Mechanistic insights into anomalous kinetic behaviour in the hydrogenation of a substituted nitrobenzene

Advanced Synthesis and Catalysis

Volumn 346, Issue 8, 2004, Pages 943-946

  LeBars, Joel ^a,c   Dini, Stefano ^a   Hawkins, Joel M ^b   Blackmond, Donna G ^a,d  

^a UNIVERSITY OF HULL   (United Kingdom)

^b PFIZER INC   (United States)

^c ASTRAZENECA   (United Kingdom)

^d IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

Heterogeneous catalysis; Hydrogenation; Kinetic modelling; Langmuir Hinshelwood kinetics; Nitrobenzene; Rideal kinetics

Indexed keywords

NITROBENZENE;

ANALYTIC METHOD; ARTICLE; BINDING AFFINITY; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; HYDROGENATION; KINETICS; MOLECULAR INTERACTION; MOLECULAR MODEL; QUANTUM YIELD; SUBSTITUTION REACTION;

EID: 4344582934     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200303202     Document Type: Article

References (9)

1. J. M. Hawkins, T. W. Makowski, Org. Proc. Res. Dev. 2001, 5, 328.
2. J. LeBars, T. Haussner, J. Lang, A. Pfaltz, D. G. Blackmond, Adv. Synth. Catal. 2001, 2, 207.
3. V. Höller, D. Wegricht, I. Yuranox, L. Kiwi-Minsker, A. Renken, Chem. Eng. Tech. 2000, 23, 251.
4. a) D. D. Eley, E. K. Rideal, Proc. R. Soc. London, Ser. A. 1941, 178, 429, 452;
5. b) C. N. Satterfield, Heterogeneous Catalysis in Practice, McGraw-Hill, New York, 1980, pp 52-53.
6. eq to account for any surface sites containing "weakly bound" substrate remaining.
7. a) R. van Hardeveld, F. Hartog, Surf. Science, 1969, 15, 189;
8. b) J. Le Bars, U. Specht, J. S. Bradley, D. G. Blackmond, Langmuir, 1999, 15, 7621.
9. T. Rosner, J. LeBars, A. Pfaltz, D. G. Blackmond, J. Am. Chem. Soc. 2001, 123, 1848.