A powerful new oxidation agent towards metallic gold powder: N,N′-dimethylperhydrodiàzepine-2,3-dithione (D) bis(diiodine). Synthesis and X-ray structure of [AuDI2]I3

Chemical Communications

Volumn , Issue 21, 1998, Pages 2351-2352

  Bigoli, Francesco ^a   Deplano, Paola ^b   Mercuri, Maria Laura ^b   Pellinghelli, Maria Angela ^a   Pintus, Gloria ^b   Serpe, Angela ^b   Trogu, Emanuele F ^b  

^a UNIVERSITY OF PARMA   (Italy)

^b UNIVERSITY OF CAGLIARI   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 4244163338     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a806158k     Document Type: Article

References (17)

1. N. Bricklebank, S. M. Godfrey, C. A. McAuliffe, A. G. Mackie and R. G. Pritchard, J. Chem. Soc., Chem. Commun., 1992, 944;
2. S. M. Godfrey, C. A. McAuliffe and R. G. Pritchard, J. Chem. Soc., Dalton Trans., 1993, 371 and 2875;
3. S. M.Godfrey, D. G. Kelly, C. A. McAuliffe and R. G. Pritchard, J. Chem. Soc., Dalton Trans., ibid., 2053;
4. S. M. Godfrey, C. A. McAuliffe and R. G. Pritchard, J. Chem. Soc., Chem. Commun., 1994, 45;
5. N. Bricklebank, S. M. Godfrey, C. A. McAuliffe and R. G. Pritchard, J. Chem. Soc., Dalton Trans., 1996, 157.
6. S. M. Godfrey, N. Ho, C. A. McAuliffe and R. G. Pritchard, Angew. Chem., Int. Ed. Engl., 1996, 33, 2344.
7. F. Bigoli, P. Deplano, F. A. Devillanova, V. Lippolis, M. L. Mercuri, M. A. Pellinghelli and E. F. Trogu, Inorg. Chim. Acta, 1998, 267, 115, and references therein.
8. Prepared according to R. Isaksson, T. Liljefors and J. Sandstrom, J. Chem. Res. (S), 1981, 43.
9. (a) T. J. Marks, Ann. NY Acad. Sci., 1970, 313, 594;
10. (b) J. R. Ferraro, Coord. Chem. Rev., 1982, 43, 205;
11. (c) P. Deplano, F. A. Devillanova, J. R. Ferraro, F. Isaia, V. Lippolis and M. L. Mercuri, Appl. Spectrosc., 1992, 46, 1625;
12. (d) F. Bigoli, P. Deplano, M. L. Mercuri, M. A. Pellinghelli, A. Sabatini, E. F. Trogu and A. Vacca, J. Chem. Soc., Dalton Trans., 1996, 3583.
13. 2 [d(I-I) = 2.715 Å, F. van Bolhuis, P. B. Koster and T. Migehelsen, Acta Crystallogr., 1967, 23, 90]) is shifted to lower frequencies upon coordination as a consequence of the lowering of the force constant of the I-I vibration in a CT adduct.
14. 1/2.
15. N. Walker and D. Stuart, Acta Crystallogr., Sect. A, 1983, 39, 158.
16. A. Altomare, C. Cascarano, C. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori and M. Camalli, J. Appl. Crystallogr., 1994, 27, 435.
17. G. M. Sheldrick, SHELX-97: Program for Crystal Structure Determination, Universität Göttingen, Germany, 1997.