277, 51.
25. Yamazaki, T.; Tamai, N.; Yamazaki, I. Chem. Phys. Lett. 1986, 124, 326.
26. Winnik, F. M. Chem. Rev. 1993, 93, 587.
27. Martinho, J. M. G.; Farinha, J. P.; Berberan-Santos, M. N.; Duhamel, J.; Winnik, M. A., J. Chem. Phys. 1992, 96, 8143.
28. Chu, B.; Ying, Q.; Grosberg, A. Y. Macromolecules 1995, 28, 180.
29. Ivanov, V. A.; Paul, W.; Binder, K. J. Chem. Phys. 1998, 13, 109.
30. Doye, J. P. K.; Sear, R.; Frenkel, D. J. Chem. Phys. 1998, 108, 2134.
31. Winnik, M. A. Acc. Chem. Res. 1985, 18, 73.
32. Martinho, J. M. G.; Martinho, M. H.; Winnik, M. A.; Beinert, G. Makromol. Chem. Suppl. 1989, 15, 113.
33. Winnik, M. A.; Li, X.-B.; Guillet, J. E. Macromolecules 1984, 17, 699. Winnik, M. A.; Egan, L. E.; Tencer, M.; Croucher, M. D. Polymer 1987, 28, 1553.
34. Winnik, M. A.; Li, X.-B.; Guillet, J. E. Macromolecules 1984, 17, 699. Winnik, M. A.; Egan, L. E.; Tencer, M.; Croucher, M. D. Polymer 1987, 28, 1553.
35. Kanagalingam, S.; Spartalis, J.; Cao, T.-M.; Duhamel, J. Macromolecules 2002, 35, 8571.
36. Duhamel, J.; Kanagalingam, S.; O'Brien, T.; Ingratta, M. J. Am. Chem. Soc. 2003, 125, 12810.
37. Prazeres, T. J. V.; Beingessner, R.; Duhamel. J.; Olesen, K.; Shay, G.; Bassett, D. R. Macromolecules 2001, 34, 7876.
38. Kanagalingam, S.; Ngan, C. F.; Duhamel, J. Macromolecules 2002, 35, 8560.
39. Zhang, M.; Duhamel, J.; van Duin, M.; Meessen, P. Macromolecules 2004, 37, 1877.
40. Siu, H.; Duhamel, J., manuscript submitted.
41. Winnik, F. M.; Regismond, S. T. A.; Goddard, E. D. Langmuir 1997, 13, 111.
42. Lee, S.; Duhamel, J. Macromolecules 1998, 31, 9193.
43. Cuniberti, C.; Perico, A. Prog. Polym. Sci. 1984, 10, 271.
44. CRC Handbook of Chemistry and Physics, 77th ed.; CRC Press: Boca Raton, FL, 1996.
45. Pyrene labeling might slightly shift the 6 temperature from the used value of 34.5°C.
46. Polymer Handbook, 3rd ed.; Brandrup, J., Immergut, E. M., Eds.; Wiley-Interscience: New York, 1989.
47. Schmidt, M.; Buchard, W. Macromolecules 1981, 14, 210.
48. Akcasu, A. Z.; Han, C. C. Macromolecules 1979, 12, 276.
49. Chu, B.; Wang, Z. Macromolecules 1989, 22, 380.
50. Raos, G.; Allegra, G. J. Chem. Phys. 1997, 107, 6479.