Interpretation of relaxation and swelling phenomena in lyocell regenerated cellulosic fibres and textiles associated with the uptake of solutions of sodium hydroxide

Cellulose

Volumn 15, Issue 3, 2008, Pages 393-406

  Ibbett, Roger ^a   Taylor, Jim ^b   Schuster, K Christian ^b   Cox, Mike ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b LENZING AG   (Austria)

Author keywords

Cellulose; Fibre swelling; Gel pressure; Ionic equilibrium; Lyocell; Mechanics; Osmotic pressure; Regenerated; Relaxation; Shrinkage; Sodium cellulose; Sodium hydroxide; Textile; X ray diffraction

Indexed keywords

DIFFUSION; FIBERS; ION EXCHANGE; MATHEMATICAL MODELS; OSMOSIS; PORE STRUCTURE; SHRINKAGE; STRESS RELAXATION; SWELLING; TEXTILES;

GEL PRESSURE; IONIC EQUILIBRIUM; LYOCELL;

CELLULOSE;

CELLULOSE FABRIC; CELLULOSE FIBERS; DIFFUSION; ION EXCHANGE; MATHEMATICAL MODELS; OSMOTIC PRESSURE; SHRINKAGE; STRESS RELAXATION; SWELLING;

DIFFUSION; LYOCELL FIBER; REGENERATED CELLULOSE FIBER; RELAXING; SWELLING; WOVEN FABRIC;

EID: 42649105862     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-007-9180-6     Document Type: Article

References (36)

1. Abu-Rous M, Ingolic E, Schuster KC (2006) Visualisation of the fibrillar and pore morphology of cellulosic fibres applying transmission electron microscopy. Cellulose 13:411-419
2. Bird CL, Boston WS (1975) (eds) The theory of colouration of textiles. Chapter 5 by Jones F. The Dyers Company Publications, Trust, Bradford UK
3. Colom X, Carillo F (2002) Crystallinity changes in lyocell and viscose-type fibres by caustic treatment. Eur Polym J 38:2225-2230
4. Crawshaw J, Cameron RE (2000) A small angle X-ray scattering study of the pore structure in Tencle cellulose fibres and the effects of physical treatments. Polymer 41:4691-4698
5. Donnan FG (1934) Z physik Chem 168A:369
6. Eichhorn SJ, Young RJ, Davies GR (2005) Modeling crystal and molecular deformation in regenerated cellulose fibers. Biomacromolecules 6:507-513
7. Fieldson GT Barbari TA (1993) The use of FTIR-ATR spectroscopy to characterize penetrant diffusion in polymers. Polymer 34(6):1146-1153
8. Fink H-P, Weigel P, Purz H-J, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473-1524
9. Glueckauf E (1952) A theoretical treatment of cation exchangers I. The prediction of equilibrium constants from osmotic data. Proc Roy Soc A 214(1117):207-225
10. Gregor HP (1951) Gibbs-Donnan equilibria in ion exchange resin systems. J Am Chem Soc 73:642-650
11. Hearles JWS, Miles LWC (1971) The setting of fibres and fabrics. Merrow Publishing Co Ltd, Watford, UK
12. Hodson S, Earlam R (1993) The incorporation of gel pressure into the irreversible thermodynamic equation of fluid flow in order to explain biological tissue swelling. J Theor Biol 163:173-180
13. Ibbett (1996) Tencel Ltd Internal report
14. Ibbett RN, Hsieh Y-L (2001) Effect of fibre swelling on the structure of lyocell fabrics. Text Res J 71(2):164-173
15. Ibbett RN, Fashing M, Domvoglou D (2007) Characterisation of the supramolecular structure of chemically and physically modified regenerated cellulosic fibers by means of high-resolution Carbon-13 solid state NMR. Polymer 48:1287-1296
16. Kawai T (1959) Sorption of water vapor by cellulose and polymers at high humidities. J Polym Sci 37:181-198
17. Kolpak FJ, Weih M, Blackwell J (1978) Mercerisation of cellulose: L. Determination of the structure of mercerized cotton. Polymer 19:123-131
18. Laity PR, Gover PM, Godward J, McDonald PJ, Hay JN (2000) Structural studies and diffusion measurements of water-swollen cellophane by NMR Imaging. Cellulose 7:227-246
19. Lenz J, Schurz J, Eichinger D (1994) Properties and structure of lyocell and viscose-type fibres in the swollen state. Lenzinger Berichte 74:19-25
20. Moss CE, Butler MF, Müller M, Cameron RE (2002) Microfocus small-angle X-ray scattering investigation of the skin-core microstructure of lyocell cellulose fibers. J Appl Polym Sci 83:2799-2816
21. Neale SM (1929) J Textile Inst 20:T373
22. Nishimura H, Sarko A (1987) Mercerisation of cellulose III. Changes in crystallite sizes. J Appl Polym Sci 33:855-866
23. Nishimura H, Sarko A (1991b) Mercerisation of cellulose 6. Crystal and molecular structure of Na-cellulose IV. Macromolecules 24:771-778
24. Nishimura H, Okano T, Sarko A (1991a) Mercerisation of cellulose 5. Crystal and molecular structure of Na-cellulose-I. Macromolecules 24:759-770
25. Okano T, Sarko A (1984) Mercerisation of cellulose. I X-ray diffraction evidence for intermediate structures. J Appl Polym Sci 29:4175-4182
26. Okano T, Sarko A (1985) Mercerisation of cellulose. II Alkali-cellulose intermediates and a possible mercerization mechanism. J Appl Polym Sci 30:325-332
27. Paterson R (1970) An introduction to ion-exchange. Hayden and Son Ltd, London
28. Pennings AJ, Prins W (1962) The polyelectrolyte nature of cellulose gels in alkali solutions. J Polym Sci 58:229-248
29. Pierce FT (1937) The geometry of cloth structure. J Textile Inst 28:45-96
30. Preston C (1986) (ed) The Dyeing of Cellulosic Fibres. Chapter 3. by Holme I, Dyers' Company Publications Trust, Bradford UK
31. Scallan AM, Grignon J (1980) Effect of pH and neutral salts upon the swelling of cellulose gels. J Appl Polym Sci 25:2829-2843
32. Schurz J, Lenz J (1994) Investigation of the structure of regenerated cellulose fibres. Macromol Symp 83:273-289
33. Tarfaoui M, Akesbi S (2001) Study of the mechanical behaviour of textile structures. Int J Clothing Sci Technol 13:166-175
34. 3C CP/MAS NMR study on alkali cellulose. J App Pol Sci 41:783-791
35. Zhang W, Okubayashi S, Bechtold T (2005) Fibrillation tendency of cellulosic fibers. Part 1: Effects of swelling. Cellulose 12(3):267-273
36. Zhu Y, Ren X, Wu C (2004) Influence of alkali treatment on the structure of newcell fibres. J Appl Polym Sci 93:1731-1735