The effect of nitrate esters on the thermal decomposition mechanism of GAP

Journal of Hazardous Materials

Volumn 154, Issue 1-3, 2008, Pages 112-117

  Sun, Yunlan ^a   Li, Shufen ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

Author keywords

GAP; Nitrate esters; Thermal decomposition mechanism

Indexed keywords

CROSSLINKING; NITRATES; PLASTICIZERS; PYROLYSIS;

NITRATE ESTERS; THERMAL DECOMPOSITION MECHANISM;

ESTERS;

ESTER DERIVATIVE; GLYCIDYL AZIDE POLYMER; ISOCYANATE; NITRATE; POLYMER; PROPELLANT;

CROSSLINKING; ESTERS; NITRATES; PLASTICIZERS; PYROLYSIS;

CARBAMATE; COMPARATIVE STUDY; DIFFERENTIAL THERMAL ANALYSIS; ESTER; EXPERIMENTAL STUDY; FTIR SPECTROSCOPY; NITRATE; POLYMER; THERMAL DECOMPOSITION; THERMOGRAVIMETRY;

ADDITION REACTION; ARTICLE; CROSS LINKING; DECOMPOSITION; INFRARED SPECTROSCOPY; TEMPERATURE SENSITIVITY; THERMAL ANALYSIS; THERMOGRAVIMETRY;

DIFFERENTIAL THERMAL ANALYSIS; ESTERS; HEAT; NITRATES; POLYMERS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; THERMOGRAVIMETRY;

EID: 43049091567     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2007.10.002     Document Type: Article

References (16)

1. E.J. Vandenburg, Polymers Containing Azidomethyl Side Chains, US Patent 3,645,917 (1972).
2. A. Provatas, Energetic Polymers and Plasticisers for Explosive Formulations-A Review of Recent Advances, Melbourne, Australia, 2000.
3. Oyumi Y., Kimura E., and Nagayama K. Impact sensitivity of azide polymer composite propellants. Propellants Explos. Pyrotech. 23 (1998) 123
4. Desai H.J., Cunliffe A.V., Millar R.W., Paul N.C., Stewart M.J., and Amass A.J. Synthesis of narrow molecular weight α,ω-hydroxy telechelic poly(glycidyl nitrate) and estimation of theoretical heat of explosion. Polymer 37 15 (1996) 3471
5. Vasudevan V., and Sundararajan G. Synthesis of GAP-PB-GAP triblock copolymer and application as modifier in AP/HTPB composite propellant. Propellants Explos. Pyrotech. 24 (1999) 295
6. Feng H.T., Mintz K.J., Augsten R.A., and Jones D.E.G. Thermal analysis of branched GAP. Thermochem. Acta 311 (1998) 105
7. Agrawal J.P., Walley S.M., and Field J.E. High-speed photographic study of the impact response of ammonium dinitramide and glycidyl azide polymer. J. Propuls Power 13 (1997) 463
8. Selim K., Ozkar S., and Yilmaz L. Thermal characterization of glycidyl azide polymer (GAP) and GAP-based binders for composite propellants. J. Appl. Polym. Sci. 77 (2000) 538
9. Fazlioǧlu H., and Hacaloǧlu J. Thermal decomposition of glycidyl azide polymer by direct insertion probe mass spectrometry. J. Anal. Appl. Pyrol. 63 (2002) 327
10. Hori K., and Kimura M. Combustion mechanism of glycidyl azide polymer. Propellants Explos. Pyrotech. 21 (1996) 160
11. Korobeinichev O.P., Kuibida L.V., Volkov E.N., and Shmakov A.G. Mass spectrometric study of combustion and thermal decomposition of GAP. Combust. Flame 129 (2002) 136
12. Arisawa H., and Brill T.B. Thermal decomposition of energetic materials, 71. Structure decomposition and kinetic relationships in flash pyrolysis of glycidyl azide polymer (GAP). Combust. Flame 112 (1998) 533
13. Tang C.J., and Litzinger T.A. Simultaneous temperature and species measurements of the glycidyl azide polymer (GAP) propellant during laser-induced decomposition. Combust. Flame 117 (1999) 244
14. Trubert J.F., Duterque J., and Lengellé G. Thirtieth International Annual Conference of ICT Fraunhofer Institut Chemische Technologie. Karlsruhe (1999) 23.1-23.17
15. Roos B.D., and Brill T.B. Thermal decomposition of energetic materials, 81. Flash pyrolysis of GAP/RDX/BTTN propellant combinations. Propellants Explos. Pyrotech. 26 (2001) 213
16. Liu Rong, The Thermal Behavior of Nitrocellulose with High Nitrogen Contents [D], Xi'an Modern Chemistry Research Institution, 1997 (in Chinese).