High spin/low spin phase transitions of a spin-crossover complex in the emulsion polymerization of trifluoroethylmethacrylate (TFEMA) using PVA as a protective colloid

Colloid and Polymer Science

Volumn 286, Issue 5, 2008, Pages 525-534

  Suzuki, Atsushi ^a   Fujiwara, Motoyasu ^b   Nishijima, Masahiko ^c  

^a UNIVERSITY OF SHIGA PREFECTURE   (Japan)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

Emulsion polymerization; Highspin low spin (HS LS) phase transition; Poly(vinylalcohol) (PVA); Spin crossover complex; Trifluoroethyl methacrylate(TFEMA)

Indexed keywords

JAHN-TELLER EFFECT; LIGAND SUBSTITUTION; SPIN-CROSSOVER COMPLEX; TRIFLUOROETHYLMETHACRYLATE;

CHEMICAL MODIFICATION; EMULSION POLYMERIZATION; PARAMAGNETIC RESONANCE; PHASE TRANSITIONS; POLYVINYL ALCOHOLS; PROTECTIVE COLLOIDS;

ORGANIC POLYMERS;

DODECYL SULFATE SODIUM; FERROUS ION; METHACRYLIC ACID; POLYMER; POLYVINYL ALCOHOL; TRIFLUOROETHANOL; TRIFLUOROETHYLMETHACRYLATE; UNCLASSIFIED DRUG;

ANISOTROPY; ARTICLE; CHEMICAL MODIFICATION; COLLOID; CONTROLLED STUDY; ELECTRON SPIN RESONANCE; EMULSION; PHASE TRANSITION; POLYMERIZATION; PRIORITY JOURNAL;

EID: 42549138489     PISSN: 0303402X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00396-007-1796-4     Document Type: Article

References (19)

1. Decurtins S, Gütlich P, Hasselbach KM, Hauser A, Spiering H (1985) Inorg Chem 24:2174-2178
2. Kröber J, Codjovi E, Kahn O, Groliere F, Jay C (1994) J Am Chem Soc 115:9810-9812
3. Gütlich P, Hauser A, Spiering H (1994) Angew Chem, Int Ed Engl 33:204-2054
4. Kato K, Takata M, Moritomo Y, Nakamoto A, Kojima N (2007) Appl Phys Lett 90:201902
5. Moritomo Y, Kato K, Kuriki A, Nakamoto A, Kojima N, Takata M, Sakata M (2002) J Phys Soc Jpn 71:2609-2612
6. Kahn O, Martinez CJ (1998) Science 279:44
7. Carbonera C, Cosata JS, Money VA, Elhaïk J, Howard JAK, Halcrow MA, Letard JF (2006) Dalton Transactions. Chemical Society, London, pp 3058-3066
8. Yamada M, Arai M, Kurihara M, Sakamoto M, Miyake M (2004) J Am Chem Soc 126:9482
9. Yamada M, Maesaka M, Kurihara M, Sakamoto M, Miyake M (2005) Chem Commun 4851-4853
10. Yamada M, Shen Z, Miyake M (2006) Chem Commun 2569-2571
11. Landfester K (2001) Adv Mater 10:765
12. Antonietti M, Landfester K (2002) Prog Polym Sci 27:689
13. Okaya T, Suzuki A, Kikuchi K (2002) Colloid and Poly Sci 280:188-192
14. Suzuki A, Yano M, Saiga T, Kikuchi K, Okaya T (2003) Prog in Colloid and Poly Sci 124:27-30
15. Saiga T, Suzuki A, Kikuchi K, Okaya T (2005) e-polymers 77:1-9
16. Suzuki A, Yano M, Saiga T, Kikuchi K, Okaya T (2006) Colloid and Poly Sci 285:185-192
17. Suzuki A, Matsuda Y, Kikuchi K, Okaya T (2006) Colloid and Poly Sci 285:193-201
18. Suzuki S, Kikuchi K, Suzuki A, Okaya T, Nomura M (2006) Colloid and Poly Sci 285:523-534
19. Herchel R, Boca R, Gembicky M, Kozisek J, Renz F (2004) Inorg Chem 43:4103-4105