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Stochastic fields created by high-amplitude nuclear motions manifest the rearrangement of molecular groups in a given environment. Therefore, such fields can be characterized by mean lifetimes [Formula Presented] (or mean escape frequencies [Formula Presented] of molecular groups related to the mean times they spent in certain sites [Formula Presented], c18
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Stochastic fields created by high-amplitude nuclear motions manifest the rearrangement of molecular groups in a given environment. Therefore, such fields can be characterized by mean lifetimes τj (or mean escape frequencies νj=τj-1) of molecular groups related to the mean times they spent in certain sites j 18.
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To derive a Born approximation from a general form of the stochastic master equation one has to be sure that [Formula Presented] is in fact a small perturbation. To find a perturbation [Formula Presented] in a concrete physical system, the given system has to be divided in such a manner that a chosen quantum system and a heat bath become well separated from one another, i.e., a mixture between ce:degrees of freedom of the system and the bath caused by an interaction [Formula Presented] has to be rather weak
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To derive a Born approximation from a general form of the stochastic master equation one has to be sure that V is in fact a small perturbation. To find a perturbation V in a concrete physical system, the given system has to be divided in such a manner that a chosen quantum system and a heat bath become well separated from one another, i.e., a mixture between ce:degrees of freedom of the system and the bath caused by an interaction V has to be rather weak.
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