Reaction kinetics and critical phenomena: Saponification of ethyl acetate at the consolute point of 2-butoxyethanol + water

International Journal of Thermophysics

Volumn 25, Issue 4, 2004, Pages 1025-1036

  Kim, Y W ^a   Baird, J K ^a  

^a University of Alabama in Huntsville   (United States)

Author keywords

2 butoxyethanol; Critical slowing down; Kinetics; Saponification; Water

Indexed keywords

2-BUTOXYETHANOL; CONSTANT PRESSURE BINARY LIQUID MIXTURES; CRITICAL SLOWING DOWN;

BINARY MIXTURES; GIBBS FREE ENERGY; HYDROLYSIS; REACTION KINETICS; SAPONIFICATION;

PHASE DIAGRAMS;

EID: 4344679087     PISSN: 0195928X     EISSN: None     Source Type: Journal    
DOI: 10.1023/B:IJOT.0000038497.48181.11     Document Type: Article

References (17)

1. A. Findlay, A. N. Campbell, and N. O. Smith, The Phase Rule, 9th Ed. (Dover Publications, New York, 1951), Chapt. 6.
2. J. C. Clunie and J. K., Baird, Fluid Phase Equilib. 150-151:549 (1998).
3. J. K. Baird and J. C. Clunie, J. Phys. Chem. A 102:6498 (1998).
4. E. S. Gould, Mechanism and Structure in Organic Chemistry (Holt, Rinehart, and Winston, New York, 1959) Chaps. 8 and 9.
5. Y. W. Kim and J. K. Baird, Int. J. Thermophys. 22:1449 (2001).
6. Y. W. Kim and J. K. Baird, J. Phys. Chem. 107:8435 (2003).
7. J. K. Baird, J. Chem. Educ. 76:1146 (1999).
8. R. G. Griffiths and J. C. Wheeler, Phys. Rev. A 2:1047 (1970).
9. Y. W. Kim. Dissertation, University of Alabama in Huntsville (2000).
10. C.-H. Shaw and W. I. Goldburg, J. Chem. Phys. 65:4906 (1976).
11. J. F. Counsell, D. H. Everett, and R. J. Munn, Pure Appl Chem. 2:335 (1961).
12. J. C. Wheeler and R. G. Petschek, Phys. Rev. A 28:2442 (1983).
13. J. March, Advanced Organic Chemistry, 4th Ed. (John Wiley, New York, 1992), pp. 298-305.
14. C. A. VanderWerf, Acids, Bases, and the Chemistry of the Covalent Bond (Reinhold Publishing Corp., New York, 1961).
15. S. C. Greer and M. R. Moldover, Annu. Rev. Phys. Chem. 32:233 (1981).
16. J. V. Sengers and J. M. H. Levelt-Sengers, Annu. Rev. Phys. Chem. 37:189 (1986).
17. J. K. Baird and Y. W. Kim, J. Phys. Chem. 107:10241 (2003).