NMR spectroscopy of naturally occurring surface-adsorbed fluoride on Georgia kaolinite

Clays and Clay Minerals

Volumn 56, Issue 1, 2008, Pages 90-99

  Cochiara, Stacey G ^a   Phillips, Brian L ^a  

^a STONY BROOK UNIVERSITY   (United States)

Author keywords

19F NMR; Fluoride; Gibbsite; Kaolinite; Spectroscopy

Indexed keywords

CORRELATION METHODS; FLUORIDE MINERALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SORPTION; SUSPENSIONS (FLUIDS);

ACID WASH; GIBBSITE; MAGIC ANGLE SPINNING;

KAOLINITE;

ALUMINUM; CHEMICAL BONDING; EXPERIMENTAL MINERALOGY; FLUORIDE; KAOLINITE; NUCLEAR MAGNETIC RESONANCE; SORPTION; SPECTROSCOPY;

GEORGIA; NORTH AMERICA; UNITED STATES; WASHINGTON COUNTY [GEORGIA];

EID: 43349102732     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.2008.0560108     Document Type: Article

References (35)

1. Agarwal, M., Rai, K., Shrivastav, R., and Dass, S. (2002) A study on fluoride sorption by montmorillonite and kaolinite. Water Air and Soil Pollution, 141, 247-261.
2. Bar-Yosef, B., Afik, I., and Rosenberg, R. (1988) Fluoride sorption by montmorillonite and kaolinite. Soil Science, 145, 194-200.
3. Bickmore, B.R., Nagy, K.L., Sandlin, P.E., and Crater, T.S. (2002) Quantifying surface areas of clays by atomic force microscopy. American Mineralogist, 87, 780-783.
4. - system. Inorganic Chemistry, 39, 2530-2537.
5. Bower, C.A. and Hatcher, J.T. (1967) Adsorption of fluoride by soils and minerals. Soil Science, 103, 151-155.
6. Brady, P.V., Cygan, R.T., and Nagy, K.L. (1996) Molecular controls on kaolinite surface charge. Journal of Colloid and Interface Science, 183, 356-364.
7. 2Cl. Journal of the American Chemical Society, 123, 1694-1702.
8. Chupas, P.J., Corbin, D.R., Rao, V.N.M., Hanson, J.C., and Grey, C.P. (2003) A combined solid-state NMR and diffraction study of the structures and acidity of fluorinated aluminas: Implications for catalysis. Journal of Physical Chemistry B, 107, 8327-8336.
9. Davis, J.A. and Kent, D.B. (1990) Surface complexation modeling in aqueous geochemistry. Pp. 177-260 in: Interface Geochemistry (M.F. Hochella and A.F. White, editors). Reviews in Mineralogy, 23, Mineralogical Society of America, Washington, D.C.
10. Edmunds, W.M., and Smedley, P.L, (2005) Fluoride in natural waters Pp. 301-330 in: Essentials of Medical Geology: Impacts of the Natural Environment on Public Health (O. Selinus, editor). Academic Press, New York.
11. Fischer, L., Harle, V., Kasztelan, S., and de la Caillerie, J.B.D. (2000) Identification of fluorine sites at the surface of fluorinated γ-alumina by two-dimensional MAS NMR. Solid State Nuclear Magnetic Resonance, 16, 85-91.
12. 27 Al TRAPDOR NMR. Journal of the American Chemical Society, 117, 8232-8242.
13. Hiemstra, T. and van Riemsdijk, W.H. (2000) Fluoride adsorption on goethite in relation to different types of surface sites. Journal of Colloid and Interface Science, 225, 94-104.
14. Huertas, F.J., Chou, L., and Wollast, R. (1998) Mechanism of kaolinite dissolution at room temperature and pressure: Part I. surface speciation. Geochimica et Cosmochimica Acta, 62, 417-431.
15. 19F MAS-NMR study of structural fluorine in some natural and synthetic 2:1 layer silicates. Clays and Clay Minerals, 40, 186-191.
16. Kau, P.M.H., Smith, D.W., and Binning, P.J. (1997) The dissolution of kaolin by acidic fluoride wastes. Soil Science, 162, 996-911.
17. Kau, P.M.H., Smith, D.W., and Binning, P. (1998) Experimental sorption of fluoride by kaolinite and bentonite. Geoderma, 84, 89-108.
18. 19F nuclear magnetic resonance study of natural clays. Clays and Clay Minerals, 43, 697-704.
19. 19F NMR shifts. Journal of Physical Chemistry B, 107, 11280-11289.
20. Meenakshi and Maheshwari, R.C. (2006) Fluoride in drinking water and its removal. Journal of Hazardous Materials, 137, 456-463.
21. 19FNMR spectroscopy and aqueous surface chemistry. Geochimica et Cosmochimica Acta, 63, 3513-3524.
22. Perrott, K.W., Smith, B.F.L., and Inkson, R.H.E. (1976) Reaction of fluoride with soils and soil minerals. Journal of Soil Science, 27, 58-67.
23. 3-HF solutions at 298.2°K. Journal of Colloid and Interface Science, 101, 554-564.
24. 3) at equilibrium. Geochimica et Cosmochimica Acta, 68, 3547-3555.
25. 3) particles in aqueous suspension. Langmuir, 18, 4598-4604.
26. Sigg, L. and Stumm, W. (1981) The interaction of anions and weak acids with the hydrous goethite (α-FeOOH) surface. Colloids and Surfaces, 2, 101-117.
27. Sposito, G. (1984) The Surface Chemistry of Soils. Oxford University Press, New York, 234 pp.
28. Thomas, J., Glass, H.D., White, W.A., and Trandel, R.M. (1977) Fluoride content of clay minerals and argillaceous earth materials. Clays and Clay Minerals, 25, 278-284.
29. Vasudevan, D. and Stone, A.T. (1998) Adsorption of 4-nitrocatechol, 4-nitro-2-aminophenol, and 4-nitro-1,2-phenylenediamine at the metal (hydr)oxide/water interface: Effect of metal (hydr)oxide properties. Journal of Colloid and Interface Science, 202, 1-19.
30. Weerasooriya, R. and Wickramarathna, H.U.S. (1999) Modeling anion adsorption on kaolinite. Journal of Colloid and Interface Science, 213, 395-399.
31. Weerasooriya, R., Wickramarathne, H.U.S., and Dharmagunawardhane, H.A. (1998) Surface complexation modeling of fluoride adsorption onto kaolinite. Colloids and Surfaces A, 144, 267-273.
32. Wolff-Boenisch, D., Gislason, S.R., and Oelkers, E.H. (2004) The effect of fluoride on the dissolution rates of natural glasses at pH 4 and 25°C. Geochimica et Cosmochimica Acta, 68, 4571-4582.
33. 12 polyoxocation: Implications for aluminum (hydr)oxide mineral surfaces. Geochimica et Cosmochimica Acta, 67, 1065-1080.
34. Zeng, Q. and Stebbins, J.F. (2000) Fluoride sites in alumino-silicate glasses: High-resolution 19F NMR results. American Mineralogist, 85, 863-867.
35. Zutic, V. and Stumm, W. (1984) Effect of organic acids and fluoride on the dissolution kinetics of hydrous alumina: A model study using the rotating disk electrode. Geochimica et Cosmochimica Acta, 48, 1493-1503.