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Since the vibrational levels are nearly degenerate, Fermi-type resonances may also cause both intrastate and interstate couplings.
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D is the vibrational quantum number at the dissociation limit, and μ is the reduced mass [see R. J. LeRoy, Can. J. Phys. 50, 953 (1972); R. J. LeRoy and M. G. Barwell, ibid. 53, 1983 (1975)].
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85015783720
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note
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Here we assume a geometrical average.
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42
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85015763562
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note
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Overlap of the wave functions occurs in regions where the wave functions oscillate rapidly, giving rise to small Frank-Condon factors.
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