Competition experiments as a means of evaluating linear free energy relationships. An experiment for the advanced undergraduate organic chemistry lab

Journal of Chemical Education

Volumn 81, Issue 9, 2004, Pages 1357-1361

  Mullins, Richard J ^a   Vedernikov, Andrei ^a   Viswanathan, Rajesh ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CHEMICAL LABORATORIES; EXPERIMENTS; FREE ENERGY; MAGNESIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RATE CONSTANTS; SODIUM COMPOUNDS; STUDENTS; SUBSTRATES; TEACHING; THERMAL EFFECTS;

HYDROXYLAMINE; KINETIC EXPERIMENTS; LINEAR FREE ENERGY RELATIONSHIPS; METHYLMAGNESIUM BROMIDE; ORGANIC CHEMISTRY; SODIUM BOROHYDRIDE; TEACHING LAB;

PHYSICAL CHEMISTRY;

EID: 4344561594     PISSN: 00219584     EISSN: None     Source Type: Journal    
DOI: 10.1021/ed081p1357     Document Type: Article

References (19)

1. Isaacs, N. Physical Organic Chemistry, 2nd ed.; Longman Scientific & Technical: Harlow, United Kingdom, 1995; pp 146-192.
2. Lowry, T. H.; Richardson, K. S. Mechanism and Theory in Organic Chemistry, 3rd ed.; Harper & Row: New York, 1987; pp 143-159.
3. Hammett, L. P. J. Chem. Educ. 1966, 43, 464.
4. Hammett L. P. Chem. Rev. 1935, 17, 225.
5. Schwan, A. L. J. Chem. Educ. 1993, 70, 1001.
6. Marrs, P. S. J. Chem. Educ. 2001, 78, 527.
7. Leisten, J. A. J. Chem. Educ. 1961, 38, 302.
8. Hathaway, B. A.; Olesen, B. J. Chem. Educ. 1993, 70, 953.
9. Rodig, O. R.; Bell, C. E., Jr.; Clark, A. K. Organic Chemistry Laboratory, Standard and Microscale Experiments; Saunders: Philadelphia, PA, 1990; Chapters 22 and 23.
10. Blunt, J. W.; Harper, D. A. R. J. Chem. Educ. 1979, 56, 56.
11. Setliff, F. L.; Soman, N. G.; Toland, A. D. J. Chem. Educ. 1995, 72, 362.
12. Salmón, M.; Jiménez, A.; Salazar, I.; Zawadzki, R. J. Chem. Educ. 1973, 50, 370.
13. Schauble, J. H.; Walter, G. J.; Morin, J. G. J. Org. Chem. 1974, 39, 755.
14. Bowden, K.; Hardy, M. Tetrahedron 1966, 22, 1169.
15. Caplin, G. A. Org. Magn. Resonance 1973, 6, 99.
16. Bordwell, F. G.; Cornforth, F. J. J. Org. Chem. 1978, 43, 1763.
17. Aramendía, M. A.; Borau, V.; Goméz, J. F.; Herrera, A.; Jiménez, C.; Marinas, J. M. J. Catal. 1993, 140, 335.
18. Gordon, A. J.; Ford, R. A. The Chemist's Companion: A Handbook of Practical Data, Techniques, and References; Wiley: New York, 1972; p 144.
19. Lowry, T. H.; Richardson, K. S. Mechanism and Theory in Organic Chemistry, 3rd ed.; Harper & Row: New York, 1987; pp 702-709.