Electrocatalytic dechlorination of a PCB congener at a palladized granular-graphite-packed electrode: Reaction equilibrium and mechanism

Applied Catalysis B: Environmental

Volumn 80, Issue 3-4, 2008, Pages 327-334

  Fang, Yuanxiang ^a   Al Abed, Souhail R ^a  

^a U S ENVIRONMENTAL PROTECTION AGENCY   (United States)

Author keywords

Electrocatalytic dechlorination; Equilibrium; Kinetics; Polychlorinated biphenyls (PCBs); Rate law; Reaction mechanism

Indexed keywords

CATALYST ACTIVITY; DECHLORINATION; ELECTROCATALYSIS; ELECTROCHEMICAL ELECTRODES; REACTION KINETICS;

ELECTROCATALYTIC DECHLORINATION; FIRST ORDER KINETICS; RATE LAW;

POLYCHLORINATED BIPHENYLS;

EID: 42749089646     PISSN: 09263373     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcatb.2007.11.021     Document Type: Article

References (16)

1. Farwell S.O., Beland F.A., and Geer R.D. Electroanal. Chem. Interf. Electrochem. 61 (1975) 315-324
2. Rusling J.F., Shi C.N., and Suib S.L. J. Electroanal. Chem. 245 (1988) 331-337
3. Zhang S., and Rusling J.F. Environ. Sci. Technol. 27 (1993) 1375-1380
4. Kulikov S.M., Plekhanov V.P., Tsyganok A.I., Schlimm C., and Heitz E. Electrochim. Acta 41 (1996) 527-531
5. Cheng I.F., Fernando Q., and Korte N. Environ. Sci. Technol. 31 (1997) 1074-1078
6. Tsyganok A.I., Otsuka K., and Yamanaka I. J. Electrochem. Soc. 145 (1998) 3844-3850
7. Lin C.-H., and Tseng S.-K. Chemosphere 39 (1999) 2375-2389
8. Szebenyi-Gyori E., Gagyi-Palffy E., Bajnoczy G., and Prepostffy E. Period. Polytech. Ser. Chem. Eng. 43 (1999) 65-76
9. Tsyganok A.I., Yamanaka I., and Otsuka K. Chemosphere 39 (1999) 1819-1831
10. Dabo P., Cyr A., Laplante F., Jean F., Menard H., and Lessard J. Environ. Sci. Technol. 34 (2000) 1265-1268
11. Fang Y., and Al-Abed S.R. Chemosphere 66 (2007) 226-233
12. Holmes D.A., and Harrison B.K. Environ. Sci. Technol. 27 (1993) 725-731
13. Schwarzenbach R.P., Gschwend P.M., and Imboden D.M. Environmental Organic Chemistry. 2nd ed. (2003), Wiley-Interscience
14. Vogel T.M., Criddle C.G., and McCarty P.L. Environ. Sci. Technol. 21 (1987) 722-736
15. Masel R.I. Principles of Adsorption and Reaction on Solid Surfaces (1996), John Wiley & Sons Inc.
16. Rieger P.H. Electrochemistry. 2nd ed. (1994), Chapman & Hall Inc.